Abstract
Highly crystalline gmelinite (GME) zeolites with Si/Al ratio of ~ 3 were successfully synthesized from FAU zeolites as the starting silica/alumina source using the dual-template method with a mixture of tetraethylphosphonium and N,N-dimethyl-3,5-dimethylpiepridinium cations as an organic structure-directing agent (OSDA). It was also found that the prepared GME zeolite exhibited high porosity when the as-made GME zeolite was K+ ion-exchanged and then calcined at 580 °C at 6 h to remove OSDAs in the zeolitic pores.
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This work was partially supported by a Grant-in-Aid for Scientific Research (B) (Grant Number 16H04218) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan (MEXT).
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Mitani, E., Tsunoji, N., Sadakane, M. et al. Synthesis of GME zeolite with high porosity by hydrothermal conversion of FAU zeolite using a dual-template method with tetraethylphosphonium and N,N-dimethyl-3,5-dimethylpiepridinium hydroxides. J Porous Mater 26, 1345–1352 (2019). https://doi.org/10.1007/s10934-019-00725-x
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DOI: https://doi.org/10.1007/s10934-019-00725-x