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Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8

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Abstract

In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO3)2 as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N2 sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability.

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Acknowledgements

The authors acknowledge IlamUniversity, Ilam, Iran for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran

    Zakieh Yousofvand, Maryam Hajjami & Raziyeh Ghafouri-Nejad

  2. Department of Environment, Faculty of Natural Resource, University of Kurdistan, Sanandaj, 66177-15177, Iran

    Farshid Ghorbani

Authors
  1. Zakieh Yousofvand
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  2. Maryam Hajjami
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  3. Farshid Ghorbani
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  4. Raziyeh Ghafouri-Nejad
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Correspondence to Maryam Hajjami.

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Yousofvand, Z., Hajjami, M., Ghorbani, F. et al. Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8 . J Porous Mater 25, 1349–1358 (2018). https://doi.org/10.1007/s10934-017-0545-4

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