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Fluorene functionalized nanoporous SBA-15 incorporated into carbon paste electrode for trace copper determination

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Abstract

In this study, fluorene 3-[2-(2-aminoethylamino)ethylamino]propyl trimethoxy silane functionalized nanoporous SBA-15 was incorporated into carbon paste electrode for the potentiometric detection of Cu2+ ions in aqueous medium. With 15.5 wt% FT-SBA-15 proportion, the developed electrode exhibited wide dynamic range of 1.0 × 10−6–1.0 × 10−2 mol L−1 toward Cu2+ with a detection limit of 5.0 × 10−7 mol L−1 and a Nernstian slope of 29.6 ± 1.0 mV decade−1. The electrode displayed rapid response (~44 s), long-term stability (more than 6 months) and high sensitivity. Moreover, the potentiometric responses could be carried out with a wide pH range of 3.9–6.6. Finally, the proposed electrode was successfully used as an indicator electrode in potentiometric titration of copper ions with EDTA and to determine the concentration of copper ions in seawater, tap water and black tea samples. The results showed a good correlation with the data obtained by graphite furnace atomic absorption spectrometry method.

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References

  1. A.K. Jain, V.K. Gupta, B.B. Sahoo, L.P. Singh, Anal. Commun. 32, 99–101 (1995)

    Article  Google Scholar 

  2. T. Rosatzin, E. Bakker, K. Suzuki, W. Simon, Anal. Chim. Acta 280, 197–208 (1993)

    Article  CAS  Google Scholar 

  3. M. Shamsipur, S. Rouhani, M.R. Ganjali, H. Eshghi, H. Sharghi, Microchem. J. 63, 202–210 (1999)

    Article  CAS  Google Scholar 

  4. S. Dadfarnia, M. Shamsipur, J. Membr. Sci. 75, 61–68 (1992)

    Article  CAS  Google Scholar 

  5. M.B. Gholivand, M. Rahimi-Nasrabadi, M.R. Ganjali, M. Salavati-Niasari, Talanta 73, 553–560 (2007)

    Article  CAS  Google Scholar 

  6. S. Sadeghi, M.T. Vardhini, H. Naeimi, Ann. Chim. 96, 65–74 (2006)

    Article  CAS  Google Scholar 

  7. P. Norouzi, M.R. Ganjali, F. Faridbod, M. Salavati-Niasari, Bull. Korean Chem. Soc. 27, 1439–1444 (2006)

    Article  CAS  Google Scholar 

  8. M. Shamsipur, M. Javanbakht, M.F. Mousavi, M.R. Ganjali, V. Lippolis, A. Garau, L. Tei, Talanta 55, 1047–1054 (2001)

    Article  CAS  Google Scholar 

  9. S.J. Park, O.J. Shon, J.A. Rim, J.K. Lee, J.S. Kim, H. Nam, H. Kim, Talanta 55, 297–304 (2001)

    Article  CAS  Google Scholar 

  10. A.H. Kamel, W.H. Mahmoud, M.S. Mostafa, Electroanalysis 22, 2453–2459 (2010)

    Article  CAS  Google Scholar 

  11. M.H. Mashhadizadeh, S. Ramezani, M.K. Rofouei, Mater. Sci. Eng. C Mater. Biol. Appl. 47, 273–280 (2015)

    Article  CAS  Google Scholar 

  12. Y. Xiujuan, C. Yaqin, Y. Ruo, Z. Qiang, Y. Chunli, Anal. Methods 4, 3332–3337 (2012)

    Article  Google Scholar 

  13. G. Junxiang, C. Yaqin, Y. Ruo, S. Zhongju, Z. Zhifen, Sens. Actuators B Chem. 155, 639–645 (2011)

    Article  Google Scholar 

  14. M. Javanbakhta, F. Divsar, A.R. Badiei, F. Fatollahi, Y. Khaniani, M.R. Ganjali, P. Norouzi, M. Chaloosi, G.M. Ziarani, Electrochim. Acta 54, 5381–5386 (2009)

    Article  Google Scholar 

  15. Z. Ting, C. Yaqin, Y. Ruo, G. Junxiang, Mater. Sci. Eng. C 32, 1179–1183 (2012)

    Article  Google Scholar 

  16. M. Javanbakhta, F. Divsar, A.R. Badiei, M.R. Ganjali, P. Norouzi, G. Mohammadi Ziarani, M. Chaloosi, A.A. Jahangir, Anal. Sci. 25, 789–794 (2009)

    Article  Google Scholar 

  17. M. Ghaedi, A. Shokrollahi, A.R. Salimibeni, S. Noshadi, S. Joybar, J. Hazard. Mater. 178, 157–163 (2010)

    Article  CAS  Google Scholar 

  18. W. Zhou, Y. Chai, R. Yuan, J. Guo, X. Wu, Anal. Chim. Acta 647, 210–214 (2009)

    Article  CAS  Google Scholar 

  19. M.H. Mashhadizadeh, S. Ramezani, S. Ebrahimi, Sens. Actuators B 169, 305–311 (2012)

    Article  CAS  Google Scholar 

  20. W.L.F. Armarego, D.D. Perrin, Purification of Laboratory Chemicals (Elsevier, Burlington, 1996)

    Google Scholar 

  21. A.R. Badiei, H. Goldooz, G. Mohammadi Ziarani, Appl. Surf. Sci. 257, 4912–4918 (2011)

    Article  CAS  Google Scholar 

  22. J.A. Bae, S.H. Hwang, K.C. Song, J.K. Jeon, Y.S. Ko, J.H. Yim, J. Nanosci. Nanotechnol. 10, 290–296 (2010)

    Article  CAS  Google Scholar 

  23. D.I. Kim, J.H. Park, S.D. Kim, J.Y. Lee, J.H. Yim, J.K. Jeon, S.H. Park, Y.K. Park, J. Ind. Eng. Chem. 17, 1–5 (2011)

    Article  CAS  Google Scholar 

  24. H. Abbastabar-Ahangar, A. Shirzadmehr, K. Marjani, H. Khoshsafar, M. Chaloosi, L. Mohammadi, J. Incl. Phenom. Macrocycl. Chem. 63, 287–293 (2009)

    Article  CAS  Google Scholar 

  25. A. Afkhami, T. Madrakian, H. Ghaedi, H. Khanmohammadi, Electrochim. Acta 66, 255–264 (2012)

    Article  CAS  Google Scholar 

  26. R.N. Goyal, M. Oyama, V.K. Gupta, S.P. Singh, R.A. Sharma, Sens. Actuators B 134, 816–821 (2008)

    Article  CAS  Google Scholar 

  27. I. Svancara, K. Vytras, K. Kalcher, A. Walcarius, J. Wang, Electroanalysis 21, 7–28 (2009)

    Article  CAS  Google Scholar 

  28. I. Svancara, A. Walcarius, K. Kalcher, K. Vytras, Cent. Eur. J. Chem. 7, 598–656 (2009)

    Article  CAS  Google Scholar 

  29. A. Afkhami, T. Madrakian, S.J. Sabounchei, M. Rezaei, S. Samiee, M. Pourshahbaz, Sens. Actuators B 161, 542–548 (2012)

    Article  CAS  Google Scholar 

  30. F. Faridbod, M.R. Ganjali, R. Dinarvand, P. Norouzi, S. Riahi, Sensors 8, 1645–1703 (2008)

    Article  CAS  Google Scholar 

  31. Y. Umezawa, K. Umezawa, H. Sato, Pure Appl. Chem. 67, 507–518 (1995)

    Article  Google Scholar 

  32. R.P. Buck, E. Lindneri, Pure Appl. Chem. 66, 2527–2536 (1994)

    Article  CAS  Google Scholar 

  33. S. Yoshimoto, H. Mukai, T. Kitano, Y. Sohrin, Anal. Chim. Acta 494, 207–213 (2003)

    Article  CAS  Google Scholar 

  34. V.K. Gupta, R.N. Goyal, N. Bachheti, L.P. Singh, S. Agarwal, Talanta 68, 193–197 (2005)

    Article  CAS  Google Scholar 

  35. M.H. Mashhadizadeh, K. Eskandari, A. Foroumadi, A. Shafiee, Talanta 76, 497–502 (2008)

    Article  CAS  Google Scholar 

  36. A.K. Jain, V.K. Gupta, L.P. Singh, J.R. Raisoni, Talanta 66, 1355–1361 (2005)

    Article  CAS  Google Scholar 

  37. A. Abbaspour, S.M.M. Moosavi, Talanta 56, 91–96 (2002)

    Article  CAS  Google Scholar 

  38. I.M. Yousry, I. Hosny, S.R. Ola, J. Electroanal. Chem. 666, 11–18 (2012)

    Article  Google Scholar 

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Acknowledgments

This work has been funded by Payame Noor University.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University (PNU), P.O. Box 19395-4697, Tehran, Iran

    Faten Divsar, Azizollah Nezhadali & Sara Easapour

  2. Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran

    Neda Isapour & Hassan Kefayati

  3. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Alireza Badiei & Marzieh Yadavi

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  1. Faten Divsar
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  2. Neda Isapour
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  3. Hassan Kefayati
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  4. Alireza Badiei
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  5. Azizollah Nezhadali
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  6. Sara Easapour
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  7. Marzieh Yadavi
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Correspondence to Faten Divsar.

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Divsar, F., Isapour, N., Kefayati, H. et al. Fluorene functionalized nanoporous SBA-15 incorporated into carbon paste electrode for trace copper determination. J Porous Mater 22, 1655–1661 (2015). https://doi.org/10.1007/s10934-015-0049-z

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