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Silica aerogels; a review of synthesis, applications and fabrication of hybrid composites

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Abstract

Silica aerogels are gaining significant importance and have attracted considerable interest due to their extraordinary properties and numerous applications. Silica aerogels are highly porous with high surface area and very low density and thermal conductivity. Usually they are prepared and synthesized via sol-gel technique, which involves making a sol containing a precursor, a solvent and a catalyst. The properties possessed by the final product depend upon numerous factors such as ratio of precursor to solvent and the drying method employed. Due to the flexibility of synthesis methods and the production of aerogels with tailored properties, silica aerogels have found numerous commercial applications and are being investigated of their suitability in several areas, such biomedical and aerospace engineering. Despite having exceptional properties, silica aerogels come with drawbacks such as brittleness and low mechanical strength, which can be resolved by fabricating composites extending the potential applications. This paper reviews the synthesis of silica aerogels via sol-gel technique, and the applications where this extraordinary material has shown promising results. The different materials used for the fabrication of composites to improve and enhance the physical and chemical properties of silica aerogels are also presented.

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References

  1. O.R. Evans, W.E. Rhine, J.F. Nebo, J.R. Abeles, Jon C. 10, 233,303 (2020)

    Google Scholar 

  2. I. Smirnova, P. Gurikov, J. Supercrit. Fluids 134, 228 (2018)

    Article  CAS  Google Scholar 

  3. J.L. Gurav, I.K. Jung, H.H. Park, E.S. Kang, D.Y. Nadargi, J. Nanomater. 2010, (2010)

  4. S. Karamikamkar, H.E. Naguib, C.B. Park, Adv. Colloid Interface Sci. 276, 102101 (2020)

    Article  CAS  PubMed  Google Scholar 

  5. A. Soleimani Dorcheh, M.H. Abbasi, J. Mater. Process. Technol. 199, 10 (2008)

    Article  CAS  Google Scholar 

  6. R. Garrido, J.D. Silvestre, I. Flores-Colen, M. de F. Júlio, M. Pedroso, J. Non. Cryst. Solids 516, 26 (2019)

    Article  CAS  Google Scholar 

  7. Q. Feng, K. Chen, D. Ma, H. Lin, Z. Liu, S. Qin, Y. Luo, Colloids Surfaces A Physicochem. Eng. Asp. 539, 399 (2018)

    Article  CAS  Google Scholar 

  8. T.A. Esquivel-Castro, M.C. Ibarra-Alonso, J. Oliva, A. Martínez-Luévanos, Mater. Sci. Eng. C 96, 915 (2019)

    Article  CAS  Google Scholar 

  9. F.P. Soorbaghi, M. Isanejad, S. Salatin, M. Ghorbani, S. Jafari, H. Derakhshankhah, Biomed. Pharmacother. 111, 964 (2019)

    Article  CAS  PubMed  Google Scholar 

  10. S.P. Patil, P. Shendye, B. Markert, Scr. Mater. 177, 65 (2020)

    Article  CAS  Google Scholar 

  11. A. Venkateswara Rao, N.D. Hegde, H. Hirashima, J. Colloid Interface Sci. 305, 124 (2007)

    Article  CAS  PubMed  Google Scholar 

  12. G. Zu, J. Shen, X. Wei, X. Ni, Z. Zhang, J. Wang, G. Liu, J. Non. Cryst. Solids 357, 2903 (2011)

    Article  CAS  Google Scholar 

  13. M. Juzkow, Power Electron. 28, 58 (2002)

    Google Scholar 

  14. A. Lamy-Mendes, R.F. Silva, L. Durães, J. Mater. Chem. A 6, 1340 (2018)

    Article  CAS  Google Scholar 

  15. D. Wang, F. Zhang, J. Tang, Electrochemistry 83, 84 (2015)

    Article  CAS  Google Scholar 

  16. C.T. Wang, C.L. Wu, I.C. Chen, Y.H. Huang, Sensors Actuators, B Chem. 107, 402 (2005)

    Article  CAS  Google Scholar 

  17. S. Bag, P.N. Trikalitis, P.J. Chupas, G.S. Armatas, M.G. Kanatzidis, Science (80-.). 317, 490 (2007)

    Article  CAS  Google Scholar 

  18. Y. Kobayashi, T. Saito, A. Isogai, Angew. Chem. Int. Ed. Engl. 53, 10394 (2014)

    Article  CAS  PubMed  Google Scholar 

  19. N. Mittal, R. Kumar, G. Mishra, D. Deva, A. Sharma, Adv. Mater. Interfaces 3, 1 (2016)

    Article  Google Scholar 

  20. S. Azat, A.V. Korobeinyk, K. Moustakas, V.J. Inglezakis, J. Clean. Prod. 217, 352 (2019)

    Article  CAS  Google Scholar 

  21. K. Ebisike, A.E. Okoronkwo, K.K. Alaneme, J. King Saud Univ. - Sci. 32, 550 (2020)

    Article  Google Scholar 

  22. Z. Xu, L. Gan, Y. Jia, Z. Hao, M. Liu, L. Chen, J. Sol-Gel. Sci. Technol. 41, 203 (2007)

    Article  CAS  Google Scholar 

  23. A. Venkateswara Rao, S.D. Bhagat, H. Hirashima, G.M. Pajonk, J. Colloid Interface Sci. 300, 279 (2006)

    Article  PubMed  Google Scholar 

  24. Q. Wang, D.B. Mahadik, P. Meti, Y.D. Gong, K.Y. Lee, H.H. Park, Microporous Mesoporous Mater. 294, 109863 (2020)

    Article  CAS  Google Scholar 

  25. S.D. Bhagat, C.S. Oh, Y.H. Kim, Y.S. Ahn, J.G. Yeo, Microporous Mesoporous Mater. 100, 350 (2007)

    Article  CAS  Google Scholar 

  26. E.J. Zanto, S.A. Al-Muhtaseb, J.A. Ritter, Ind. Eng. Chem. Res. 41, 3151 (2002)

    Article  CAS  Google Scholar 

  27. R. Rodríguez-Dorado, C. López-Iglesias, C.A. García-González, G. Auriemma, R.P. Aquino, and P. Del Gaudio, Molecules 24, 4 (2019)

    Google Scholar 

  28. N. Buchtová, T. Budtova, Cellulose 23, 2585 (2016)

    Article  Google Scholar 

  29. G. Hayase, S. Nagayama, K. Nonomura, K. Kanamori, A. Maeno, H. Kaji, K. Nakanishi, J. Asian Ceram. Soc. 5, 104 (2017)

    Article  Google Scholar 

  30. A. Baimenov, D.A. Berillo, S.G. Poulopoulos, V.J. Inglezakis, Adv. Colloid Interface Sci. 276, 102088 (2020)

    Article  CAS  PubMed  Google Scholar 

  31. O. Okay, Polymeric Cryogels Macroporous Gels with Remarkable Properties (2014)

  32. Z.J. Rogers, S.A. Bencherif, Gels 5, 6 (2019)

    Article  Google Scholar 

  33. H. Maleki, L. Durães, A. Portugal, J. Non. Cryst. Solids 385, 55 (2014)

    Article  CAS  Google Scholar 

  34. I. Smirnova, P. Gurikov, Annu. Rev. Chem. Biomol. Eng. 8, 307 (2017)

    Article  PubMed  Google Scholar 

  35. J.E. Amonette, J. Matyáš, Microporous Mesoporous Mater. 250, 100 (2017)

    Article  CAS  Google Scholar 

  36. A. Ślosarczyk, Nanomaterials 7, (2017)

  37. K.Y. Lee, D.B. Mahadik, V.G. Parale, H.H. Park, J. Korean Ceram. Soc. 57, 1 (2020)

    Article  Google Scholar 

  38. W. Stöber, A. Fink, E. Bohn, J. Colloid Interface Sci. 26, 62 (1968)

    Article  Google Scholar 

  39. Y.J. Wong, L. Zhu, W.S. Teo, Y.W. Tan, Y. Yang, C. Wang, H. Chen, J. Am. Chem. Soc. 133, 11422 (2011)

    Article  CAS  PubMed  Google Scholar 

  40. M. Moner-Girona, A. Roig, E. Molins, J. Llibre, J. Sol-Gel. Sci. Technol. 26, 645 (2003)

    Article  CAS  Google Scholar 

  41. H. Cai, Y. Jiang, J. Feng, S. Zhang, F. Peng, Y. Xiao, L. Li, J. Feng, Mater. Des. 191, 108640 (2020)

    Article  CAS  Google Scholar 

  42. D.B. Mahadik, A.V. Rao, R. Kumar, S.V. Ingale, P.B. Wagh, S.C. Gupta, J. Porous Mater. 19, 87 (2012)

    Article  CAS  Google Scholar 

  43. K.E. Parmenter, F. Milstein, J. Non. Cryst. Solids 223, 179 (1998)

    Article  CAS  Google Scholar 

  44. C.J. Lee, G.S. Kim, S.H. Hyun, J. Mater. Sci. 37, 2237 (2002)

    Article  CAS  Google Scholar 

  45. N. Gupta, W. Ricci, J. Mater. Process. Technol. 198, 178 (2008)

    Article  CAS  Google Scholar 

  46. D. Ge, L. Yang, Y. Li, J.P. Zhao, J. Non. Cryst. Solids 355, 2610 (2009)

    Article  CAS  Google Scholar 

  47. C.Q. Hong, J.C. Han, X.H. Zhang, J.C. Du, Scr. Mater. 68, 599 (2013)

    Article  CAS  Google Scholar 

  48. R. Daoussi, S. Vessot, J. Andrieu, O. Monnier, Chem. Eng. Res. Des. 87, 899 (2009)

    Article  CAS  Google Scholar 

  49. R.M. Asmussen, J. Matyáš, N.P. Qafoku, A.A. Kruger, J. Hazard. Mater. 379, 119364 (2019)

    Article  CAS  PubMed  Google Scholar 

  50. P. Gerard, Aerogel Synthesis. Catalyst Preparation (CRC Press, Boca Raton, 2006)

    Google Scholar 

  51. S.D. Bhagat, Y.H. Kim, M.J. Moon, Y.S. Ahn, J.G. Yeo, Solid State Sci. 9, 628 (2007)

    Article  CAS  Google Scholar 

  52. M.A.B. Meador, E.F. Fabrizio, F. Ilhan, A. Dass, G. Zhang, P. Vassilaras, J.C. Johnston, N. Leventis, Chem. Mater. 17, 1085 (2005)

    Article  CAS  Google Scholar 

  53. P. Shajesh, S. Smitha, P.R. Aravind, K.G.K. Warrier, J. Sol-Gel. Sci. Technol. 50, 353 (2009)

    Article  CAS  Google Scholar 

  54. H. Maleki, N. Hüsing, Appl. Catal. B Environ. 221, 530 (2018)

    Article  CAS  Google Scholar 

  55. M.R. Kim, J.H. Oh, K.S. Oh, J.K. Lee, 10,197,211 (2019)

  56. A.M. Ibrahim, B.T. Chiad, W.A.A. Twej, R.A. Mohammed, Iraqi J. Sci. 60, 119 (2019)

    Google Scholar 

  57. M.Y. Nassar, I.S. Ahmed, M.A. Raya, J. Mol. Liq. 282, 251 (2019)

    Article  CAS  Google Scholar 

  58. S.D. Bhagat, A.V. Rao, Appl. Surf. Sci. 252, 4289 (2006)

    Article  CAS  Google Scholar 

  59. M. de F. Júlio, L.M. Ilharco, Materialia 9, 100527 (2020)

    Article  Google Scholar 

  60. D. Du, Y. Jiang, J. Feng, L. Li, J. Feng, Vacuum 173, 109117 (2020)

    Article  CAS  Google Scholar 

  61. S.D. Bhagat, Y.H. Kim, Y.S. Ahn, J.G. Yeo, Appl. Surf. Sci. 253, 3231 (2007)

    Article  CAS  Google Scholar 

  62. A. Venkateswara Rao, M.M. Kulkarni, G.M. Pajonk, D.P. Amalnerkar, T. Seth, J. Sol-Gel. Sci. Technol. 27, 103 (2003)

    Article  Google Scholar 

  63. I. De Marco, S. Miranda, S. Riemma, R. Iannone, Chem. Eng. Trans. 49, 319 (2016)

    Google Scholar 

  64. I. De Marco, S. Riemma, R. Iannone, J. Supercrit. Fluids 143, 305 (2019)

    Article  Google Scholar 

  65. M. Dowson, M. Grogan, T. Birks, D. Harrison, S. Craig, Appl. Energy 97, 396 (2012)

    Article  CAS  Google Scholar 

  66. I. Pinto, J.D. Silvestre, J. de Brito, M.F. Júlio, J. Clean. Prod. 252, (2020)

  67. Y. Pan, X. Cheng, T. zhou, L. Gong, H. Zhang, Mater. Lett. 229, 265 (2018)

    Article  CAS  Google Scholar 

  68. Y. Pan, S. He, L. Gong, X. Cheng, C. Li, Z. Li, Z. Liu, H. Zhang, Mater. Des. 113, 246 (2017)

    Article  CAS  Google Scholar 

  69. T. Zhou, X. Cheng, Y. Pan, C. Li, L. Gong, H. Zhang, Appl. Surf. Sci. 437, 321 (2018)

    Article  CAS  Google Scholar 

  70. F. He, X. He, W. Yang, X. Zhang, L. Zhou, J. Non. Cryst. Solids 488, 36 (2018)

    Article  CAS  Google Scholar 

  71. J. Zhu, J. Hu, C. Jiang, S. Liu, Y. Li, Carbohydr. Polym. 207, 246 (2019)

    Article  CAS  PubMed  Google Scholar 

  72. H. Tamon, H. Ishizaka, T. Yamamoto, T. Suzuki, Dry. Technol. 19, 313 (2001)

    Article  CAS  Google Scholar 

  73. P. Terzioğlu, S. Yücel, Ç Kuş, Asia-Pacific J. Chem. Eng. 14, 1 (2019)

    Article  Google Scholar 

  74. Y. Xu, N. Porter, J.L. Foster, J.P. Muir, P. Schwab, B.L. Burson, R.W. Jessup, Agronomy 10, 1 (2020)

    Google Scholar 

  75. J.A. Adebisi, J.O. Agunsoye, S.A. Bello, M. Haris, M.M. Ramakokovhu, M.O. Daramola, S.B. Hassan, Part. Sci. Technol. 38, 667 (2020)

    Article  CAS  Google Scholar 

  76. S. Azat, E. Arkhangelsky, T. Papathanasiou, A.A. Zorpas, A. Abirov, V.J. Inglezakis, Comptes Rendus Chim. 23, 77 (2020)

    Article  CAS  Google Scholar 

  77. H. Nguyen, M.Jamali Moghadam, H. Moayedi, J. Mater. Cycles Waste Manag. 21, 1039 (2019)

    Article  CAS  Google Scholar 

  78. J. Choi, D.J. Suh, Catal. Surv. from Asia 11, 123 (2007)

    Article  CAS  Google Scholar 

  79. L. Casas, A. Roig, E. Rodríguez, E. Molins, J. Tejada, J. Sort, J. Non. Cryst. Solids 285, 37 (2001)

    Article  CAS  Google Scholar 

  80. Y.K. Li, D.K. Yang, Y.C. Chen, H.J. Su, J.C. Wu, and Y. W. Chen-Yang, Acta Biomater. 6, 1462 (2010)

  81. M. Koebel, A. Rigacci, P. Achard, J. Sol-Gel. Sci. Technol. 63, 315 (2012)

    Article  CAS  Google Scholar 

  82. A.J. Hunt, C.A. Jantzen, W. Cao, in ASTM Spec. Tech. Publ., edited by R. S. Graves and D. C. Wysocki (ASTM International, West Conshohocken, PA, 1991), pp. 455–463

  83. N. Saad, M. Chaaban, D. Patra, A. Ghanem, H. El-Rassy, Microporous Mesoporous Mater. 292, 109759 (2020)

    Article  CAS  Google Scholar 

  84. M. Nuckols, J. Henkener, J. Chao, C. Shaffer, M. Swiergosz, Proc. Int. Conf. Offshore Mech. Arct. Eng. - OMAE 2006, (2006)

  85. G. Mishra, N. Mittal, A. Sharma, ACS Appl. Mater. Interfaces 9, 19371 (2017)

    Article  CAS  PubMed  Google Scholar 

  86. N. Mittal, D. Deva, R. Kumar, A. Sharma, Carbon N. Y. 93, 492 (2015)

    Article  CAS  Google Scholar 

  87. M.F. Bertino, J.F. Hund, G. Zhang, C. Sotiriou-Leventis, A.T. Tokuhiro, N. Leventis, J. Sol-Gel. Sci. Technol. 30, 43 (2004)

    Article  CAS  Google Scholar 

  88. H. Ren, L. Zhang, Colloids Surfaces A Physicochem. Eng. Asp. 372, 98 (2010)

    Article  CAS  Google Scholar 

  89. M.A.B. Meador, S.L. Vivod, L. McCorkle, D. Quade, R.M. Sullivan, L.J. Ghosn, N. Clark, L.A. Capadona, J. Mater. Chem. 18, 1843 (2008)

    Article  CAS  Google Scholar 

  90. H. Wu, Y. Chen, Q. Chen, Y. Ding, X. Zhou, H. Gao, J. Nanomater. 2013, (2013)

  91. Y. Liao, H. Wu, Y. Ding, S. Yin, M. Wang, A. Cao, J. Sol-Gel. Sci. Technol. 63, 445 (2012)

    Article  CAS  Google Scholar 

  92. B. Yuan, S. Ding, D. Wang, G. Wang, H. Li, Mater. Lett. 75, 204 (2012)

    Article  CAS  Google Scholar 

  93. X. Yang, Y. Sun, D. Shi, J. Liu, Mater. Sci. Eng. A 528, 4830 (2011)

    Article  Google Scholar 

  94. J.L. Mohanan, S.L. Brock, Chem. Mater. 15, 2567 (2003)

    Article  CAS  Google Scholar 

  95. G. Guzel Kaya, E. Yilmaz, H. Deveci, Adv. Powder Technol. 31, 926 (2020)

    Article  CAS  Google Scholar 

  96. H. Rocha, U. Lafont, C. Semprimoschnig, Acta Astronaut. 165, 9 (2019)

    Article  CAS  Google Scholar 

  97. W. Gonçalves, J. Morthomas, P. Chantrenne, M. Perez, G. Foray, C.L. Martin, Acta Mater. 145, 165 (2018)

    Article  Google Scholar 

  98. S.P. Patil, V.G. Parale, H.H. Park, B. Markert, Mater. Sci. Eng. A 742, 344 (2019)

    Article  CAS  Google Scholar 

  99. S.P. Patil, A. Rege, M. Itskov, B. Markert, J. Non. Cryst. Solids 498, 125 (2018)

    Article  CAS  Google Scholar 

  100. L.D. Gelb, J. Phys. Chem. C 111, 15792 (2007)

    Article  CAS  Google Scholar 

  101. S.P. Patil, A. Rege, M. Sagardas, Itskov, B. Markert, J. Phys. Chem. B 121, 5660 (2017)

    Article  CAS  PubMed  Google Scholar 

  102. S.P. Patil, Molecules 24, (2019)

  103. Z. Talebi, P. Soltani, N. Habibi, F. Latifi, Constr. Build. Mater. 220, 76 (2019)

    Article  CAS  Google Scholar 

  104. “business innovation observatory Aerogels, getting their second wind - Google Search.” https://www.google.com/search?q=business+innovation+observatory+Aerogels%2 C+getting+their+second+wind&oq=business+innovation+observatory+Aerogels%2 C+getting+their+second+wind&aqs=chrome.69i57j69i60.300j0j7&sourceid=chrome&ie=UTF-8 (accessed Apr. 13, 2021).

  105. “Aerogels 2021–2031: Technologies, Markets and Players: IDTechEx.” https://www.idtechex.com/en/research-report/aerogels-2021-2031-technologies-markets-and-players/801 (accessed Apr. 13, 2021).

  106. E. Strobach, B. Bhatia, S. Yang, L. Zhao, E.N. Wang, J. Non. Cryst. Solids 462, 72 (2017)

    Article  CAS  Google Scholar 

  107. “Making a remarkable material even better | MIT Energy Initiative.” https://energy.mit.edu/news/making-a-remarkable-material-even-better/ (accessed Apr. 13, 2021).

  108. S. Zhao, G. Siqueira, S. Drdova, D. Norris, C. Ubert, A. Bonnin, S. Galmarini, M. Ganobjak, Z. Pan, S. Brunner, G. Nyström, J. Wang, M.M. Koebel, W.J. Malfait, Nature 584, 387 (2020)

    Article  CAS  PubMed  Google Scholar 

  109. A.R.A. Talib, M.I.N. Bheekhun, Struct. Heal. Monit. Biocomposites, Fibre-Reinforced Compos. Hybrid Compos (Elsevier, 2018), pp. 191–225

  110. C.A. García-González, T. Budtova, L. Durães, C. Erkey, P. Del Gaudio, P. Gurikov, M. Koebel, F. Liebner, M. Neagu, I. Smirnova, Molecules 24, (2019)

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Conceptualization, F.A. and S.A.S.; methodology, F.A. and V.J.I; investigation, F.A.; resources, S.A.S. and M.S.; writing—original draft preparation, F.A.; writing—review and editing, V.J.I.; supervision, S.A.S. and M.S; project administration, V.J.I; funding acquisition, V.J.I. All authors have read and agreed to the published version of the manuscript.

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Akhter, F., Soomro, S.A. & Inglezakis, V.J. Silica aerogels; a review of synthesis, applications and fabrication of hybrid composites. J Porous Mater 28, 1387–1400 (2021). https://doi.org/10.1007/s10934-021-01091-3

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