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Journal of Porous Materials

, Volume 20, Issue 4, pp 937–949 | Cite as

Porous silica supported Co2+-tetrachlorophthalocyanine (CoPcCl-APTES@SiO2): a novel and recyclable organic–inorganic hybrid catalyst for eco-friendly oxidation of secondary alcohols

  • R. K. Sharma
  • Shikha Gulati
  • Amit Pandey
Article

Abstract

A novel, selective and recyclable cobalt based catalyst has been synthesized by covalent grafting of Co2+-tetrachlorophthalocyanine (CoPcCl) onto porous silica functionalized with 3-aminopropyltriethoxysilane (APTES), and the resulting organic–inorganic hybrid porous material was found to be highly effective catalyst for peroxidative oxidation of secondary alcohols. The porous material was characterized by elemental analysis, diffuse reflectance UV–Visible spectroscopy, 13C CPMAS and 29Si CPMAS NMR spectroscopy, X-ray diffraction (XRD), Scanning electron microscopy (SEM), BET surface area analysis, Energy dispersive X-ray fluorescence (ED-XRF), Fourier transform Infrared (FT-IR) and Atomic absorption spectroscopy (AAS) techniques. High turnover frequency, mild reaction conditions, high selectivity for ketones, and easy recovery and reusability of the catalyst renders the present protocol highly essential to address the industrial needs and environmental concerns.

Keywords

Co2+-tetrachlorophthalocyanine Porous support Silica Immobilization Recyclable catalyst Ketones 

Notes

Acknowledgments

The financial assistance from University Grant Commission, Delhi, India is acknowledged. Due thanks to AIRF, JNU, Delhi, India for SEM analysis and IISc, Bangalore, India for solid state NMR measurements.

Supplementary material

10934_2012_9671_MOESM1_ESM.doc (698 kb)
Supplementary material 1 (DOC 699 kb)

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.Department of Chemistry, Green Chemistry Network CentreUniversity of DelhiDelhiIndia

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