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Preparation and characterization of a mesoporous polycrown impregnated silica and its adsorption for palladium from highly acid medium

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Abstract

A polycrown loaded silica composite material named Polycrown/SiO2-P was firstly prepared by impregnating and immobilizing polycrown into porous silica and was characterized by scanning electron microscope (SEM), and Fourier transformed infrared (FT-IR) spectroscopy, nitrogen adsorption and desorption isotherms. Polycrown/SiO2-P was tested with regard to adsorption performance. Interestingly, Polycrown/SiO2-P preferred Pd(II) than alkali metals, alkaline-earth metals and actinides. Pd(II) adsorption with Polycrown/SiO2-P as functions of HNO3 concentration, contact time, initial Pd(II) concentration, temperature were thus investigated. The results showed the optimal adsorption acidity was determined as 5.0 M nitric acid, proving good acidity-resistant. Pseudo-second-order kinetics model fitted adsorption well indicating chemical adsorption. The isotherm adsorption equilibrium was well described by Langmuir isotherm model with maximum adsorption capacity of 14.30 mg/g. Pd(II) adsorption increased with temperature increased. The positive ΔH° and ΔS°, and the negative ΔG° indicated the adsorption was endothermic, entropy increase and spontaneous in nature. Pd(II) loaded Polycrown/SiO2-P was characterized by XPS. Further, the adsorption efficiency of recovered Polycrown/SiO2-P retained up ~93.7% after five ad-desorption cycles. Polycrown/SiO2-P was promising to separate Pd(II) from highly acid medium.

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Acknowledgments

The present work was financially supported by National Natural Science Foundation of China (No. 11605027, No. U1407115 and No. 91126021), the Project of the Jiangxi Provincial Department of Education (Grant No. GJJ150560), the Doctoral Research Fund of East China University of Technology (Grant No.DHBK2015301), the Natural Science Foundation of Jiangxi Province (No.20151BDH80073), the Research Foundation of Education Bureau of Jiangxi Province (No. GJJ150566) and the Zhejiang Provincial Natural Science Foundation of China (No.LY17B060004).

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Authors and Affiliations

  1. College of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, Zhejiang, People’s Republic of China

    Ying Dai & Anyun Zhang

  2. School of Chemistry, Biological and Materials Science, East China University of Technology, Nanchang, 330013, Jiangxi, People’s Republic of China

    Ying Dai & Yan Liu

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  1. Ying Dai
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Correspondence to Anyun Zhang.

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Dai, Y., Liu, Y. & Zhang, A. Preparation and characterization of a mesoporous polycrown impregnated silica and its adsorption for palladium from highly acid medium. J Porous Mater 24, 1037–1045 (2017). https://doi.org/10.1007/s10934-016-0343-4

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