Skip to main content
SpringerLink
Log in

Fabrication of functional dual-mesoporous silicas by using peroxo-tungstate ionic liquid and their applications in oxidative desulfurization

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

A novel strategy has been applied for synthesis of bimodal mesoporous silica by ionic liquid [C16mim]2[W2O3(O2)4] as a single template as well as tungsten source to incorporate tungsten species onto mesoporous silica. The results show that the sample possesses short-range ordering dual-mesopores and the tungsten species are incorporated onto the mesoporous silicas matrix successfully. The material also turns out to be a robust catalyst for oxidative desulfurization without any organic solvents. Sulfur removal of dibenzothiophene could reach 100 % within 30 min when using 0.2W–SiO2 (mole ratio between W and Si is 0.2) as catalyst. Moreover, this catalyst could be recycled nine times with little decrease in activity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. C.S. Song, Catal. Today 86, 211–263 (2003)

    Article  CAS  Google Scholar 

  2. F.T. Li, R.H. Liu, J.H. Wen, D.S. Zhao, Z.M. Sun, Y. Liu, Green Chem. 11, 883–888 (2009)

    Article  CAS  Google Scholar 

  3. S. Otsuki, T. Nonaka, N. Takashima, W.H. Qian, A. Ishihara, T. Imai, T. Kabe, Energy Fuels 14, 1232–1239 (2000)

    Article  CAS  Google Scholar 

  4. W.S. Zhu, B.L. Dai, P.W. Wu, Y.H. Chao, J. Xiong, S.H. Xun, H.P. Li, H.M. Li, ACS Sustain. Chem. Eng. 3, 186–194 (2015)

    Article  CAS  Google Scholar 

  5. F.L. Yu, R. Wang, Acta Chim. Sin. 72, 105–113 (2014)

    Article  CAS  Google Scholar 

  6. W.S. Zhu, P.W. Wu, L. Yang, Y.H. Chang, Y.H. Chao, H.M. Li, Y.Q. Jiang, W. Jiang, S.H. Xun, Chem. Eng. J. 229, 250–256 (2013)

    Article  CAS  Google Scholar 

  7. W.S. Zhu, C. Wang, H.M. Li, P.W. Wu, S.H. Xun, W. Jiang, Z.G. Chen, Z. Zhao, H.M. Li, Green Chem. 17, 2464–2472 (2015)

    Article  CAS  Google Scholar 

  8. W.S. Zhu, H.M. Li, Q.Q. Gu, P.W. Wu, G.P. Zhu, Y.S. Yan, G.Y. Chen, J. Mol. Catal. A: Chem. 336, 16–22 (2011)

    Article  CAS  Google Scholar 

  9. W.S. Zhu, H.M. Li, X. Jiang, Y.S. Yan, H.D. Lu, J.X. Xia, Energy Fuels 21, 2514–2516 (2007)

    Article  CAS  Google Scholar 

  10. D.H. Wang, E.W.H. Qian, H. Amano, K. Okata, A. Ishihara, T. Kabe, Appl. Catal. a Gen. 253, 91–99 (2003)

    Article  CAS  Google Scholar 

  11. Q. Tang, S. Lin, Y. Cheng, S.J. Liu, J.R. Xiong, Ultrason. Sonochem. 20, 1168–1175 (2013)

    Article  CAS  Google Scholar 

  12. Y.X. Ding, W.S. Zhu, H.M. Li, W. Jiang, M. Zhang, Y.Q. Duan, Y.H. Chang, Green Chem. 13, 1210–1216 (2011)

    Article  CAS  Google Scholar 

  13. J. Zhang, A.J. Wang, Y.J. Wang, H.Y. Wang, J.Z. Gui, Chem. Eng. J. 245, 65–70 (2014)

    Article  CAS  Google Scholar 

  14. F.T. Li, C.G. Kou, Z.M. Sun, Y.J. Hao, R.H. Liu, D.S. Zhao, J. Hazard. Mater. 205, 164–170 (2012)

    Article  Google Scholar 

  15. H.Y. Lü, S.A. Wang, C.L. Deng, W.Z. Ren, B.C. Guo, J. Hazard. Mater. 279, 220–225 (2014)

    Article  Google Scholar 

  16. C.H. Ma, B. Dai, P. Liu, N. Zhou, A.J. Shi, L.L. Ban, H.W. Chen, J. Ind. Eng. Chem. 20, 2769–2774 (2014)

    Article  Google Scholar 

  17. J.L. Wang, D.S. Zhao, K.X. Li, Energy Fuels 24, 2527–2529 (2010)

    Article  CAS  Google Scholar 

  18. H.Y. Lue, Y.N. Zhang, Z.X. Jiang, C. Li, Green Chem. 12, 1954–1958 (2010)

    Article  CAS  Google Scholar 

  19. S.C. Chen, W.Y. Lu, Y.Y. Yao, H.X. Chen, W.X. Chen, React. Kinet. Mech. Catal. 111, 535–547 (2014)

    Article  CAS  Google Scholar 

  20. W.S. Zhu, Y.X. Ding, H.M. Li, J. Qin, Y.H. Chao, J. Xiong, Y.H. Xu, H. Liu, Rsc Adv. 3, 3893–3898 (2013)

    Article  CAS  Google Scholar 

  21. W.S. Zhu, G.P. Zhu, H.M. Li, Y.H. Chao, Y.H. Chang, G.Y. Chen, C.R. Han, J. Mol. Catal. A: Chem. 347, 8–14 (2011)

    Article  CAS  Google Scholar 

  22. W.L. Huang, W.S. Zhu, H.M. Li, H. Shi, G.P. Zhu, H. Liu, G.Y. Chen, Ind. Eng. Chem. Res. 49, 8998–9003 (2010)

    Article  CAS  Google Scholar 

  23. M. Zhang, W.S. Zhu, S.H. Xun, H.M. Li, Q.Q. Gu, Z. Zhao, Q. Wang, Chem. Eng. J. 220, 328–336 (2013)

    Article  CAS  Google Scholar 

  24. W.S. Zhu, W.L. Huang, H.M. Li, M. Zhang, W. Jiang, G.Y. Chen, C.R. Han, Fuel Process. Technol. 92, 1842–1848 (2011)

    Article  CAS  Google Scholar 

  25. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J.L. Schlenker, J. Am. Chem. Soc. 114, 10834–10843 (1992)

    Article  CAS  Google Scholar 

  26. C.P. Mehnert, R.A. Cook, N.C. Dispenziere, M. Afeworki, J. Am. Chem. Soc. 124, 12932–12933 (2002)

    Article  CAS  Google Scholar 

  27. Z.E.A. Abdalla, B.S. Li, Chem. Eng. J. 20, 113–121 (2012)

    Article  Google Scholar 

  28. D. Zhao, A. Rodriguez, N.M. Dimitrijevic, T. Rajh, R.T. Koodali, J. Phys. Chem. C 114, 15728–15734 (2010)

    Article  CAS  Google Scholar 

  29. X.L. Yang, W.L. Dai, R.H. Gao, K.N. Fan, J. Catal. 249, 278–288 (2007)

    Article  CAS  Google Scholar 

  30. I. Jimenez-Morales, J. Santamaria-Gonzalez, P. Maireles-Torres, A. Jimenez-Lopez, Appl. Catal. A Gen. 379, 61–68 (2010)

    Article  CAS  Google Scholar 

  31. W.H. Wang, G. Li, W.G. Li, L.P. Liu, Chem. Commun. 47, 3529–3531 (2011)

    Article  CAS  Google Scholar 

  32. S. Areva, C. Boissiere, D. Grosso, T. Asakawa, C. Sanchez, M. Linden, Chem. Commun. 14, 1630–1631 (2004)

    Article  Google Scholar 

  33. J. Wei, Q. Yue, Z.K. Sun, Y.H. Deng, D.Y. Zhao, Angew. Chem. Int. Ed. 51, 6149–6153 (2012)

    Article  CAS  Google Scholar 

  34. W.S. Zhu, H.M. Li, X.Y. He, Q. Zhang, H.M. Shu, Y.S. Yan, Catal. Commun. 9, 551–555 (2008)

    Article  CAS  Google Scholar 

  35. W.S. Zhu, P.W. Wu, Y.H. Chao, H.M. Li, F. Zou, S.H. Xun, F.X. Zhu, Z. Zhao, Ind. Eng. Chem. Res. 52, 17399–17406 (2013)

    Article  CAS  Google Scholar 

  36. C.J. Adams, A.E. Bradley, K.R. Seddon, Aust. J. Chem. 54, 679–681 (2001)

    Article  CAS  Google Scholar 

  37. Y.L. Zhao, D. Wu, T. Tang, Y.H. Sun, Mater. Res. Bull. 48, 4839–4843 (2013)

    Article  CAS  Google Scholar 

  38. J. Zhang, Y.B. Ma, F. Shi, L.Q. Liu, Y.Q. Deng, Microporous Mesoporous Mater. 119, 97–103 (2009)

    Article  CAS  Google Scholar 

  39. M. Zhang, W.S. Zhu, H.M. Li, S.H. Xun, W.J. Ding, J.J. Liu, Z. Zhao, Q. Wang, Chem. Eng. J. 243, 386–393 (2014)

    Article  CAS  Google Scholar 

  40. Q.Q. Gu, W.S. Zhu, S.H. Xun, Y.H. Chang, J. Xiong, M. Zhang, W. Jiang, F.X. Zhu, H.M. Li, Fuel 117, 667–673 (2014)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by State Key Laboratory of Heavy Oil Processing and the National Nature Science Foundation of China (Nos. 21276117, 21376111, 21376109), Six Big Talent Peak in Jiangsu province (JNHB-004), Natural Science Foundation of Jiangsu Province (No. BK20131207) and Postdoctoral Foundation of China (No. 2014M551516).

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang, 212013, People’s Republic of China

    Wenshuai Zhu, Qingqing Gu, JuanJuan Hu, Peiwen Wu, Sheng Yin, Fengxia Zhu, Jun Xiong & Huaming Li

  2. Insititute for Energy Research, Jiangsu University, 301 Xuefu Road, Zhenjiang, 212013, People’s Republic of China

    Ming Zhang

Authors
  1. Wenshuai Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qingqing Gu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. JuanJuan Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Peiwen Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Sheng Yin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Fengxia Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Ming Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Jun Xiong
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Huaming Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Wenshuai Zhu or Huaming Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhu, W., Gu, Q., Hu, J. et al. Fabrication of functional dual-mesoporous silicas by using peroxo-tungstate ionic liquid and their applications in oxidative desulfurization. J Porous Mater 22, 1227–1233 (2015). https://doi.org/10.1007/s10934-015-9999-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-015-9999-4

Keywords

Search

Navigation