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Temperature programmed desorption of n-hexane and n-heptane from MFI and FAU zeolites

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Abstract

TPD studies of n-hexane and n-heptane from NaX, Y and ZSM-5 (Na+ or H+ exchanged) in the experimental system with a TCD detector were performed, using pure He or He/n-alkane mixture as a carrier gas. The TPD profiles with one desorption peak for Y and two peaks for ZSM-5, measured using He/hydrocarbon mixture, were similar to the previously reported equilibrated thermodesorption results. TPD profiles were accurately fitted with a model based on the equilibrium control of the desorption and the adsorption functions derived from the Langmuir or dual site Langmuir isotherms.

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Authors and Affiliations

  1. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060, Krakow, Poland

    Wacław Makowski

  2. Regional Laboratory for Physicochemical Analyses and Structural Research, Jagiellonian University, Ingardena 3, 30-060, Krakow, Poland

    Dorota Majda

Authors
  1. Wacław Makowski
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  2. Dorota Majda
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Correspondence to Wacław Makowski.

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Makowski, W., Majda, D. Temperature programmed desorption of n-hexane and n-heptane from MFI and FAU zeolites. J Porous Mater 14, 27–35 (2007). https://doi.org/10.1007/s10934-006-9004-3

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  • DOI: https://doi.org/10.1007/s10934-006-9004-3

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