Skip to main content
Log in

Preparation of super-hydrophobic cotton fabrics with conductive property based on graphene/Ag composite aerogels

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

In this work, graphene/Ag (GA/Ag) composite aerogels with the micro rough porous structure and conductive property and polydimethylsiloxane(PDMS) with the low surface energy were used to prepare super-hydrophobic cotton fabric (GA/Ag/PDMS@cotton) with conductive property was successfully prepared. The surface morphologies, chemical composition, wettability, conductive property and microwave absorption property of GA/Ag/PDMS@cotton fabric were characterized. It was shown that GA/Ag and PDMS were successfully coated onto the surface of cotton fabrics. The water contact angle of GA/Ag/PDMS@cotton was 157°. And it could make the luminous diode shining continuously. The treated cotton fabrics exhibited excellent super-hydrophobic and conductive properties. The minimum reflection loss of GA/Ag/PDMS@cotton fabric was − 28 dB, and it had a larger effective absorption bandwidth. In addition, the treated cotton fabric also showed excellent anti-fouling and self-cleaning properties. The GA/Ag/PDMS@cotton fabric cannot be wetted and polluted by water, fruit juice, milk and black tea. And it also had excellent washing durability, acid and alkali corrosion and storage stability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. K. Qian, Z. Yao, H. Lin et al., The influence of Nd substitution in Ni–Zn ferrites for the improved microwave absorption properties. Ceram. Int. 46(1), 227–235 (2019)

    Article  Google Scholar 

  2. J.L. Pan, R.J. Zhang, J. Ling et al., Controllable preparation and microwave absorption properties of shape anisotropic Fe3O4 nanobelts. J. Materiomics (2021). https://doi.org/10.1016/j-jmat.2021.03.009

    Article  Google Scholar 

  3. P. Chen, L.W. Jiang, S.S. Yang et al., Facile synthesis and microwave-absorption properties of organic-inorganic CoFeO/Polyaniline nanocomposites with embedded structure. J. Nanosci. Nanotechnol. 20(3), 1756–1764 (2020)

    Article  CAS  PubMed  Google Scholar 

  4. M.A. Kazakova, N.V. Semikolenova, E.Y. Korovin et al., Co/multi-walled carbon nanotubes/polyethylene composites for microwave absorption: tuning the effectiveness of electromagnetic shielding by varying the components ratio. Compos. Sci. Technol. (2021). https://doi.org/10.1016/J.COMPSCITECH.2021.108731

    Article  Google Scholar 

  5. C.B. Ge, G.L. Wang, G.Q. Zhao et al., Lightweight and flexible poly (ether-block-amide)/ multiwalled carbon nanotube composites with porous structure and segregated conductive networks for electromagnetic shielding applications. Compos. A (2021). https://doi.org/10.1016/J.COMPOSITESA.2021.106356

    Article  Google Scholar 

  6. M.M. Jiang, Y. Ding, L.H. Xu et al., Application of graphene in electrical resistance electromagnetic shielding fabric. J. Phys. Conf. Ser. (2021). https://doi.org/10.1088/1742-6596/1790/1/012079

    Article  Google Scholar 

  7. M. Mohseni, H.S. Far, M. Hasanzadeh et al., Non-fluorinated sprayable fabric finish for durable and comfortable super-hydrophobic textiles. Prog. Org. Coat. 157, 42–46 (2021)

    Google Scholar 

  8. K.K. Kazemi, T. Zarifi, M. Mohseni et al., Smart super-hydrophobic textiles utilizing a long-range antenna sensor for hazardous aqueous droplet detection plus prevention. ACS Appl. Mater. Interfaces. (2021). https://doi.org/10.1021/ACSAMI.1C07880

    Article  PubMed  Google Scholar 

  9. H.K. Peng, Y.T. Wang, T.T. Li et al., Super-hydrophobic/flame retardant/emi shielding fabrics: manufacturing techniques and property evaluations. Appl. Sci. 9(9), 1914 (2019)

    Article  CAS  Google Scholar 

  10. J.F. Gao, L. Wang, Z. Guo et al., Flexible, super-hydrophobic, and electrically conductive polymer nanofiber composite for multifunctional sensing applications. Chem. Eng. J. 381(381), 493–502 (2020)

    Google Scholar 

  11. M. Abraham, K. Svetlana, Super-hydrophobic surfaces: methodological considerations for physical design. J. Colloid Interface Sci. 568(568), 148–154 (2020)

    Google Scholar 

  12. S.H. Li, J.Y. Huang, Z. Chen et al., Review on special wettability textiles: theoretical models, fabrication technologies and multifunctional applications. J. Mater. Chem. A 5(1), 31–55 (2017)

    Article  CAS  Google Scholar 

  13. L. Wang, S. Zhang, A. Ambrosi, 3D-graphene for electrocatalysis of oxygen reduction: increasing number of layers increases the catalytic effect. Electrochem. commun. 46, 148–151 (2014)

    Article  CAS  Google Scholar 

  14. Y.X. Xu, K.X. Sheng, C. Li et al., Self-assembled graphene hydrogel via a one-stephydrothermal process. ACS Nano. 4(7), 4324–4330 (2010)

    Article  CAS  PubMed  Google Scholar 

  15. W. Chen, L. Yan, In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures. Nanoscale 3(8), 1–5 (2011)

    Article  CAS  Google Scholar 

  16. C. Zhu, S. Dong, Recent process in graphene-based nanomaterials as advanced electrocatalysts towards oxygen reduction reaction. Nanoscale 5(5), 1753–1767 (2013)

    Article  CAS  PubMed  Google Scholar 

  17. Y. Qin, C.L. Xue, H.R. Yu et al., The construction of bio-inspired hierarchically porous graphene aerogel for efficiently organic pollutants absorption. J. Hazard. Mater. (2021). https://doi.org/10.1016/J.JHAZMAT.2021.126441

    Article  PubMed  Google Scholar 

  18. J.H. Yin, D. Gao, X.M. Zhu et al., One-pot synthesis of 3D porous Bi7O9I3/N-doped graphene aerogel with enhanced photocatalytic activity for organic dye degradation in wastewater. Ceram. Int. (2021). https://doi.org/10.1016/J.CERAMINT.2021.03.293

    Article  Google Scholar 

  19. L.J. Zou, X. Xiao, C.H. Chu et al., Facile synthesis of porous CoFe2O4/graphene aerogel for catalyzing efficient removal of organic pollutants. Sci. Total Environ. (2021). https://doi.org/10.1016/J.SCITOTENV.2020.143398

    Article  PubMed  Google Scholar 

  20. Z.C. Chen, T.L. Chang, C.H. Chen et al., Flexible NO gas sensor fabricated using graphene/silver nanoparticles stacked electrode structures. Mater. Lett. (2021). https://doi.org/10.1016/J.MATLET

    Article  Google Scholar 

  21. C.R. Guo, Y.X. Li, Y.P. Zhu et al., Synthesis and characterization of free-stand graphene/silver nanowire/graphene nano composite as transparent conductive film with enhanced stiffness. Appl. Sci. (2020). https://doi.org/10.3390/app10144802

    Article  Google Scholar 

  22. W.X. Zhang, W. Song, J.M. Huang et al., Graphene:silver nanowire composite transparent electrode based flexible organic solar cells with 13.4% efficiency. J. Mater. Chem. A (2019). https://doi.org/10.1039/C9TA07493G

    Article  Google Scholar 

  23. G. Shi, T.Q. Liu, Z. Kopecki et al., A Multifunctional Wearable Device with a Graphene/Silver Nanowire Nanocomposite for Highly Sensitive Strain Sensing and Drug Delivery. C (2019). https://doi.org/10.3390/c5020017

    Article  Google Scholar 

  24. L.Z. Zheng, X.J. Su, X.J. Lai et al., Conductive super-hydrophobic cotton fabrics via layer-by-layer assembly of carbon nanotubes for oil-water separation and human motion detection[J]. Mater. Lett. 253, 230–233 (2019)

    Article  CAS  Google Scholar 

  25. X.F. Liao, H.Q. Li, X.J. Lai et al., Facile fabrication of super-hydrophobic conductive polydimethylsiloxane@silver nanowires cotton fabric via dipping-thermal curing method[J]. Mater. Lett. 255, 37–49 (2019)

    Article  Google Scholar 

  26. M. Ashraf, C. Campagne, A. Perwuelz, P. Champagne et al., Development of superhydrophilic and superhydrophobic polyester fabric by growing Zinc Oxide nanorods. J. Colloid Interface Sci. 255, 37–49 (2019)

    Google Scholar 

Download references

Acknowledgements

This work was financially supported by Shanghai Natural Science Foundation (Grant No. 21ZR426200); National Natural Science Foundation of China (Grant No. 51703123).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lihui Xu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, Y., Xu, L., Pan, H. et al. Preparation of super-hydrophobic cotton fabrics with conductive property based on graphene/Ag composite aerogels. J Porous Mater 29, 2019–2030 (2022). https://doi.org/10.1007/s10934-022-01311-4

Download citation

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-022-01311-4

Keywords

Navigation