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Application of copper iodide nanoparticles immobolized porous polysulfonamide gel as an effective nanocatalyst for synthesis of aminoindolizines

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Abstract

In this paper, we investigate the catalytic activity of CuI NPs supported on porous cross-linked poly(ethyleneamine)–polysulfonamide (PEA–PSA@CuI) as an effective and recyclable nanocatalyst for the synthesis of indolizine derivatives. Three-component reaction of 2-pyridine carbaldehyde with phenylacetylene and second-order amines in the presence of PEA–PSA@CuI as catalyst under solvent-free conditions resulted amino indolizine products in good to excellent yields. The present catalytic system offers advantages such as high catalytic activity in short reaction time, recovered the catalyst by centrifugation and recycled for five times without significant loss in its efficiency.

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Acknowledgements

The authors wish to thank Bu-Ali Sina University, Center of Excellence Developmental of Environmentally Friendly Methods for Chemical Synthesis (CEDEFMCS) for financial support to carry out this research.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 65174, Iran

    Sepideh Solgi, Ramin Ghorbani-Vaghei & Sedigheh Alavinia

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  1. Sepideh Solgi
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  2. Ramin Ghorbani-Vaghei
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  3. Sedigheh Alavinia
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Correspondence to Ramin Ghorbani-Vaghei.

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Solgi, S., Ghorbani-Vaghei, R. & Alavinia, S. Application of copper iodide nanoparticles immobolized porous polysulfonamide gel as an effective nanocatalyst for synthesis of aminoindolizines. J Porous Mater 28, 289–298 (2021). https://doi.org/10.1007/s10934-020-00989-8

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