Skip to main content
Log in

Synthesis and characterization of activated carbons prepared from benzene CVD on zeolite Y

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

Microporous activated carbons were prepared using zeolite NaY as the template and benzene as the carbon precursor. Chemical vapor deposition of benzene was conducted in the temperature range of 600–950 °C and under different flow rates of benzene. The structural properties of the derived carbons were characterized with various experimental techniques. It was found that the CVD temperature of 650 °C results in carbons with the highest surface area of 1,511 m2/g, a pore volume of 0.93 cm3/g, and a good structural regularity. The higher CVD temperatures (e.g. ~900 °C) were found to result in carbons with lower surface area and poor structural regularity. The increased benzene flow rate will result in carbons with lower surface area and larger pore sizes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. C.O. Ania, V. Khomenko, E. Raymundo-Pinero, J.B. Parra, F. Beguin, Adv. Funct. Mater. 17, 1828 (2007)

    Article  CAS  Google Scholar 

  2. H. Nishihara, P.-X. Hou, L.-X. Li, M. Ito, M. Uchiyama, T. Kaburagi, A. Ikura, J. Katamura, T. Kawarada, K. Mizuuchi, T. Kyotani, J. Phys. Chem. C 113, 3189 (2009)

    Article  CAS  Google Scholar 

  3. C. Guan, F. Su, X.S. Zhao, K. Wang, Sep. Purif. Technol. 64, 124 (2008)

    Article  CAS  Google Scholar 

  4. B. Sakintuna, Y. Yurum, Ind. Eng. Chem. Res. 44, 2893 (2005)

    Article  CAS  Google Scholar 

  5. L. Chen, R.K. Singh, P. Webley, Microporous Mesoporous Mater. 102, 159 (2007)

    Article  CAS  Google Scholar 

  6. T. Kyotani, Z. Ma, A. Tomita, Carbon 41, 1451 (2003)

    Article  CAS  Google Scholar 

  7. Z. Ma, T. Kyotani, A. Tomita, Chem. Commun. 23, 2356 (2000)

    Google Scholar 

  8. F. Su, X.S. Zhao, L. Lv, Z. Zhou, Carbon 42, 2821 (2004)

    Article  CAS  Google Scholar 

  9. Z. Yang, Y. Xia, R. Mokaya, Microporous Mesoporous Mater. 86, 69 (2005)

    Article  CAS  Google Scholar 

  10. K.P. Gierszal, M. Jaroniec, J. Phys. Chem. C 111, 9742 (2007)

    Article  CAS  Google Scholar 

  11. W. Guo, F. Su, X.S. Zhao, Carbon 43, 2423 (2005)

    Article  CAS  Google Scholar 

  12. D.J. Kim, H.I. Lee, J.E. Yie, S.-J. Kim, J.M. Kim, Carbon 43, 1868 (2005)

    Article  CAS  Google Scholar 

  13. T.-W. Kim, R. Ryoo, K.P. Gierszal, M. Jaroniec, L.A. Solovyov, Y. Sakamoto, O. Terasaki, J. Mater. Chem. 15, 1560 (2005)

    Article  CAS  Google Scholar 

  14. F. Su, J. Zeng, X. Bao, Y. Yu, J.Y. Lee, X.S. Zhao, Chem. Mater. 17, 3960 (2005)

    Article  CAS  Google Scholar 

  15. Z. Zhou, Q. Yan, F. Su, X.S. Zhao, J. Mater. Chem. 15, 2569 (2005)

    Article  CAS  Google Scholar 

  16. C. Guan, X. Zhang, K. Wang, C. Yang, Sep. Purif. Technol. 66, 565 (2009)

    Article  CAS  Google Scholar 

  17. P.-X. Hou, H. Orikasa, T. Yamazaki, K. Matsuoka, A. Tomita, N. Setoyama, Y. Fukushima, T. Kyotani, Chem. Mater. 17, 5187 (2005)

    Article  CAS  Google Scholar 

  18. P.-X. Hou, T. Yamazaki, H. Orikasa, T. Kyotani, Carbon 43, 2624 (2005)

    Article  CAS  Google Scholar 

  19. P. Srinivasu, A. Vinu, S. Hishita, T. Sasaki, K. Ariga, T. Mori, Microporous Mesoporous Mater. 108, 340 (2008)

    Article  CAS  Google Scholar 

  20. C. Wang, C. Yan, J. Yao, L. Zhang, N. Xu, X. Liu, J. Porous. Mater. 16, 699 (2009)

    Article  CAS  Google Scholar 

  21. W. Huanlei, G. Qiuming, H. Juan, C. Zhi, Carbon 47, 2259 (2009)

    Article  Google Scholar 

  22. Z. Yang, Y. Xia, R. Mokaya, J. Am. Chem. Soc. 129, 1673 (2007)

    Article  CAS  Google Scholar 

  23. Z. Yang, Y. Xia, X. Sun, R. Mokaya, J. Phys. Chem. B 110, 18424 (2006)

    Article  CAS  Google Scholar 

  24. T. Kyotani, T. Nagai, S. Inoue, A. Tomita, Chem. Mater. 9, 609 (1997)

    Article  CAS  Google Scholar 

  25. J. Parmentier, V. Valtchev, F. Gaslain, L. Tosheva, C. Ducrot-Boisgontier, J. Moler, J. Patarin, C. Vix-Guterl, Carbon 47, 1066 (2009)

    Article  CAS  Google Scholar 

  26. A. Garsuch, O. Klepel, Carbon 43, 2330 (2005)

    Article  CAS  Google Scholar 

  27. A. Garsuch, O. Klepel, R.R. Sattler, C. Berger, R. Glaser, J. Weitkamp, Carbon 44, 593 (2006)

    Article  CAS  Google Scholar 

  28. C. Ducrot-Boisgontier, J. Parmentier, J. Patarin, Microporous Mesoporous Mater. 126, 101 (2009)

    Article  CAS  Google Scholar 

  29. C.J. Meyers, S.D. Shah, S.C. Patel, R.M. Sneeringer, C.A. Bessel, N.R. Dollahon, R.A. Leising, E.S. Takeuchi, J. Phys. Chem. B 105, 2143 (2001)

    Article  CAS  Google Scholar 

  30. L. Song, J.-I. Miyamoto, T. Ohba, H. Kanoh, K. Kaneko, J. Phys. Chem. C 111, 2459 (2007)

    Article  Google Scholar 

  31. T. Kyotani, Bull. Chem. Soc. Jpn. 79, 1322 (2006)

    Article  CAS  Google Scholar 

  32. J. Lee, J. Kim, T. Hyeon, Adv. Mater. 18, 2073 (2006)

    Article  CAS  Google Scholar 

  33. Z. Ma, T. Kyotani, Z. Liu, O. Terasaki, A. Tomita, Chem. Mater. 13, 4413 (2001)

    Article  CAS  Google Scholar 

  34. Z. Ma, T. Kyotani, A. Tomita, Carbon 40, 2367 (2002)

    Article  CAS  Google Scholar 

  35. Y. Kawabuchi, S. Kawano, I. Mochida, Carbon 34, 711 (1996)

    Article  CAS  Google Scholar 

  36. F. Su, J. Zeng, Y. Yu, L. Lv, J.Y. Lee, X.S. Zhao, Carbon 43, 2366 (2005)

    Article  CAS  Google Scholar 

  37. H. Wilhelm, M. Lelaurain, J. Appl. Phys. 84, 6552 (1998)

    Article  CAS  Google Scholar 

  38. F. Tuinstra, J.L. Koenig, J. Chem. Phys. 53, 1126 (1970)

    Article  CAS  Google Scholar 

  39. A.A. Zakhidov, R.H. Baughman, Z. Iqbal, C. Cui, I. Khayrullin, S.O. Dantas, J. Marti, V.G. Ralchenko, Science 282, 897 (1998)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Song, X.H., Teo, W.S. & Wang, K. Synthesis and characterization of activated carbons prepared from benzene CVD on zeolite Y. J Porous Mater 19, 211–215 (2012). https://doi.org/10.1007/s10934-011-9462-0

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-011-9462-0

Keywords

Navigation