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Novel nanocasting method for synthesis of ordered mesoporous metal oxides

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Abstract

Novel one-step high vacuum nanocasting method is developed to prepare ordered mesoporous rare earth and transition metal oxides with high-surface area using mesoporous KIT-6 as hard templates. Characterization of these mesostructured materials was performed by the X-ray powder diffraction, high resolution transmission electron microscopy and N2 adsorption–desorption isotherms. In this synthesis method, metal oxide precursors are effectively filled into the channels of hard templates by a one-step high vacuum impregnation, and the excess precursors can be removed through vacuum filtration. It is a very effective nanocasting method and has the wider application in the preparation of mesoporous metal oxides with high surface area and high purity.

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Acknowledgment

We thank National Natural Science Foundation of China (No. 20971044) and key project of Shanghai Science and Technology Committee ((Nos. 05JC14070, 06DZ05025 and 08JC1408600) for financial support.

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Authors and Affiliations

  1. Department of Chemistry, East China Normal University, 200062, ShangHai City, China

    AiGuo Kong, HaiYan Zhu, WenJuan Wang, QiYing Zhang, Fan Yang & YongKui Shan

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  1. AiGuo Kong
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  2. HaiYan Zhu
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  3. WenJuan Wang
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  4. QiYing Zhang
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  5. Fan Yang
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  6. YongKui Shan
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Correspondence to YongKui Shan.

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Kong, A., Zhu, H., Wang, W. et al. Novel nanocasting method for synthesis of ordered mesoporous metal oxides. J Porous Mater 18, 107–112 (2011). https://doi.org/10.1007/s10934-010-9361-9

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  • DOI: https://doi.org/10.1007/s10934-010-9361-9

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