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A fast and efficient method for the removal of hexavalent chromium from aqueous solutions

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Abstract

In this study, removal of chromium (VI) from aqueous solution by as-synthesized MCM-48 adsorbent was studied. Cetyltrimethylammonium bromide (CTAB) was used as a cationic template for the synthesis of MCM-48. The extent of adsorption was investigated as a function of solution pH, agitation speed, contact time, adsorbent and adsorbate concentrations, reaction temperature and supporting electrolyte (sodium chloride). Langmuir and Freundlich isotherms were used to model the adsorption equilibrium data. The adsorption of Cr (VI) is found to be maximum at pH values in the range of 1–3. The yielded maximum adsorption capacity of 153.8 mg/g at initial concentration of 800 (mg/L) is well predicted by of the Langmuir isotherm. Compared to the various adsorbents reported in the literature, the surfactant-containing material prepared in this study showed promise for practical applications.

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References

  1. S.J. Kohler, P. Cubillas, J.D. Rodr-lguez-Blanco, C. Bauer, M. Prieto, Environ. Sci. Technol. 41, 112 (2007)

    Article  Google Scholar 

  2. S.D. Kim, K.S. Park, M.B. Gu, J. Hazard. Mater. A 93, 155 (2002)

    CAS  Google Scholar 

  3. G. Donmez, Z. Aksu, Process Biochem. 38, 751 (2002)

    Article  CAS  Google Scholar 

  4. T. Wang, Z. Li, J. Hazard. Mater. B 112, 63 (2004)

    Article  CAS  Google Scholar 

  5. D. Pmila, P.S. Subbaiyan, M. Ramaswamy, Ind. J. Environ. HITH 33, 218 (1991)

    Google Scholar 

  6. S.B. Lalvani, T. Wiltowski, A. Hubner, A. Weston, N. Mandich, Carbon 36, 1219 (1998)

    Article  CAS  Google Scholar 

  7. A. Ozer, H.S. Altundogan, M. Erdem, F. Tumen, Environ. Pollut. 97, 107 (1997)

    Article  CAS  Google Scholar 

  8. M. Lotfi, N. Adhoum, Sep. Purif. Technol. 26, 137 (2002)

    Article  Google Scholar 

  9. C. Namasivayam, R.T. Yamuna, Chemosphere 30, 561 (1995)

    Article  CAS  Google Scholar 

  10. S. Rengaraj, C.K. Joo, Y. Kim, J. Yi, J. Hazard. Mater. B 102, 257 (2003)

    Article  CAS  Google Scholar 

  11. R. Mauri, R. Shinnar, M.D. Amore, P. Giordano, A. Volpe, AIChE J. 47, 509 (2001)

    Article  CAS  Google Scholar 

  12. A.P. Padilla, E.L. Tavani, Desalination 129, 219 (1999)

    Article  Google Scholar 

  13. D. Mohan, K.P. Singh, V.K. Singh, Ind. Eng. Chem. Res. 44, 1027 (2005)

    Article  CAS  Google Scholar 

  14. T. Karthikeyan, S. Rajgopal, L.R. Miranda, J. Hazard. Mater. B 124, 192 (2005)

    Article  CAS  Google Scholar 

  15. Z. Hu, L. Lei, Y. Li, Y. Ni, Sep. Purif. Technol. 31, 13 (2003)

    Article  CAS  Google Scholar 

  16. S.B. Laluani, T. Wiltowski, A. Hubner, A. Weston, N. Mandich, Carbon 36, 1216 (1998)

    Google Scholar 

  17. A. Chakir, J. Bessiere, K. Kacemi, B. Marouf, J. Hazard. Mater. 95, 29 (2002)

    Article  CAS  Google Scholar 

  18. S.S. Baral, S.N. Das, P. Rath, Biochem. Eng. J. 31, 216 (2006)

    Article  CAS  Google Scholar 

  19. S. Mor, K. Ravindra, N.R. Bishnoi, Bioresour. Technol. 98, 954 (2007)

    Article  CAS  Google Scholar 

  20. V. Gupta, A. Shrivastava, N. Jain, Water Res. 35, 4079 (2001)

    Article  CAS  Google Scholar 

  21. J. Melo, S. Dsouza, Bioresour. Technol. 92, 151 (2004)

    Article  CAS  Google Scholar 

  22. R. Bai, T. Abraham, Bioresour. Technol. 87, 17 (2003)

    Article  Google Scholar 

  23. Z. Aksu, U. Acikel, E. Kabasakal, S. Teze, Water Res. 36, 3063 (2002)

    Article  CAS  Google Scholar 

  24. A. Celik, K. Dost, H. Sezer, Fresenius Environ. Bull. 13, 124 (2004)

    CAS  Google Scholar 

  25. A. Baran, E. Bicak, S.H. Baysal, S. Onal, Bioresour. Technol. 98, 661 (2006)

    Article  Google Scholar 

  26. N. Sankararamakrishnan, A. Dixit, L. Iyengar, R. Sanghi, Bioresour. Technol. 97, 2377 (2006)

    CAS  Google Scholar 

  27. L. Yu, S. Shukla, K. Dorris, A. Shukla, J. Margrave, J. Hazard. Mater. B 100, 53 (2003)

    Article  CAS  Google Scholar 

  28. C. Raji, T. Anirudhan, Water Res. 32, 3772 (1998)

    Article  CAS  Google Scholar 

  29. M. Rao, A. Parwate, A. Bhole, Waste Manage. 22, 821 (2002)

    Article  CAS  Google Scholar 

  30. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature 359, 710 (1992)

    Article  CAS  Google Scholar 

  31. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J.L. Schlenker, J. Am. Chem. Soc. 114, 10834 (1992)

    Article  CAS  Google Scholar 

  32. M. Ghiaci, R. Kia, A. Abbaspur, F. Seyedeyn-Azad, Sep. Purif. Technol. 40, 285 (2004)

    Article  CAS  Google Scholar 

  33. L. Bois, B. Anne, R. Annie, Colloids Surf. A Physicochem. Eng. Asp. 221, 221 (2003)

    Article  CAS  Google Scholar 

  34. M. Anbia, S.E. Moradi, Chem. Eng. J. 148, 452 (2009)

    Article  CAS  Google Scholar 

  35. M. Anbia, K. Mohammadi, Chin. J. Chem. 26, 2051 (2008)

    Article  CAS  Google Scholar 

  36. M. Anbia, M.K. Rofouei, S.W. Husain, Asian J. Chem. 19, 3862 (2007)

    CAS  Google Scholar 

  37. M. Anbia, M.K. Rofouei, S.W. Husain, Chin. J. Chem. 24, 1026 (2006)

    Article  CAS  Google Scholar 

  38. M. Anbia, M.K. Rofouei, S.W. Husain, J. Iran Chem. Soc. 2, 54 (2005)

    Google Scholar 

  39. H. Kosslick, G. Lischke, H. Landmesser, B. Parlitz, W. Storek, R. Fricke, J. Catal. 176, 102 (1998)

    Article  CAS  Google Scholar 

  40. P.T. Tanev, T.J. Pinnavaia, Chem. Mater. 8, 2068 (1996)

    Article  CAS  Google Scholar 

  41. Y. Shao, L. Wang, J. Zhang, M. Anpo, Microporous Mesoporous Mater. 86, 314 (2005)

    Article  CAS  Google Scholar 

  42. A.D. Eaton, L.S. Clesceri, A.E. Greenberg, Standard Methods for the Examination of Water and Wastewater (American Public Health Association, Washington, DC, 1995), pp. 225–257

    Google Scholar 

  43. V. Alfredsson, M.W. Anderson, Chem. Mater. 8, 1141 (1996)

    Article  CAS  Google Scholar 

  44. J. Xu, Z. Luan, M. Hartmann, L. Kevan, Chem. Mater. 11, 2928 (1999)

    Article  CAS  Google Scholar 

  45. R.A. Pierotti, J. Rouquerol, T. Siemieniewska, J. Pure Appl. Chem. 57, 603 (1985)

    Article  Google Scholar 

  46. K. Selvaraj, S. Manonmani, S. Pattabhi, Bioresour. Technol. 89, 207 (2003)

    Article  CAS  Google Scholar 

  47. N.R. Bishnoi, M. Bajaj, N. Sharma, A. Gupta, Bioresour. Technol. 91, 305 (2004)

    Article  CAS  Google Scholar 

  48. K.K. Sing, R. Rastogi, S.H. Hason, J. Colloid Interface Sci. 290, 61 (2005)

    Article  Google Scholar 

  49. Y.C. Sharma, C.H. Weng, J. Hazard. Mater. 142, 449 (2007)

    Article  CAS  Google Scholar 

  50. K.K. Deepa, M. Sathishkumar, A.R. Binupriya, G.S. Murugesan, K. Swaminathan, S.E. Yun, Chemosphere 62, 833 (2006)

    Article  CAS  Google Scholar 

  51. Y.C. Sharma, J. Colloid Interface Sci. 233, 265 (2001)

    Article  CAS  Google Scholar 

  52. G.H. Pino, L.M.S. de Mesquita, M.L. Torem, G.A.S. Pinto, Sep. Sci. Technol. 41, 3141 (2006)

    Article  CAS  Google Scholar 

  53. G.S. Agarwal, H.K. Bhuptawat, S. Chaudhari, Bioresour. Technol. 97, 949 (2006)

    Article  CAS  Google Scholar 

  54. M. Dakiky, M. Khamis, A. Manassra, M. Mer’eb, Adv. Environ. Res. 6, 533 (2002)

    Article  CAS  Google Scholar 

  55. C. Namasivayam, D. Sangeetha, Toxicol. Environ. Chem. 88, 219 (2006)

    Article  CAS  Google Scholar 

  56. C.H. Weng, J.H. Wang, C.P. Huang, Water Sci. Technol. 35, 55 (1997)

    CAS  Google Scholar 

  57. X.S. Wang, Y. Qin, J. Hazard. Mater. B 138, 582 (2006)

    Article  CAS  Google Scholar 

  58. Z.C. Di, J. Ding, X.J. Peng, Y.H. Li, Z.K. Luan, J. Liang, Chemosphere 62, 861 (2006)

    Article  CAS  Google Scholar 

  59. J. Hu, I.M.C. Lo, G. Chen, Langmuir 21, 11173 (2005)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Research council of Iran University of Science and Technology (IUST, Iran) as well as Iranian Nanotechnology Initiative Council are acknowledged for the financial support.

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Correspondence to Mansoor Anbia.

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Anbia, M., Mohammadi, N. A fast and efficient method for the removal of hexavalent chromium from aqueous solutions. J Porous Mater 18, 13–21 (2011). https://doi.org/10.1007/s10934-009-9351-y

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