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Hydroxyapatite coating on titanium surface with titania nanotube layer and its bond strength to substrate

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Abstract

A vertically aligned titania nanotube layer on titanium surface was prepared by electrochemical anodic oxidation in an F−-containing electrolyte, followed by annealing at 450 °C. Bioactive hydroxyapatite (HA) coatings on as anodized titania nanotube layer were obtained by a biomimetic method without other surface treatment. The morphology, crystal structure, and components of the titania nanotube layer and bioactive coatings were examined by scanning electron microscopy, thin film X-ray diffraction, and Fourier transform infrared spectroscopy. The bond strength between the HA coatings and substrates was tested using a mechanical tester. The diameter of the titania nanotubes was about 100 nm, the wall thickness about 19 nm and the height about 1 μm. HA rapidly deposited on the as anodized nanotube surface after immersion in a biomineral solution only for 1 day. The HA coatings were carbonated apatite and composed of a number of column-like crystals with nanometer size. Tensile test shows that the bond strength between the HA coating and the nanotube layer was larger than 15.3 MPa.

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Acknowledgments

This work was financially supported by the Chinese NSFC (50871093), FANEDD (200554), and National Key Project of Scientific and Technical Supporting Programs Funded by MSTC (2006BAI16B01).

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Authors and Affiliations

  1. Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, People’s Republic of China

    Bo Feng, Xueji Chu, Jianxin Wang, Xiong Lu & Jie Weng

  2. State Key Lab of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, 730000, People’s Republic of China

    Jianmin Chen

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  1. Bo Feng
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  2. Xueji Chu
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  3. Jianmin Chen
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Correspondence to Bo Feng.

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Feng, B., Chu, X., Chen, J. et al. Hydroxyapatite coating on titanium surface with titania nanotube layer and its bond strength to substrate. J Porous Mater 17, 453–458 (2010). https://doi.org/10.1007/s10934-009-9307-2

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  • DOI: https://doi.org/10.1007/s10934-009-9307-2

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