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Synthesis of highly ordered mesoporous silica thin films for nano-fabrication of platinum nanodot arrays

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Abstract

Mesoporous silica thin films with highly ordered cubic Pm-3n and three dimensional hexagonal P63/mmc symmetries were synthesized by evaporation induced self assembly (EISA) method controlling the ratio of HCl and tetramethoxysilane in the initial sol solution and the humidity in the dip-coating chamber. Using these optimized mesoporous silica thin films, highly ordered Pt nanodot arrays with cubic and three dimensional hexagonal symmetries were synthesized by simple immersion in a Pt precursor solution and photoreduction. These periodic nanodot arrays in the silica thin film have a potential to be applied to single-electron devices mediated by coupling interactions with neighboring nanodots.

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Authors and Affiliations

  1. Toyota Central R&D Labs., Inc., 41-1 Yokomichi Nagakute, Aichi, 480-1192, Japan

    Yoko Kumai, Noriaki Sugimoto, Hiroshi Tsukada & Shinji Inagaki

Authors
  1. Yoko Kumai
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  2. Noriaki Sugimoto
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  3. Hiroshi Tsukada
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  4. Shinji Inagaki
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Correspondence to Yoko Kumai.

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Kumai, Y., Sugimoto, N., Tsukada, H. et al. Synthesis of highly ordered mesoporous silica thin films for nano-fabrication of platinum nanodot arrays. J Porous Mater 17, 529–534 (2010). https://doi.org/10.1007/s10934-009-9321-4

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  • DOI: https://doi.org/10.1007/s10934-009-9321-4

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