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Acidic property of BEA zeolite synthesized by seed-directed method

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Abstract

The acidic property of a BEA zeolite prepared by a seed-directed synthesis (SDS) method without organic structure directing agent (OSDA) was analyzed by a method of ammonia infrared/mass spectroscopic temperature-programmed desorption. The number of Brønsted acid sites on the SDS-BEA zeolite was larger than that on a conventional BEA zeolite synthesized from using OSDA. The enthalpy of ammonia desorption, distributed mainly in a range between 115 and 145 kJ mol−1, was in agreement with the acid strength region generated by isomorphous substitution of Si4+ by Al3+ in the BEA framework. These observations confirm that the microstructure around the incorporated Al in the SDS-BEA zeolite was equivalent to that in the conventional one.

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Acknowledgments

This study was partly supported by a Grant-in-Aid for Scientific Research (B) 23360358 from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

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Authors and Affiliations

  1. Center for Research on Green Sustainable Chemistry, Graduate School of Engineering, Tottori University, 4-101 Koyama-cho Minami, Tottori, 680-8552, Japan

    Satoshi Suganuma

  2. State Key Lab of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, China

    Haiyan Zhang & Chengguang Yang

  3. Key Lab of Applied Chemistry of Zhejiang Province, Zhejiang University, Hangzhou, 310028, China

    Feng-Shou Xiao

  4. Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University, 4-101 Koyama-cho Minami, Tottori, 680-8552, Japan

    Naonobu Katada

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  1. Satoshi Suganuma
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  5. Naonobu Katada
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Correspondence to Satoshi Suganuma.

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Suganuma, S., Zhang, H., Yang, C. et al. Acidic property of BEA zeolite synthesized by seed-directed method. J Porous Mater 23, 415–421 (2016). https://doi.org/10.1007/s10934-015-0095-6

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  • DOI: https://doi.org/10.1007/s10934-015-0095-6

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