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The effect of mesoporous support on the catalytic performance of Pd nanoparticles in the hydrogenation of cyclopentene

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Abstract

Here, a comparison between four mesoporous siliceous compounds is conducted to investigate the effect of support on formation and catalytic behavior of palladium (Pd) nanoparticles. The four investigated supports are: the commercially available MCM-41, SBA-15 and MCM-48, in addition to the home-made TUD-1 material. The same amount of Pd (Si/Pd = 200) was impregnated in the four mesoporous samples by using water as a solvent, and no further activation/reduction was performed. The obtained characterization data showed that SBA-15 accommodated the maximum amount of PdO nanoparticles that located inside its channels, while the maximum surface area after impregnation was obtained in MCM-48 sample. The four Pd samples was used to catalyze the solvent-free reduction of cyclopentene at room temperature by using 1 atm of hydrogen gas. Pd-TUD-1 exhibited the maximum activity with a total TOF of 4.83 s−1, while the TOF of SBA-15 was 2.28 s−1. The activity results clearly show the effect of the open three dimensional structure of TUD-1 in offering the maximum accessibility to and from Pd nanoparticles’ active sites.

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Acknowledgements

The authors are acknowledged the Deanship of Scientific Research at King Khalid University for funding this work through research group program under Grant Number R.G.P.1/115/40. AA, SA and MR extend their appreciation to the Deanship of Scientific Research at King Saud University for funding this work through Research Group, No. RG-1436-005.

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Authors and Affiliations

  1. Catalysis Research group (CRG), Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, 61413, Abha, Saudi Arabia

    Mhamed Benaissa, Abdullah M. Alhanash, Murad Eissa & Mohamed S. Hamdy

  2. Chemical Engineering Department, College of Engineering, University of Hail, P.O. Box 2440, Hail, Saudi Arabia

    Mhamed Benaissa

  3. King Abdullah Institute for Nanotechnology, King Saud University, 11451, Riyadh, Saudi Arabia

    Ali Aldalbahi & Shaykha Alzahly

  4. Department of Chemistry, College of Science, King Saud University, 11451, Riyadh, Saudi Arabia

    Ali Aldalbahi, Mostafizur Rahaman & Govindasami Periyasami

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  1. Mhamed Benaissa
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  2. Abdullah M. Alhanash
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  3. Murad Eissa
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  4. Ali Aldalbahi
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  7. Govindasami Periyasami
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  8. Mohamed S. Hamdy
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Correspondence to Mohamed S. Hamdy.

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Benaissa, M., Alhanash, A.M., Eissa, M. et al. The effect of mesoporous support on the catalytic performance of Pd nanoparticles in the hydrogenation of cyclopentene. J Porous Mater 27, 1735–1743 (2020). https://doi.org/10.1007/s10934-020-00949-2

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