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Journal of Porous Materials

, Volume 24, Issue 5, pp 1209–1214 | Cite as

Reversible adsorption and desorption of water in nanoporous copper(II) metal–organic nanocapsules

  • Elham Mirzadeh
  • Kamran AkhbariEmail author
Article

Abstract

Nanocapsule of [Cu2(bda)2(bpy)2]·4H2O (1) with nanoparticle morphology (bda2− = 2,2ʹ-biphenyl dicarboxylate and bpy = 2,2ʹ-bipyridine), was synthesized by sonochemical process. Guest water molecules can be removed from the nanopores of 1 by thermal treatment at 200 °C. The color of this compound changed from blue to deep green during this process. This process is reversible and compound [Cu2(bda)2(bpy)2] (2) with the pore size of 4.3 × 5.5 Å can absorb water again. Thus nanoparticles of compound 2 with 1.53% weight absorption of water/compound 2 at room temperature could be used as water adsorption material like silica gel. Adsorption and desorption of water in these copper(II) metal–organic nanocapsules were studied by IR spectroscopy, thermo gravimetric analyses (TGA), X-ray powder diffraction (XRD) and scanning electron microscopy (SEM).

Keywords

Nanocapsule Nanoparticles Adsorption Desorption Sonochemical Nanopore 

Notes

Acknowledgements

The authors would like to acknowledge the financial support of University of Tehran for this research under Grant number 01/1/389845.

Supplementary material

10934_2017_360_MOESM1_ESM.doc (2 mb)
Supplementary material 1 (DOC 2002 KB)

References

  1. 1.
    X.W. Lou, L.A. Archer, Z. Yang, Adv. Mater. 20, 3987 (2008)CrossRefGoogle Scholar
  2. 2.
    Y. Zhao, L. Jiang, Adv. Mater. 21, 3621 (2009)CrossRefGoogle Scholar
  3. 3.
    J. Jang, J.H. Oh, X.L. Li, J. Mater. Chem. 19, 2872 (2004)CrossRefGoogle Scholar
  4. 4.
    C.A. Morris, M.L. Anderson, R.M. Stroud, C.I. Merzbacher, D.R. Rolison, Science 284, 622 (1999)CrossRefGoogle Scholar
  5. 5.
    G. Yun, Z. Hassan, J. Lee, J. Kim, N.S. Lee, N.H. Kim, K. Beak, I. Hwang, Ch..G. Park, K. Kim, Angew. Chem. Int. Ed. Engl. 53, 6414 (2014)CrossRefGoogle Scholar
  6. 6.
    X.W. Wang, W. Gao, H. Fan, D. Ding, X.F. Lai, Y.X. Zou, L. Chen, Zh.. Chen, W. Tan, Nanoscale 8, 7942 (2016)CrossRefGoogle Scholar
  7. 7.
    C.E. Mora-Huertas, H. Fessi, A. Elaissari, J. Pharm. 385, 113 (2010)Google Scholar
  8. 8.
    D.G. Shchukin, G.B. Sukhorukov, H. Mohwald, Angew. Chem., Int. Ed. Engl. 42, 4472 (2003)CrossRefGoogle Scholar
  9. 9.
    N. Gaponik, I.L. Radtchenko, M.R. Gerstenberger, Y.A. Fedutik, G.B. Sukhorukov, A.L. Rogach, Nano Lett. 39, 369 (2003)CrossRefGoogle Scholar
  10. 10.
    J. Jang, J.H. Oh, Adv. Mater. 15, 977 (2003)CrossRefGoogle Scholar
  11. 11.
    E. Wilson, Chem. Eng. News 77, 32 (1999)Google Scholar
  12. 12.
    E. Choi, M. Kwak, B. Jang, Y. Piao, Nanoscale 5, 151 (2013)CrossRefGoogle Scholar
  13. 13.
    L. Chen, Zh. Peng, Zh. Zeng, Y. She, J. Wei, Y. Chen, J. Polym. Sci., Part A: Polym. Chem. 52, 2202 (2014)CrossRefGoogle Scholar
  14. 14.
    Y. Zhang, B.Y.W. Hsu, Ch. Ren, J. Wang, Chem. Soc. Rev. 44, 315 (2015)CrossRefGoogle Scholar
  15. 15.
    F. Caruso, R.A. Caruso, H. Möhwald, Science 282, 1111 (1998)CrossRefGoogle Scholar
  16. 16.
    S.S. Kim, W. Zhang, T.J. Pinnavaia, Science 282, 13020 (1998)CrossRefGoogle Scholar
  17. 17.
    Zh. Li, T. Yang, Ch. Lin, Q. Li, S. Liu, F. Xu, H. Wang, X. Cui, ACS Appl. Mater. Interfaces 6, 826 (2014)CrossRefGoogle Scholar
  18. 18.
    G. Lu, Z. An, C. Tao, J. Li, Langmuir 20, 8401 (2004)CrossRefGoogle Scholar
  19. 19.
    Z. Wu, Y. Wu, W. He, X. Lin, J. Sun, Q. He, Angew. Chem. Int. Ed. 52, 7000 (2013)CrossRefGoogle Scholar
  20. 20.
    G. Yeroslavsky, M. Richman, L.O Dawidowicz, Sh. Rahimipou, Chem. Commun. 49, 5721 (2013).CrossRefGoogle Scholar
  21. 21.
    F.Sh. Shirazi, K. Akhbari, S. Kawata, R. Ishikawa, J. Mol. Struct. 1123, 206 (2016)CrossRefGoogle Scholar
  22. 22.
    N. Amara, B. Ratsimba, A.M. Wilhelm, H. Delmas, Ultrason. Sonochem. 8, 265 (2001)CrossRefGoogle Scholar
  23. 23.
    N. Enomoto, S. Maruyama, Z. Nakagawa, J. Mater. Res. 12, 1410 (1997)CrossRefGoogle Scholar
  24. 24.
    S. Koda, A. Susuki, H. Nomura, Polym. J. 27, 1144 (1995).CrossRefGoogle Scholar
  25. 25.
    A. Alizadeh, H. Sedighian, R. Ghanbaripour, Helv. Chim. Acta 97, 447 (2014)CrossRefGoogle Scholar
  26. 26.
    T. Ding, J.J. Zhu, J.M. Hong, Mater. Lett. 57, 4445 (2003)CrossRefGoogle Scholar
  27. 27.
    J.H. Zhang, Z. Chen, Z.L. Wang, N.B. Ming, J. Mater. Res. 18, 1804 (2003)CrossRefGoogle Scholar
  28. 28.
    H.-Y. He, Y.-L. Zhou, J. Gao, Acta Cryst. E 63, 2007 (2007)CrossRefGoogle Scholar
  29. 29.
    H.-X. Guo, M. Liang, B. Lin, Q.-H. Wang, X.-Z. Li, Acta Cryst. E 64, 1171 (2008)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.School of Chemistry, College of ScienceUniversity of TehranTehranIslamic Republic of Iran

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