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Synthesis, characterization and catalytic properties of MCM-36 pillared via the MCM-56 precursor

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Abstract

Pillared layered MCM-36 zeolite (MCM-36-I) was successfully synthesized from MCM-56 precursor with polymeric silica as the pillaring agent. The structure and properties of the sample was characterized by means of N2 adsorption, XRD, TEM and IR spectroscopy of pyridine adsorption. The results showed that MCM-36-I has higher external surface area and more Brönsted acidic sites on external surface than that on the MCM-36 sample (MCM-36-II) which was synthesized from layered MCM-22 precursor. The catalytic properties of these samples were tested for alkylation of benzene with isopropanol. Compared with MCM-36-II catalyst, MCM-36-I showed higher conversion of benzene and selectivity to cumene. This should be mainly assigned to the fact that MCM-36-I possesses larger amount of accessible Brönsted acid sites which located on the external surface than that of MCM-36-II.

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References

  1. M. Käldström, N. Kumar, T. Heikkilä, D.Y. Murzin, Appl. Catal. A Gen. 397, 13 (2011)

    Article  Google Scholar 

  2. S. Maheshwari, C. Martínez, M.T. Portilla, F.J. Llopis, A. Corma, M. Tsapatsis, J. Catal. 272, 298 (2010)

    Article  CAS  Google Scholar 

  3. S. Laforge, P. Ayrault, D. Manin, M. Guisnet, Appl. Catal. A Gen. 279, 79 (2005)

    Article  CAS  Google Scholar 

  4. Y.J. He, G.S. Nivarthy, F. Eder, K. Seshan, J.A. Lercher, Microporous Mesoporous Mater. 25, 207 (1998)

    Article  CAS  Google Scholar 

  5. S. Maheshwari, E. Jordan, S. Kumar, F.S. Bates, R.L. Penn, D.F. Shantz, M. Tsapatsis, J. Am. Chem. Soc. 130, 1507 (2008)

    Article  CAS  Google Scholar 

  6. J. Kornatowski, J.O. Barth, K. Erdmann, M. Rozwadowski, Microporous Mesoporous Mater. 90, 251 (2006)

    Article  Google Scholar 

  7. J.O. Barth, J. Kornatowski, J.A. Lercher, J. Mater. Chem. 12, 369 (2002)

    Article  CAS  Google Scholar 

  8. Y. Zhang, H.J. Xing, P.P. Yang, P. Wu, M.J. Jia, J.Z. Sun, T.H. Wu, React. Kinet. Catal. Lett. 90, 45 (2007)

    Article  CAS  Google Scholar 

  9. P. Wu, Q.B. Kan, D.Y. Wang, H.J. Xing, M.J. Jia, T.H. Wu, Catal. Commun. 6, 449 (2005)

    Article  CAS  Google Scholar 

  10. Z.W. Zhang, Y. Zhang, Z.L. Wang, H.J. Xing, M.J. Jia, T.H. Wu, W.X. Zhang, Chin. J. Catal. 29(10), 1015 (2008)

    CAS  Google Scholar 

  11. A.F. Fung, S.L. Lawton, J. Roth. US patent. 5362697 (1994)

  12. G.G. Juttu, R.F. Lobo, Microporous Mesoporous Mater. 40, 9 (2000)

    Article  CAS  Google Scholar 

  13. Y. Wang, Y.M. Liu, L.L. Wang, H.H. Wu, X.H. Li, M.Y. He, P. Wu, J. Phys. Chem. C 113, 18753 (2009)

    Article  CAS  Google Scholar 

  14. A. Corma, U. Diaz, V. Fornés, J.M. Guil, J. Martínez-Triguero, E.J. Creyghton, J. Catal. 191, 218 (2000)

    Article  CAS  Google Scholar 

  15. A. Corma, V. Fornés, J. Martínez-Triguero, S.B. Pergher, J. Catal. 186, 57 (1999)

    Article  CAS  Google Scholar 

  16. A. Corma, V. Fornés, L. Forni, F. Márquez, J. Martínez-Triguero, D. Moscotti, J. Catal. 179(2), 451 (1998)

    Article  CAS  Google Scholar 

  17. M.W. Kasture, P.S. Niphadkar, N. Sharanappa, S.R. Mirajkar, V.V. Bokade, P.N. Joshi, J. Catal. 227, 375 (2004)

    Article  CAS  Google Scholar 

  18. C.A. Emeis, J. Catal. 141, 347 (1993)

    Article  CAS  Google Scholar 

  19. K.S.N. Reddy, B.S. Rao, V.P. Shiralkar, Appl. Catal. A Gen. 95(1), 53 (1993)

    Article  CAS  Google Scholar 

  20. A. Corma, V. Martínez-Soria, E. Schnoeveld, J. Catal. 192, 163 (2000)

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (20773050), the Technological Development Program of Jilin Province (20090590), the open subject of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (2012-15) and The innovation project of frontiers of Science and new interdiscipline of Jilin University.

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Authors and Affiliations

  1. Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Jiefang Road 2519, Changchun, 130021, People’s Republic of China

    Zuowang Zhang, Wanchun Zhu, Mingjun Jia, Wenxiang Zhang & Zhenlu Wang

  2. First Hospital of Jilin University, Changchun, 130021, People’s Republic of China

    Shubo Zai

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  1. Zuowang Zhang
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  2. Wanchun Zhu
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  3. Shubo Zai
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  4. Mingjun Jia
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  5. Wenxiang Zhang
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Correspondence to Zhenlu Wang.

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Zhang, Z., Zhu, W., Zai, S. et al. Synthesis, characterization and catalytic properties of MCM-36 pillared via the MCM-56 precursor. J Porous Mater 20, 531–538 (2013). https://doi.org/10.1007/s10934-012-9625-7

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