This study covered preparation, characterization and application of novel NiGa/MSO catalyst. The catalyst was prepared by impregnation method using precursors such as nitrates of nickel and gallium and support as mesoporous silica (mesosilica, MSO). Ordered mesoporous structure of the mesosilica support provided the catalyst with high dispersion of active sites and good thermal stability. Conversion of CO2 to methanol was also investigated to find suitable temperature and pressure for the process. Especially, oxidation state of active sites and catalyst element composition were also determined and calculated. Characterizations including XRD, TEM, TG-DSC-MS and XPS were used in the study. GC coupled with TCD and FID detectors were applied to determine the chemical composition of gas product.
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A. George, G.K. Olah, G. Alain, S. Prakash, Beyond oil and gas: the methanol economy, Wiley, New York, ISBN 978-3-527-32422-4 (2009)
B. Cong Liu, E.C. Yang, S. Tyo, J. Seifert, B. DeBartolo, P. von Issendorff, S. Zapol, L.A. Vajda, Curtiss, Carbon dioxide conversion to methanol over size-selected Cu4 clus-ters at low pressures. J. Am. Chem. Soc. 137(27), 8676–8679 (2015)
G. Suhas, P.D. Jadhav, B.M. Vaidya, B. Bhanage, J. Joshi, Catalytic carbon dioxide hydrogenation to methanol: a review of recent studies. Chem. Eng. Res. Des. 92(11), 2557–2567 (2014)
J.G. Wu, M. Saito, M. Takeuchi, T. Watanabe, The stability of Cu/ZnO-based catalysts in methanol synthesis from a CO2-rich feed and from a CO-rich feed. Appl. Catal. A Gen 218, 235–240 (2001)
J. Ma, N. Sun, X. Zhang, N. Zhao, F. Xiao, W. Wei, Y. Sun, A short review of catalysis for CO2 conversion. Catal. Today 148, 221–231 (2009)
W.J. Shen, M. Okumura, Y. Matsumura, M. Haruta, The influence of the support on the activity and selectivity of Pd in CO hydrogenation. Appl. Catal. A Gen. 213, 225–232 (2001)
C.H. Kim, J.S. Lee, D.L. Trimm, The preparation and characterisation of Pd–ZnO catalysts for methanol synthesis. Top. Catal. 22, 319–324 (2003)
X.L. Liang, X. Dong, G.D. Lin, H.B. Zhang, Carbon nanotube-supported Pd–ZnO catalyst for hydrogenation of CO2 to methanol. Appl. Catal. B Environ. 88, 315–322 (2009)
N. Iwasa, H. Suzuki, M. Terashita, M. Arai, N. Takezawa, Methanol synthesis from CO2 under atmospheric pressure over supported Pd catalysts. Catal. Lett. 96, 75–78 (2004)
I. Sharafutdinov, D. Gardini, G.L. Chiarello, C.F. Elkjær, H.W. Pereira de Carvalho, C.D. Damsgaard, J.B. Wagner, J.-D. Grunwaldt, S. Dahl, I. Chorkendorff, J. Catal. 320, 77–88 (2014)
Ibram, Ganesh, Conversion of carbon dioxide into methanol—a potential liquid fuel: fundamental challenges and opportunities (a review). Renew. Sustain. Energy Rev. 31, 221–257 (2014)
W. Wang, S. Wang, X. Ma, J. Gong, Recent advances in catalytic hydrogenation of carbon dioxide. Chem. Soc. Rev. 40, 3703–3727 (2011)
K.D. Hong, T.D. Nguyen, Preparation of meso-structured silica–calcium mixed oxide (MSCMO) catalyst for converting Vietnamese rubber seed oil to biodiesel. J. Porous Mater. 24(2), 443–454 (2017)
K.D. Hong, P.V. Nguyen, D. Pham, A. Vo, Preparation, characterization and thermal stability improvement of mesoporous sulfated zirconia for converting deodorizer distillate to methyl esters. J. Porous Mater. 24(2), 411–419 (2017)
H.K.D. Nguyen, H. Van Nguyen, D.S. Dao, L.L. Hoang, Preparation and characterization of ordered mesoporous Mg–Al–Co hydrotalcite based catalyst for decarboxylation of jatropha oil. J. Porous Mater. 24(3), 731–740 (2017)
I. Felix Studt, F. Sharafutdinov, C.F. Abild-Pedersen, S. Elkjær, K. Nørskov, S. Dahl, C. Jens. Nat. Chem. 6, 320–324 (2014)
This work was financially supported by the National Foundation for Science and Technology Development, Vietnam (NAFOSTED) under Grant Number 104.05-2017.21.
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Nguyen, H.K.D., Dang, T.H. Conversion of CO2 to methanol using NiGa/mesosilica (NiGa/MSO) catalyst. J Porous Mater 26, 1297–1304 (2019). https://doi.org/10.1007/s10934-019-00730-0
- Methanol production
- Carbon dioxide reduction