Synthesis of nanoporous carbons/metal nanoparticles composite through direct carbonization of a MOF for catalytic reduction of 4-nitrophenol

Abstract

A facile and effective synthetic route has been utilized to synthesize nanoporous carbons (NPCs)/cobalt nanoparticles (CoNPs) composites by direct carbonization of a Co-MOF. The combination of various spectroscopic tools demonstrated that the CoNPs (about 5 nm in diameter) in the resultant composites were evenly installed in the carbon matrix without any aggregations. Furthermore, the size of the CoNPs can be easily controlled by adjusting the temperature of the hydrothermal treatment. Results of UV–Visible spectrophotometer demonstrated the significant effects of the obtained structure on the reduction of the targeted pollutant 4-nitrophenol (4-NP). The high reaction activity catalysed by CoNPs with the presence of sodium borohydride is attributed to nanostructure advantage and the high surface area.

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References

  1. 1.

    M. Khalil, B.M. Jan, C.W. Tong, M.A. Berawi, Appl. Energy 191, 287 (2017)

    CAS  Article  Google Scholar 

  2. 2.

    S.B. Kalidindi, B.R. Jagirdar, ChemSusChem 5, 65 (2012)

    CAS  Article  Google Scholar 

  3. 3.

    S.L. Li, H. Li, J. Liu, H.L. Zhang, Y.M. Yang, Z.Y. Yang, L.Y. Wang et al., Dalton Trans. 44, 9193 (2015)

    CAS  Article  Google Scholar 

  4. 4.

    M.S. Bashir, X.B. Jiang, X.Z. Kong, Eur. Polym. J. 129, 109652 (2020)

    CAS  Article  Google Scholar 

  5. 5.

    A. Li, X.X. Chang, Z.Q. Huang, C.C. Li, Y.J. Wei, L. Zhang, T. Wang, J.L. Gong, Angew. Chem. Int. Ed. 55, 13734 (2016)

    CAS  Article  Google Scholar 

  6. 6.

    J.Y. Liu, D. Wang, J.F. Chen, Y. Zhang, Int. J. Hydrog. Energy 41, 21965 (2016)

    CAS  Article  Google Scholar 

  7. 7.

    J.Y. Liu, J.F. Chen, Y. Zhang, Catal. Sci. Technol. 3, 2559 (2013)

    CAS  Article  Google Scholar 

  8. 8.

    J.Y. Liu, J.F. Chen, Y. Zhang, RSC Adv. 5, 62931 (2015)

    CAS  Article  Google Scholar 

  9. 9.

    S.C. Tang, S. Vongehr, X.K. Meng, J. Phys. Chem. C 114, 977 (2010)

    CAS  Article  Google Scholar 

  10. 10.

    P. Zhang, C.L. Shao, Z.Y. Zhang, M.Y. Zhang, J.B. Mu, Z.C. Guo, Y.C. Liu, Nanoscale 3, 3357 (2011)

    CAS  Article  Google Scholar 

  11. 11.

    M.Y. Zhu, C.J. Wang, D.H. Meng, G.W. Diao, J. Mater. Chem. A 1, 2118 (2013)

    CAS  Article  Google Scholar 

  12. 12.

    A. Halder, S. Patra, B. Viswanath, N. Munichandraiah, N. Ravishankar, Nanoscale 3, 725 (2011)

    CAS  Article  Google Scholar 

  13. 13.

    D. Xu, D.L. Zhang, H.B. Zou, L.K. Zhu, M. Xue, Q.R. Fang, S.L. Qiu, Chem. Commun. 52, 10513 (2016)

    CAS  Article  Google Scholar 

  14. 14.

    Y.H. Deng, Y. Cai, Z.K. Sun, J. Liu, C. Liu, J. Wei, W. Li, C. Liu, Y. Wang, D.Y. Zhao, J. Am. Chem. Soc. 132, 8466 (2010)

    CAS  Article  Google Scholar 

  15. 15.

    K. Jiang, H.X. Zhang, Y.Y. Yang, R. Mothes, H. Lang, W.B. Cai, Chem. Commun. 47, 11924 (2011)

    CAS  Article  Google Scholar 

  16. 16.

    S.H. Zhang, S.L. Gai, F. He, Y.L. Dai, P. Gao, L. Li, Y.J. Chen, P.P. Yang, Nanoscale 6, 7025 (2014)

    CAS  Article  Google Scholar 

  17. 17.

    A.J. Wang, H.Y. Cheng, B. Liang, N.Q. Ren, D. Cui, N. Lin, B.H. Kim, K. Rabaey, Environ. Sci. Technol. 45, 10186 (2011)

    CAS  Article  Google Scholar 

  18. 18.

    A. Mondal, A. Mondal, B. Adhikary, D.K. Mukherjee, Bull. Mater. Sci. 40, 321 (2017)

    CAS  Article  Google Scholar 

  19. 19.

    J. Krajczewski, K. Kołątaj, A. Kudelski, Appl. Surf. Sci. 388, 624 (2016)

    CAS  Article  Google Scholar 

Download references

Acknowledgements

This research was financially supported by Three-level talent project in Zhuhai College of Jilin University (Grant No. E201804), the project of Guangdong province innovation strong school young innovative talents (Grant No. 2019KQNCX199).

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Correspondence to Jianhui Zhang.

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Zhang, J., Chen, J., Cheng, L. et al. Synthesis of nanoporous carbons/metal nanoparticles composite through direct carbonization of a MOF for catalytic reduction of 4-nitrophenol. J Porous Mater (2021). https://doi.org/10.1007/s10934-021-01053-9

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Keywords

  • Nanocomposites
  • Catalytic
  • Co-MOF
  • 4-Nitrophenol