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Construction of rigid ionic porous organic polymers (iPOPs) via Zincke reaction with tunable absorption behaviors

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Abstract

Two rigid ionic porous organic polymers (iPOPs-1 and iPOPs-2) were fabricated via the well-known Zincke reaction. Starting from different monomers which bring the different bridging structures, the porosity and dye-removal capacities of two polymers can be handled readily. Both polymers exhibited excellent capacity for dye-removal (e.g., 1823.1 mg g−1 of iPOPs-1 and 1247 mg g−1 of iPOPs-2 for methyl orange), which are the highest among all reported iPOPs. Interestingly, iPOPs-1 absorbed solely methyl orange (MO) in the mixtures of MO and methyl blue (MB), and as a contrast, iPOPs-2 showed the full adsorption of MO/MB dyes indicating the apparent size effect. Furthermore, by using a gentle washing program, they can be recycled and reused at least five times without significantly reducing performance. This research thereby provides a new strategy and insight to rationally tune the porous properties and the following adsorption capacity of iPOPs.

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Acknowledgement

We are grateful for financial support from the National Natural Science Foundation of China [No.21206016 for W.T.Gong, No.U1808210 for G.L.Ning], the Fundamental Research Funds for the Central Universities [DUT-17LK07] and the Natural Science Foundation of Liaoning province [2019-MS-046].

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  1. Weidong Qu and Shuguang Zhang have contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, People’s Republic of China

    Weidong Qu, Shuguang Zhang, Kaixun Dong, Xiaorong Deng, Weitao Gong & Guiling Ning

  2. Engineering Laboratory of Boric and Magnesic Functional Material Preparative and Applied Technology, Liaoning Province, Dalian, 116024, People’s Republic of China

    Weitao Gong & Guiling Ning

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  1. Weidong Qu
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  2. Shuguang Zhang
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  3. Kaixun Dong
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  4. Xiaorong Deng
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  5. Weitao Gong
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Correspondence to Weitao Gong or Guiling Ning.

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Qu, W., Zhang, S., Dong, K. et al. Construction of rigid ionic porous organic polymers (iPOPs) via Zincke reaction with tunable absorption behaviors. J Porous Mater 28, 507–514 (2021). https://doi.org/10.1007/s10934-020-01017-5

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