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Oxovanadium(IV) salicylidene Schiff base complex anchored on mesoporous silica MCM-41 as hybrid materials: a robust catalyst for the oxidation of sulfides

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Abstract

Oxovanadium(IV) Schiff base complex have been anchored onto the surface of purely siliceous MCM-41 and tested for its activity as catalyst for the oxidation of sulfides. This catalyst could alter this oxidation reaction extremity, exhibiting excellent yields with 100 % selectivity. The intercalation of the complex inside the silica matrix was supported by various characterization techniques like X-ray diffraction, differential thermogravimetric (TG-DTA), BET measurements, UV–Vis diffuse reflectance spectroscopy and Fourier transform infrared spectroscopy (FT-IR). The stability of the catalyst during the course of the reaction was confirmed from its post catalytic FT-IR and XRD analysis. The catalyst could be reused five times without notable loss of its catalytic activity and efficiency which indicates that the metal-Schiff base moiety is intact and the coordination environments are not altered during the reaction.

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Acknowledgments

Financial support for this work by the research affairs of Islamic Azad University, Qeshm Branch, Qeshm, Iran is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Islamic Azad University, Qeshm Branch, Qeshm, Iran

    Arida Jabbari

  2. Department of Chemistry, Faculty of Science, Ilam University, P. O. Box 69315516, Ilam, Iran

    Houri Mahdavi, Mohsen Nikoorazm & Arash Ghorbani-Choghamarani

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  1. Arida Jabbari
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  2. Houri Mahdavi
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  3. Mohsen Nikoorazm
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  4. Arash Ghorbani-Choghamarani
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Correspondence to Arida Jabbari.

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Jabbari, A., Mahdavi, H., Nikoorazm, M. et al. Oxovanadium(IV) salicylidene Schiff base complex anchored on mesoporous silica MCM-41 as hybrid materials: a robust catalyst for the oxidation of sulfides. J Porous Mater 22, 1111–1118 (2015). https://doi.org/10.1007/s10934-015-9986-9

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  • DOI: https://doi.org/10.1007/s10934-015-9986-9

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