Skip to main content
SpringerLink
Log in

Liquid phase oxidation of cyclohexane over mesoporous cobalt silicates molecular sieves synthesized in strong acidic media by assembly of preformed CoS-1 precursors with triblock copolymer

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

Cobalt–incorporated mesoporous silica materials [MCoS(n), n = Si/Co = 20; 60] have been successfully prepared in strong acidic media by assembly of preformed CoS-1 precursors with triblock copolymer of the Pluronic type (P123) by a two steps procedure. They were characterized by various techniques including XRD, BET, FT-IR spectroscopy and diffuse reflectance UV–Vis (DRUV–Vis). The results show that the calcined MCoS materials contain Co(II) ions in tetrahedral environments under low and high Co content and the mesoporous walls contain the MFI structure building units. Liquid phase oxidation of cyclohexane using TBHP as oxidant was investigated on MCoS(n). The major products detected are cyclohexanone and cyclohexanol in all cases. The MCoS(n) catalysts are more active when water free TBHP was used and the conversion of cyclohexane increases when cyclohexane to TBHP molar ratio increases from 1:1 to 1:2, while the cyclohexanol selectivity decreases, which is ascribed to a further oxidation of cyclohexanol to cyclohexanone. The catalytic activity of MCoS(n) materials is enhanced as the cobalt content increases. It is worth noting that MCoS(20)is more active than Co-SBA15(20). The most active catalyst MCoS(20) acts as truly heterogeneous catalyst and was very stable after four runs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. J.M. Thomas, R. Raja, Chem. Commun. 8, 675 (2001)

    Article  Google Scholar 

  2. K. Weissermel, H.J. Harpe, Industrial Organic Chemistry, 3rd edn. (VCH Press, Weinheim, 1997), pp. 239–242

    Book  Google Scholar 

  3. U. Schuchardt, D. Cardoso, R. Sercheli, R. Pereira, R.S. Cruz, M.C. Guerreiro, D. Mandelli, E.V. Spimace, E.L. Pires, Appl. Catal. A: Gen. 211, 1 (2001)

    Article  CAS  Google Scholar 

  4. U. Schuchardt, W.A. Carvalho, E.V. Spinace, Syn. Lett. 10, 713 (1993)

    Google Scholar 

  5. T. Tatsumi, M. Nakamura, S. Negishi, H. Tominaga, J. Chem. Soc., Chem. Commun. 6, 476 (1990)

    Article  Google Scholar 

  6. J.S. Reddy, S. Sivasanker, Catal. Lett. 11, 241 (1991)

    Article  CAS  Google Scholar 

  7. P. Concepcion, A. Corma, J.M.L. Nieto, J. Perz-Pariente, Appl. Catal. A: Gen. 143, 17 (1996)

    Article  CAS  Google Scholar 

  8. W.A. Carvalho, P.B. Varaldo, M. Wallau, U. Schuchardt, Zeolites. 18, 408 (1997)

    Article  CAS  Google Scholar 

  9. I. Belkhir, A. Germain, F. Fajula, E. Fache, J. Chem. Soc. Faraday Trans. 94, 1761 (1998)

    Article  CAS  Google Scholar 

  10. N. Perkas, Y. Kottypin, O. Palchik, A. Gedanken, S. Chandrasekaran, Appl. Catal. A: Gen. 209, 125 (2001)

    Article  CAS  Google Scholar 

  11. E.L. Pires, J.C. Magalhaes, U. Schuchardt, Appl. Catal. A: Gen. 203, 213 (2000)

    Article  Google Scholar 

  12. M. Taramasso, G. Perego, B. Notari, U. S. Patent, 4410501 (1983)

  13. M.G. Clerici, Appl. Catal. 68, 249 (1991)

    Article  CAS  Google Scholar 

  14. W. Pingping, P. Bai, K.P. Loh, X.S. Zhao, Catal. Today 158, 220 (2010)

    Article  CAS  Google Scholar 

  15. L. Gaomeng, R. Zhaoa, G. Qiana, Y. Qia, X. Wanga, J. Suoa, Catal. Lett. 97, 115 (2004)

    Article  Google Scholar 

  16. S.E. Dapurkar, A. Sakthivel, P. Selvam, New J. Chem. 27, 1184 (2003)

    Article  CAS  Google Scholar 

  17. S. Samanta, N.K. Mal, A. Bhaumik, J. Mol. Catal. A: Chem. 236, 7 (2005)

    Article  CAS  Google Scholar 

  18. H. Zhao, J.C. Zhou, H. Luo, C.Y. Zeng, D.H. Li, Y.J. Liu, Catal. Lett. 108, 49 (2006)

    Article  CAS  Google Scholar 

  19. S.S. Reddy, B.D. Raju, A.H. Padmasri, P.K.S. Prakash, K.S. Rama Rao, Catal. Today 141, 61 (2009)

    Article  CAS  Google Scholar 

  20. J.Y. Wang, F.Y. Zhao, R.J. Liu, Y.Q. Hu, J. Mol. Catal. A: Chem. 279, 153 (2008)

    Article  CAS  Google Scholar 

  21. A.P. Singh, T. Selvam, J. Mol. Catal. A: Chem. 113, 489 (1996)

    Article  CAS  Google Scholar 

  22. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature. 359, 710 (1992)

    Article  CAS  Google Scholar 

  23. A. Sayari, Chem. Mater. 8, 1840 (1996)

    Article  CAS  Google Scholar 

  24. A. Taguchi, F. Schuth, Microporous Mesoporous Mater. 77, 1 (2004)

    Article  CAS  Google Scholar 

  25. Y. Han, S. Wu, Y. Sun, D. Li, F.S. Xiao, J. Liu, X. Zhang, Chem. Mater. 14, 1144 (2002)

    Article  CAS  Google Scholar 

  26. Y. Han, X. Meng, H. Guan, Y. Yu, L. Zhao, X. Xu, X. Yang, S. Wu, N. Li, F.S. Xiao, Microporous Mesoporous Mater. 57, 191 (2003)

    Article  CAS  Google Scholar 

  27. G.A. Eimer, I. Diaz, E. Sastre, S.G. Casuscelli, M.E. Crivello, E.R. Herrero, J. Perez-Pariente, Appl. Catal. A: Gen. 343, 77 (2008)

    Article  CAS  Google Scholar 

  28. X. Meng, D. Li, X. Yang, Y. Yu, S. Wu, Y. Han, Q. Yang, D. Jiang, F.S. Xiao, J. Phys. Chem. B107, 8972 (2003)

    Article  CAS  Google Scholar 

  29. K.B. Saïdi, F. Hamidi, L.C. Aouali, S. Siffer, J. Chem. Chem. Eng. 5, 177 (2011)

    Google Scholar 

  30. M. Selvaraj, D.W. Park, Appl. Catal. A: Gen. 388, 22 (2010)

    Article  CAS  Google Scholar 

  31. A. Martínez, C. López, F. Márquez, I. Díaz, J. Catal. 220, 486 (2003)

    Article  CAS  Google Scholar 

  32. T. Tsoncheva, L. Ivanova, J. Rosenholm, M. Linden, Appl. Catal. B: Environ. 89, 365 (2009)

    Article  CAS  Google Scholar 

  33. Y. Xia, R. Mokaya, J. Mater. Chem. 14, 3427 (2004)

    Article  CAS  Google Scholar 

  34. S. Zeng, J. Blanchard, M. Breysse, Y. Shi, X. Su, H. Nie, D. Li, Appl. Catal. A: Gen. 294, 59 (2005)

    Article  CAS  Google Scholar 

  35. F. Wei, W. Song, F. Wei, C. Cao, Chin. J. Catal. 36, 838 (2015)

    Article  CAS  Google Scholar 

  36. L. Qiang, D. Tao, Z. Ying, L. Yuping, W. Shan, S. Famin, Front. Chem. Eng. China 1, 1 (2007)

    Article  Google Scholar 

  37. A. Szegedi, M. Popova, C. Minchev, J. Mater. Sci. 44, 6710 (2009)

    Article  CAS  Google Scholar 

  38. K. Bendahou, L. Cherif, S. Siffert, H.L. Tidahy, H. Benaïssa, A. Aboukaïs, Appl. Catal. A: Gen. 351, 82 (2008)

    Article  CAS  Google Scholar 

  39. H. Ma, J. Xu, C. Chen, Q. Zhang, J. Ning, H. Miao, L. Zhou, X. Li, Catal. Lett. 113, 104 (2007)

    Article  CAS  Google Scholar 

  40. Z. Lou, R. Wang, H. Sun, Y. Chen, Y. Yang, Microporous Mesoporous Mater. 110, 347 (2008)

    Article  CAS  Google Scholar 

  41. T. Inui, J.B. Kim, T. Takeguchi, Zeolites. 17, 354 (1996)

    Article  CAS  Google Scholar 

  42. E. El-Malki, D. Werst, P.E. Doan, W.M.H. Sachtler, J. Phys. Chem. B104, 5924 (2000)

    Article  CAS  Google Scholar 

  43. L. Li, H. Li, C. Jin, X. Wang, W. Ji, Y. Pan, T.V. Knaap, R.V. Stoel, C.T. Au, Catal. Lett. 136, 20 (2010)

    Article  CAS  Google Scholar 

  44. T.S. Tsoncheva, I.G. Genova, N. Scotti, M.D. Dimitrov, A. Gallo, D.G. Kovacheva, N. Ravasio, Bulg. Chem. Commun. 47, 283 (2015)

    Google Scholar 

  45. J.S. Girardon, E. Quinet, A.G. Constant, P.A. Chernavskii, L. Gengembre, A.Y. Khodakov, J. Catal. 248, 143 (2007)

    Article  CAS  Google Scholar 

  46. G.A.H. Mekhemer, H.M.M. Abd-Allah, S.A.A. Mansour, Coll. Surf. A: Phys. Eng. Aspe160, 251 (1999)

    Article  Google Scholar 

  47. Y. Brik, M. Kacimi, M. Ziyad, F.B. Verdurazy, J. Catal. 202, 118 (2001)

    Article  CAS  Google Scholar 

  48. A. Hagen, K. Schueler, F. Roessner, Microporous Mesoporous Mater. 51, 23 (2002)

    Article  CAS  Google Scholar 

  49. F. Figueras, H. Kochkar, Catal. Lett. 59, 79 (1999)

    Article  CAS  Google Scholar 

  50. R. Kumar, S. Sithambarama, S.L. Suib, J. Catal. 262, 304 (2009)

    Article  CAS  Google Scholar 

  51. S. Khare, P. Shrivastava, Catal. Lett. 146, 319 (2016)

    Article  CAS  Google Scholar 

  52. A.P. Singh, T. Selvam, Appl.Catal. A: Gen. 143, 111 (1996)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de catalyse et synthèse en chimie organique PB 119, Université de Tlemcen, Tlemcen, Algeria

    A. Ziouèche & L. Chérif-Aouali

  2. Laboratoire de chimie des matériaux, Université d’Oran, Oran, Algeria

    A. Bengueddach

Authors
  1. A. Ziouèche
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Chérif-Aouali
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Bengueddach
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. Chérif-Aouali.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ziouèche, A., Chérif-Aouali, L. & Bengueddach, A. Liquid phase oxidation of cyclohexane over mesoporous cobalt silicates molecular sieves synthesized in strong acidic media by assembly of preformed CoS-1 precursors with triblock copolymer. J Porous Mater 26, 575–581 (2019). https://doi.org/10.1007/s10934-018-0659-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-018-0659-3

Keywords

Search

Navigation