Skip to main content
SpringerLink
Log in

Binary cationic-anionic surfactant templated synthesis of organic functionalized porous silica nanomaterials

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

In this study, vinyl-functionalized porous silica (V-P-SiO2) and ureido-functionalized porous silica (UD-P-SiO2) have been synthesized separately by using hexadecyl trimethyl ammonium bromide (CTAB) and sodium dodecyl sulfonate (SDS) as mixed templates. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectrum (FTIR) and N2 adsorption–desorption measurement. The results showed that UD-P-SiO2 with a diversity of morphologies were obtained by judiciously chosen mole ratio of SDS to CTAB (R = nSDS:nCTAB). On the contrast, the mole ratio of surfactants had less effect on the morphologies of V-P-SiO2 until the mole ratio of SDS to CTAB was reached 1.6, however, FTIR proved that it had effect on the vinyl groups in the V-P-SiO2 network framework.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. J.S. Beck, J.C. Vartuli, W.G. Roth, M.E. Leonowicz, C.T. Kresge, K.D.D.K. Schmitt, C.T-W. Chu , D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J. L. Schlenker, J. Am. Chem. Soc., 114, 10834–10843, (1992)

    Article  CAS  Google Scholar 

  2. C.T. Kresge, M.E. Leonowicz, W.G. Roth, J.C. Vartuli, J.S. Beck, Nature 359, 710–712 (1992)

    Article  CAS  Google Scholar 

  3. X.F. Song, L. Gao, J. Phys. Chem. C 111, 8180–8187 (2007)

    Article  CAS  Google Scholar 

  4. F.P. Dong, W.P. Guo, S.K. Park, C.S. Ha, Chem. Commun. 48, 1108–1110 (2012)

    Article  CAS  Google Scholar 

  5. S. Duan, X. Zhang, S. Xu, C.L. Zhou, Electrochim. Acta 88, 885–891 (2013)

    Article  CAS  Google Scholar 

  6. C.O. Areana, M.J. Vesgaa, J.B. Parrab, M.R. Delgado, Ceram. Int. 39, 7407–7414 (2013)

    Article  Google Scholar 

  7. F. Hoffmann, M. Cornelius, J. Morell, M. FrÖba, Angew. Chem. Int. Ed. 45, 3216–3251 (2006)

    Article  CAS  Google Scholar 

  8. F. Zhu, Y.J. Liang, L.Y. Xia, M.Z. Rong, C.Y. Su, R. Lai, R.Y. Li, G.F. Ouyang, J. Chromatogr. A 1247, 42–48 (2012)

    Article  CAS  Google Scholar 

  9. E.M. Usai, M.F. Sini, D. Meloni, V. Solinas, A. Salis, Microporous Mesoporous Mater. 179, 54–62 (2013)

    Article  CAS  Google Scholar 

  10. B.J. Dou, Q. Hu, J.J. Li, S.Z. Qiao, Z.P. Hao, J. Hazard. Mater. 186, 1615–1624 (2011)

    Article  CAS  Google Scholar 

  11. R. Hashimoto, M. Ogawa, J. Porous Mater. 25, 425–431 (2018)

    Article  CAS  Google Scholar 

  12. J.L. Li, B. Hu, J.J. Tan, J.Z. Zhuang, Transiti. Met. Chem. 38, 495–501 (2013)

    Article  CAS  Google Scholar 

  13. D.S. Karaman, T. Gulin-Sarfraz, J.X. Zhang, J.M. Rosenholm, Mater. Lett. 143, 140–143 (2015)

    Article  Google Scholar 

  14. L. Zhang, S.B. Wu, C. Li, Q.H. Yang, Chem. Commun. 48, 4190–4192 (2012)

    Article  CAS  Google Scholar 

  15. Y. Yang, J. Liu, X.B. Li, X. Liu, Q.H. Yang, Chem. Mater. 23, 3676–3684 (2011)

    Article  CAS  Google Scholar 

  16. Y.D. Xia, R.M. Oakaya, J. Phys. Chem. B, 110, 3889–3894, (2006)

    Article  Google Scholar 

  17. K.J. Shea, D.A.O. St Websterl, J. Am. Chem. Soc., 110, 6700–6710, (1992)

    Article  CAS  Google Scholar 

  18. X.Y. Wang, Q. Kang, D.Z. Shen, Z. Zhang, J.H. Li, L.X. Chen, Talanta, 124, 7–13, (2014)

    Article  CAS  Google Scholar 

  19. T.S. Deng, F. Marlow, Chem. Mater. 24, 536–542 (2012)

    Article  CAS  Google Scholar 

  20. J. Li, L.X. Chen, X. Li, C.C. Chao, F.L. Zeng, Appl. Surf. Sci., 340, 126–131, (2015)

    Article  CAS  Google Scholar 

  21. R.L. Wang, Y.M. Zhu, X.M. Zhang, H.W. Ji, L. Li, H.Y. Ge, J. Colloid Interface Sci. 407, 128–132 (2013)

    Article  CAS  Google Scholar 

  22. W.Q. Jiao, M.B. Yue, Y.M. Wang, M.Y. He, J. Porous Mater. 19, 61–70 (2012)

    Article  CAS  Google Scholar 

  23. J.J. Wang, J.M. Lu, J.H. Yang, W. Xiao, J.Q. Wang, Mater Lett 78, 199–201 (2012)

    Article  CAS  Google Scholar 

  24. Y.H. Ma, L. Xing, H.Q. Zheng, S.A. Che, Langmuir 27, 517–520 (2011)

    Article  CAS  Google Scholar 

  25. M.T. Yatcilla, K.L. Herrington, L.L. Brasher, J. Phys. Chem. 100, 5874–5879 (1996)

    Article  CAS  Google Scholar 

  26. E.W. Kaler, A.K. Murthy, B.E. Rodriguez, J.A. Zasadzinski, Science 22, 1371–1374 (1989)

    Article  Google Scholar 

  27. I.I. Yaacob, A. Bose, J. Colloid Interface Sci. 178, 638–647 (1996)

    Article  CAS  Google Scholar 

  28. J.C. Hao, H. Hoffmann, Curr. Opin. Colloid Interface Sci. 9, 279–293 (2004)

    Article  CAS  Google Scholar 

  29. M.J. Rosen, X.Y. Hua, J. Am. Oil Chem. Soc. 59, 582–585 (1982)

    Article  CAS  Google Scholar 

  30. H.T. Pu, X. Zhang, J.J. Yuan, Z.L. Yang 331, 389–393 (2009)

    CAS  Google Scholar 

  31. Q. Wei, H.Q. Chen, Z.R. Nie, Y.L. Wang, Q.Y. Li, J.X. Zou, Mater. Lett. 61, 1469–1473 (2007)

    Article  CAS  Google Scholar 

  32. L.M. Wei, D.W. Shi, Z.H. Zhou, P.Y. Ye, J. Wang, J. Zhao, L.Y. Liu, C.X. Chen, Y.F. Zhang, Nanoscale Res. Lett. 7, 334–342 (2012)

    Article  Google Scholar 

  33. J. Li, L.X. Chen, X. Li, C.C. Zhang, Y. Jiang, New J. Chem., 39, 287–294, (2015)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the support of this research by Natural Science Foundation of Hubei Province (CN) (Grant No. 2017CFB296) and Research Fund for Doctoral Program of Wu Chang Institute of Technology (CN) (Grant No. 2017BSJ04).

Author information

Authors and Affiliations

  1. School of Food and Environmental Engineering, Wu Chang Institute of Technology, Wuhan, 430065, People’s Republic of China

    Jie Li, Zhuoqiong Wen, Jie Luo & Cui Yu

  2. School of Food and Pharmaceutical Engineering, Light Industry Division, Hubei University of Technology, Wuhan, 430068, People’s Republic of China

    Jia zhang

  3. School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan, 430070, People’s Republic of China

    Lianxi Chen & Pengpeng Wang

Authors
  1. Jie Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jia zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lianxi Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhuoqiong Wen
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jie Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Cui Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Pengpeng Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jie Li.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, J., zhang, J., Chen, L. et al. Binary cationic-anionic surfactant templated synthesis of organic functionalized porous silica nanomaterials. J Porous Mater 27, 29–35 (2020). https://doi.org/10.1007/s10934-019-00787-x

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-019-00787-x

Keywords

Search

Navigation