Skip to main content
SpringerLink
Log in

Synthesis and characterization of highly ordered mesoporous YSZ by tri-block copolymer

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

A highly ordered mesoporous yttria-stabilized zirconia (YSZ) has been successfully prepared by evaporation-induced self-assembly method (EISA) using tri-block copolymer Pluronic F127 as a structure-directing agent and inorganic chlorides as precursors in a non-aqueous medium. The characterization of the mesoporous YSZ materials was carried out by using small angle X-ray diffraction (SAXRD), transmission electron microscopy (TEM) and N2 adsorption/desorption. The well ordered mesoporous YSZ is thermally stable up to 600∘C with an average pore size of 5.4 nm and specific surface area of 90 m2/g. The walls of mesoporous YSZ are composed of ∼6.5 nm nano-crystalline domains.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, and J.S. Beck, Nature 359, 710 (1992).

    Article  CAS  Google Scholar 

  2. J.S. Beck, J.C.Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, and J.L. Schlenker, J. Am. Chem. Soc. 114, 10834 (1992).

    Article  CAS  Google Scholar 

  3. P. Yang, D. Zhao, D.I. Margolese, B.F. Chmelka, and G.D. Stucky, Nature 396, 152 (1998).

    Article  CAS  Google Scholar 

  4. K.M. Coakley, Y. Liu, M.D. McGehee, K.L. Frindell, and G.D. Stucky, Adv. Fuct. Mater. 13, 301 (2003).

    Article  CAS  Google Scholar 

  5. X. Xu, B. Tian, J. Kong, S. Zhang, B. Liu, and D. Zhao, Adv. Mater. 15, 1932 (2003).

    Article  CAS  Google Scholar 

  6. Z. Peng, Z. Shi, and M. Liu, Chem. Commun. 21, 2125 (2000).

    Article  Google Scholar 

  7. M. Mamak, N. Coombs, and G.A. Ozin, Adv. Funct. Mater. 11, 59 (2001).

    Article  CAS  Google Scholar 

  8. L.G. Teoh, I.M. Hung, J. Shieh, W.H. Lai, and M.H. Hon, Electrochemical and Solid-State Letters 6, G108 (2003).

    Article  CAS  Google Scholar 

  9. A. Sayari and P. Liu, Microporous Mater. 12, 149 (1997).

    Article  CAS  Google Scholar 

  10. F. Schuth, Chem. Mater. 13, 3184 (2001).

    Article  Google Scholar 

  11. E.L. Crepaldi, G.J. de A.A. Soler Illia, D. Grosso, and C. Sanchez, New J. Chem. 27, 9 (2003).

    Article  CAS  Google Scholar 

  12. N.Q. Minh, J. Am. Ceram. Soc. 76, 563 (1993).

    Article  CAS  Google Scholar 

  13. Z.Y. Can, H. Narita, J. Mizusaki, and H. Tagawa, Solid State Ionics 79, 344 (1995).

    Article  CAS  Google Scholar 

  14. H.C. Yao and Y.F.Y. Yao, J. Catal. 86, 254 (1984).

    Article  CAS  Google Scholar 

  15. M. Mamak, N. Coombs, and G. Ozin, Adv. Mater. 12, 198 (2000).

    Article  CAS  Google Scholar 

  16. F. Chen and M. Liu, J. Mater. Chem. 10, 2603 (2000).

    Article  CAS  Google Scholar 

  17. Y. Wang, L. Yin, O. Palchik, Y.R. Hacohen, Y. Koltypin, and A. Gedanken, Chem. Mater. 13, 1248 (2001).

    Article  CAS  Google Scholar 

  18. E.L. Crepaldi, G.J. de A. A. Soler Illia, A. Bouchara, D. Grosso, D. Durand, and C. Sanchez, Angew. Chem. Int. Ed. 42, 347 (2003).

    Article  CAS  Google Scholar 

  19. C.J. Brinker, Y. Lu, A. Sellinger, and H. Fan, Adv. Mater. 11, 579 (1999).

    Article  CAS  Google Scholar 

  20. B.D. Cullity, Elements of X-ray Diffraction (Addison-Wesley, California, 1978) p. 284.

    Google Scholar 

  21. S.J. Gregg and K.S.W. Sing, Adsorption, Surface Area and Porosity (Academic press, London, 1982) p. 4.

    Google Scholar 

  22. E.L. Crepaldi, G.J. de A.A. Soler Illia, D. Grosso, F. Cagnol, F. Ribot, and C. Sanchez, J. Am. Chem. Soc. 125, 9770 (2003).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, National Cheng Kung University, No. 1, Dashiue Road, Dung Chiu, Tainan, 701, Taiwan

    I-Ming Hung, De-Tsai Hung, Kuan-Zong Fung & Min-Hsiung Hon

  2. Dayeh University, 112 Shan-Jiau Road, Da-Tsuen, Changhua, 515, Taiwan

    Min-Hsiung Hon

Authors
  1. I-Ming Hung
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. De-Tsai Hung
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kuan-Zong Fung
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Min-Hsiung Hon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kuan-Zong Fung.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hung, IM., Hung, DT., Fung, KZ. et al. Synthesis and characterization of highly ordered mesoporous YSZ by tri-block copolymer. J Porous Mater 13, 225–230 (2006). https://doi.org/10.1007/s10934-006-8008-3

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-006-8008-3

Keywords

Search

Navigation