Skip to main content
SpringerLink
Log in

Synthesis, characterization and desulfurization performance of MCM-41 functionalized with Cu by direct synthesis and organosilanes by grafting

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

Cu-incorporated MCM-41 was prepared by the direct synthesis method. The Cu-incorporated MCM-41 was then organically functionalized by grafting of organosilanes followed by the complexation of copper ions. The results of powder X-ray diffraction, Fourier transform infrared, and temperature-programmed reduction suggest the incorporation of Cu into the framework of MCM-41 during the direct synthesis process. The mesostructure of prepared samples is preserved after functionalization. The sulfur capacities for tert-butyl mercaptan, dimethyl sulfide, and dimethyl disulfide decrease in the same order (40)Cu–M > (40)Cu–M–N–Cu. The (40)Cu–M synthesized through the direct synthesis method also shows better desulfurization performance than M–Cu prepared by the incipient wetness impregnation method. This is attributed to the incorporated Cu species in the framework and well-dispersed CuO species of (40)Cu–M.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. J. Lee, H.T. Beum, C.H. Ko, S.Y. Park, J.H. Park, J.N. Kim, B.H. Chun, S.H. Kim, Ind. Eng. Chem. Res. 50, 6382 (2011)

    Article  CAS  Google Scholar 

  2. K.S. Kim, S.H. Park, K.T. Park, B.H. Chun, S.H. Kim, Korean J. Chem. Eng. 27, 624 (2010)

    Article  CAS  Google Scholar 

  3. A. Montesinos-Castellanos, E. Lima, J.A. De los Reyes, V. Lara, J Phys Chem C 111,13898 (2007)

  4. Z.E.A. Abdalla, B. Li, Chem. Eng. J. 200–202, 113 (2012)

    Article  Google Scholar 

  5. L. Wang, S. Li, H. Cai, Y. Xu, X. Wu, Y. Chen, Fuel 94, 165 (2012)

    Article  CAS  Google Scholar 

  6. F. Subhan, B.S. Liu, Chem. Eng. J. 178, 69 (2011)

    Article  CAS  Google Scholar 

  7. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature 359, 710 (1992)

    Article  CAS  Google Scholar 

  8. H. Yoshitake, T. Yokoi, T. Tatsumi, Chem. Mater. 15, 1713 (2003)

    Article  CAS  Google Scholar 

  9. N. Gokulakrishnan, A. Pandurangan, T. Somanathan, P.K. Sinha, J. Porous Mater. 17, 763 (2010)

    Article  CAS  Google Scholar 

  10. S. Komarneni, J.Y. Kim, R. Parette, F.S. Cannon, J. Porous Mater. 17, 651 (2010)

    Article  CAS  Google Scholar 

  11. C.C. Pantazis, P.N. Trikalitis, P.J. Pomonis, J. Phys. Chem. B 109, 12574 (2005)

    Article  CAS  Google Scholar 

  12. A. Tuel, Microporous Mesoporous Mater. 27, 151 (1999)

    Article  CAS  Google Scholar 

  13. S. Wang, Y. Shi, X. Ma, Ind. Eng. Chem. Res. 51, 5737 (2012)

    Article  CAS  Google Scholar 

  14. S.C. Shen, S. Kawi, Langmuir 18, 4720 (2002)

    Article  Google Scholar 

  15. Y. Yang, S. Lim, G. Du, Y. Chen, D. Ciuparu, G.L. Haller, J. Phys. Chem. B 109, 13237 (2005)

    Article  CAS  Google Scholar 

  16. H.T. Gomes, P. Selvam, S.E. Dapurkar, J.L. Figueiredo, J.L. Faria, Microporous Mesoporous Mater. 86, 287 (2005)

    Article  CAS  Google Scholar 

  17. W.H. Tian, L.B. Sun, X.L. Song, X.Q. Liu, Y. Yin, G.S. He, Langmuir 26, 17398 (2010)

    Article  CAS  Google Scholar 

  18. P. Wang, Q. Lu, J. Li, Mater. Res. Bull. 45, 129 (2010)

    Article  CAS  Google Scholar 

  19. R. Saad, S. Hamoudi, K. Belkacemi, J. Porous Mater. 15, 315 (2008)

    Article  CAS  Google Scholar 

  20. A.M.B. Furtado, D. Barpaga, L.A. Mitchell, Y. Wang, J.B. Decoste, G.W. Peterson, M.D. Levan, Langmuir 28, 17450 (2012)

    Article  CAS  Google Scholar 

  21. K.K. Sharma, A. Anan, R.P. Buckley, W. Ouellette, T. Asefa, J. Am. Chem. Soc. 130, 218 (2008)

    Article  CAS  Google Scholar 

  22. M. Vasudevan, P.L. Sakaria, A.S. Bhatt, H.M. Mody, H.C. Bajaj, Ind. Eng. Chem. Res. 50, 11432 (2011)

    Article  CAS  Google Scholar 

  23. Y. Wang, R.T. Yang, J.M. Heinzel, Chem. Eng. Sci. 63, 356 (2008)

    Article  CAS  Google Scholar 

  24. Y. Wang, R.T. Yang, J.M. Heinzel, Ind. Eng. Chem. Res. 48, 142 (2009)

    Article  CAS  Google Scholar 

  25. H. Chen, Y. Wang, F.H. Yang, R.T. Yang, Chem. Eng. Sci. 64, 5240 (2009)

    Article  CAS  Google Scholar 

  26. H.Y. Huang, R.T. Yang, D. Chinn, C.L. Munson, Ind. Eng. Chem. Res. 42, 2427 (2003)

    Article  CAS  Google Scholar 

  27. C. Sentorun-Shalaby, S.K. Saha, X. Ma, C. Song, Appl. Catal. B 101, 718 (2011)

    Article  CAS  Google Scholar 

  28. F. Subhan, B.S. Liu, Y. Zhang, X.G. Li, Fuel Process. Technol. 97, 71 (2012)

    Article  CAS  Google Scholar 

  29. Q. Cai, W.Y. Lin, F.S. Xiao, W.Q. Pang, X.H. Chen, B.S. Zou, Microporous Mesoporous Mater. 32, 1 (1999)

    Article  CAS  Google Scholar 

  30. L. Song, T. Bu, L. Zhu, Y. Zhou, Y. Xiang, D. Xia, J. Phys. Chem. C 118, 9468 (2014)

    Article  CAS  Google Scholar 

  31. A.M.B. Furtado, Y. Wang, T.G. Glover, M.D. Levan, Microporous Mesoporous Mater. 142, 730 (2011)

    Article  CAS  Google Scholar 

  32. K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquérol, T. Siemieniewska, Pure Appl. Chem. 57, 603 (1985)

    Article  CAS  Google Scholar 

  33. I. Sobczak, M. Ziolek, M. Renn, P. Decyk, I. Nowak, M. Daturi, J.C. Lavalley, Microporous Mesoporous Mater. 74, 23 (2004)

    Article  CAS  Google Scholar 

  34. M. Kruk, M. Jaroniec, Chem. Mater. 15, 2942 (2003)

    Article  CAS  Google Scholar 

  35. F. Balas, M. Manzano, P. Horcajada, M. Vallet-Regi, J. Am. Chem. Soc. 128, 8116 (2006)

    Article  CAS  Google Scholar 

  36. X. Du, J. He, Langmuir 27, 2972 (2011)

    Article  CAS  Google Scholar 

  37. J. Qiu, K. Zhuang, M. Lu, B. Xu, Y. Fan, Catal. Commun. 31, 21 (2013)

    Article  CAS  Google Scholar 

  38. B.S. Liu, D.F. Xu, J.X. Chu, W. Liu, C.T. Au, Energy Fuels 21, 250 (2007)

    Article  CAS  Google Scholar 

  39. G.A. Eimer, S.G. Casuscelli, G.E. Ghione, M.E. Crivello, E.R. Herrero, Appl. Catal. A 298, 232 (2006)

    Article  CAS  Google Scholar 

  40. Y. Ling, M. Long, P. Hu, Y. Chen, J. Huang, J. Hazard. Mater. 264, 195 (2014)

    Article  CAS  Google Scholar 

  41. D. Rath, K.M. Parida, Ind. Eng. Chem. Res. 50, 2839 (2011)

    Article  CAS  Google Scholar 

  42. M. Chatterjee, T. Iwasaki, H. Hayashi, Y. Onodera, T. Ebina, T. Nagase, Chem. Mater. 11, 1368 (1999)

    Article  CAS  Google Scholar 

  43. J. Kim, P. Seidler, L.S. Wan, C. Fill, J. Colloid Interface Sci. 329, 114 (2009)

    Article  CAS  Google Scholar 

  44. R.Q. Long, R.T. Yang, Ind. Eng. Chem. Res. 38, 873 (1999)

    Article  CAS  Google Scholar 

  45. Z. Ozaydin, S. Yasyerli, G. Dogu, Ind. Eng. Chem. Res. 47, 1035 (2008)

    Article  CAS  Google Scholar 

  46. S. Velu, X. Ma, C. Song, Ind. Eng. Chem. Res. 42, 5293 (2003)

    Article  CAS  Google Scholar 

  47. D. Crespo, G. Qi, Y. Wang, F.H. Yang, R.T. Yang, Ind. Eng. Chem. Res. 47, 1238 (2008)

    Article  CAS  Google Scholar 

  48. X.L. Tang, X. Meng, L. Shi, Ind. Eng. Chem. Res. 50, 7527 (2011)

    Article  CAS  Google Scholar 

  49. W. Turbeville, N. Yap, Catal. Today 116, 519 (2006)

    Article  CAS  Google Scholar 

  50. C.A. Calderón, C. Ojeda, V.A. Macagno, P. Paredes-Olivera, E.M. Patrito, J. Phys. Chem. C 114, 3945 (2010)

    Article  Google Scholar 

Download references

Acknowledgments

The authors thank the National Natural Science Foundation of China (Grant 21376265) for financial support.

Compliance with Ethical Standards

The authors declare no research involving Human Participants and/or Animals. The work described has been approved by all co-authors and the responsible authorities at the institute(s).

Conflict of interest

The authors declare that they have no conflict of interest.

Author information

Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, 266580, People’s Republic of China

    Lechun Song, Jinshe Chen, Yinghui Bian, Lijun Zhu, Yulu Zhou, Yuzhi Xiang & Daohong Xia

Authors
  1. Lechun Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jinshe Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yinghui Bian
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lijun Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yulu Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yuzhi Xiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Daohong Xia
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Daohong Xia.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Song, L., Chen, J., Bian, Y. et al. Synthesis, characterization and desulfurization performance of MCM-41 functionalized with Cu by direct synthesis and organosilanes by grafting. J Porous Mater 22, 379–385 (2015). https://doi.org/10.1007/s10934-014-9906-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-014-9906-4

Keywords

Search

Navigation