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Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide catalyzed by silica–VTMO–OSO3H

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Abstract

Silica-supported catalyst exhibiting sulfonic groups was proved effective in the Baeyer–Villiger oxidation to the lactones from the corresponding cyclic ketones in high yields with clean hydrogen peroxide in acetonitrile at mild conditions. Moreover, the catalyst was easily recovered and could be reused at least four times without significant decline in catalytic activity.

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Acknowledgments

This Project is funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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Authors and Affiliations

  1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China

    Wanzhen Xing, Qingguo Ma, Junhui Xu & Xinhua Peng

Authors
  1. Wanzhen Xing
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  2. Qingguo Ma
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  3. Junhui Xu
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  4. Xinhua Peng
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Correspondence to Xinhua Peng.

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Xing, W., Ma, Q., Xu, J. et al. Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide catalyzed by silica–VTMO–OSO3H. J Porous Mater 22, 487–492 (2015). https://doi.org/10.1007/s10934-015-9918-8

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