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CoII immobilized on aminated mesoporous SBA-16 (SBA-16/GPTMS-NH2–CoII): a highly efficient mesostructured catalyst for the C–O bond formation under solvent-free conditions

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Abstract

Herein an able, facile, coherent, and environmentally benign synthesis of the C–O coupling reaction based on the functionalized mesoporous silica SBA-16 (CoII immobilized on mesoporous SBA-16 functionalized by aminated 3-glycidyloxypropyltrimethoxysilane with aminoguanidine nitrate), is described. The mesostructured nanocatalyst (SBA-16/GPTMS-NH2–CoII) is characterized by various analytical techniques such as FT-IR, small-angle XRD, XRD, BET, TEM, FE-SEM, EDX, EDX-mapping, and ICP-OES analysis. Cage-like mesoporous SBA-16 efficiently managed dispersed the metal and organic species in the well-ordered siliceous frameworks. It was found that the aforementioned mesostructured catalyst with a special structure and particle size distribution (3–8 nm) displayed great catalytic performance to promote of the C–O cross-coupling reaction from the iodobenzene and phenol in solvent-free conditions. Plus, SBA-16/GPTMS-NH2–CoII as an inimitable heterogeneous nanocatalyst can be readily separated from the reaction mixture by simple filtration under reaction conditions and recycled at least five times without any loss of its catalytic efficiency.

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All data supporting the findings of this study are available with the article, as well as the Supplementary Information file, or available from the corresponding authors upon reasonable request. Source data are provided in this paper.

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The author is grateful for the partial support of this study by Qeshm Branch, Islamic Azad University.

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  1. Department of Chemistry, Faculty of Science, Qeshm Branch, Islamic Azad University, 79515-1393, Qeshm, Iran

    Melika Eftekhar & Iman Khosravi

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  1. Melika Eftekhar
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Iman khosravi co-wrote the manuscript.

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Correspondence to Melika Eftekhar.

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Eftekhar, M., Khosravi, I. CoII immobilized on aminated mesoporous SBA-16 (SBA-16/GPTMS-NH2–CoII): a highly efficient mesostructured catalyst for the C–O bond formation under solvent-free conditions. J Porous Mater 30, 1255–1272 (2023). https://doi.org/10.1007/s10934-022-01414-y

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