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Variability of molecular sieve SAPO-11 crystals: acidity, texture, and morphology

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Abstract

A number of experiments on the synthesis of SAPO-11 crystals in different media (water; equimolar H2O/EtOH; low H2O/EtOH), using two methods of precursor mixing and various temperature regimes of hydrothermal treatment (HT) has been performed. It has turned out that one-stage HT at 200 °C had not provided SAPO-11 crystallization in low H2O/EtOH medium, only non-porous aluminum phosphates had been obtained, while a two-stage HT at 200 and 120 °C on the first and second stages, respectively, had allowed us to synthesize the AEL phase. Whereas equimolar water–ethanol synthesis medium has resulted in a mixture of both microporous and non-porous phases. The last one is apparently the result of the unusual properties of water–ethanol crystallization system. SAPO-11 samples which were obtained in different media have possessed “screw-like”, “tubular-like”, and “spindle-like” morphologies. SAPO-11 synthesized in the medium with the predominance of ethanol has had significant changes in physicochemical properties compared with ones obtained in water.

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Fig. 2

taken from open database http://www.crystallography.net

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Acknowledgements

The authors are grateful to Alekseeva N.A. (XRD patterns), Rudina N.A. (SEM images obtaining), Lysikov A.I. (TPD-NH3 measurements) and Leonova A.A. (texture measurements). This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011490008-3).

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011490008–3).

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  1. Boreskov Institute of Catalysis, Lavrentiev Ave. 5, Novosibirsk, 630090, Russia

    Irina A. Shamanaeva & Ekaterina V. Parkhomchuk

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Shamanaeva, I.A., Parkhomchuk, E.V. Variability of molecular sieve SAPO-11 crystals: acidity, texture, and morphology. J Porous Mater 29, 481–492 (2022). https://doi.org/10.1007/s10934-021-01177-y

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