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LCA to Evaluate the Environmental Impact for Chemical Pre-treatment in Plastics Metallization

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Abstract

The life cycle assessment methodology was used to calculate the environmental impacts of the current chemical pre-treatment with chromium(VI) for electroplating acrylonitrile butadiene styrene. The inventory comprised: the procurement of chemicals; the manufacturing process with successive baths and rinses that requires, in addition to chemicals, energy to heat baths, air agitation, filtration, and so forth, wastewater treatment and air emissions; and also the treatment of sludges from wastewater treatment and exhausted baths. Chromic acid was almost the unique responsible of eco-toxicity (97.5 %) and human toxicity-cancer (99.8 %) and it was one of the highest contributor to climate change, cumulative energy demand, fossil fuel depletion, human toxicity non-cancer, and in abiotic depletion.

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References

  1. EC (2006) Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/4. European Union, Brussels

    Google Scholar 

  2. Olivera S, Muralidhara HB, Venkatesh K et al (2016) Plating on acrylonitrile–butadiene–styrene (ABS) plastic: a review. J Mater Sci 51:3657–3674. doi:10.1007/s10853-015-9668-7

    Article  CAS  Google Scholar 

  3. Harscoet E, Froelich D (2008) Use of LCA to evaluate the environmental benefits of substituting chromic acid anodizing (CAA). J Clean Prod 16:1294–1305. doi:10.1016/j.jclepro.2007.06.010

    Article  Google Scholar 

  4. Serres N, Hlawka F, Costil S et al (2009) Dry coatings and ecodesign part. 1—environmental performances and chemical properties. Surf Coat Technol 204:187–196. doi:10.1016/j.surfcoat.2009.07.012

    Article  CAS  Google Scholar 

  5. Garcia-Alonso D, Serres N, Demian C et al (2011) Pre-/during-/post-laser processes to enhance the adhesion and mechanical properties of thermal-sprayed coatings with a reduced environmental impact. J Therm Spray Technol 20:719–735. doi:10.1007/s11666-011-9629-x

    Article  Google Scholar 

  6. Benveniste G, Baldo GL, Perucca M, Ruggeri B (2007) LCA comparative analysis of different technologies for surface functionalism. In: 3rd international conference on life cycle management 6

  7. Jugy C, Jacquemin L, Villemur C et al (2016) Methodology for evaluating the sustainability of products and processes: application to alternative substitution techniques of chromium VI. Int J Interact Des Manuf 10:329–334. doi:10.1007/s12008-016-0324-5

    Article  Google Scholar 

  8. Garraín D, Vidal R, Franco V, Martínez P (2008) LCA of surface coating processes of thermoplastics. 2nd international seminar on society & materials, SAM2

  9. Garraín D, Vidal R, Martínez P (2010) Análisis del Ciclo de Vida de los Procesos de Recubrimiento Metálico de Termoplásticos. Inf Tecnológica 21:59–64. doi:10.1612/inf.tecnol.4118it.08

    Google Scholar 

  10. Bayus J, Ge C, Thorn B (2016) A preliminary environmental assessment of foil and metallized film centered laminates. Resour Conserv Recycl 115:31–41. doi:10.1016/j.resconrec.2016.08.024

    Article  Google Scholar 

  11. Espinosa N, García-Valverde R, Urbina A et al (2012) Life cycle assessment of ITO-free flexible polymer solar cells prepared by roll-to-roll coating and printing. Sol Energ Mater Sol Cells 97:3–13. doi:10.1016/j.solmat.2011.09.048

    Article  CAS  Google Scholar 

  12. ISO E (2006) Environmental management. Life cycle assessment. Principles and framework (14040: 2006)

  13. ISO E (2006) Environmental management. Life cycle assessment. Requierements and guidelines (14044: 2006)

  14. McCaskie JE (2006) Plating on plastics. Met Finish 104:31–39. doi:10.1016/S0026-0576(06)80204-7

    Article  CAS  Google Scholar 

  15. Cohen RL, West KW (1973) Generative and stabilizing processes in tin-palladium sols and palladium sol sensitizers. J Electrochem Soc 120:502. doi:10.1149/1.2403486

    Article  CAS  Google Scholar 

  16. Matijević E, Poskanzer AM, Zuman P (1975) The characterization of the stannous chloride/palladium chloride catalysts for electroless plating. Plat Surf Finish 61:958–965

    Google Scholar 

  17. Cui X, Hutt DA, Scurr DJ, Conway PP (2011) The evolution of Pd/Sn catalytic surfaces in electroless copper deposition. J Electrochem Soc 158:D172. doi:10.1149/1.3536543

    Article  CAS  Google Scholar 

  18. Althaus H-J, Chudacoff M, Hischier R et al (2007) Life cycle inventories of chemicals. Final rep. ecoinvent data v2. 0 No 8:

  19. Burger B, Bauer C (2007) Final report ecoinvent No. 6-XIII. Paul Scherrer Institut Villigen, Swiss Centre for Life Cycle Inventories: Dübendorf

  20. Classen M, Althaus H-J, Blaser S, et al (2009) Life Cycle Inventories of Metals. Dübendorf, Switzerland

  21. Frischknecht R, Tuchschmid M, Faist Emmenegger M et al (2007) Strommix und stromnetz. Sachbilanzen von Energiesystemen. Final Rep. Ecoinvent v2. 0 No. 6Swiss Cent. Life Cycle Invent. Dübendorf, Villigen, Switz

  22. Jungbluth N (2007) Erdöl. Sachbilanzen von Energiesystemen: Grundlagen für den ökologischen Vergleich von Energiesystemen und den Einbezug von Energiesystemen in Ökobilanzen für die Schweiz. Ecoinvent report

  23. Kowalski Z, Kulczycka J, Wzorek Z (2007) Life cycle assessment of different variants of sodium chromate production in Poland. J Clean Prod 15:28–37. doi:10.1016/j.jclepro.2005.05.026

    Article  Google Scholar 

  24. EC (2006) Directive 2006/122/EC of the European Parliament and of the Council of 12 December 2006 amending for the 30th time Council Directive 76/769/EEC on the approximation of the laws, regulations and administrative provisions of the Member States relating to re. Strasbourg

  25. EC (2006) Reference document on best available techniques for the surface treatment of plastic and metals using electrolytic or chemical process

  26. Medio Ambiente DE (2009) Guía de Mejores Técnicas Disponibles en España del Sector de Tratamiento de Superficies Metálicas y Plásticas 2009. MARM

  27. IDAE (2007) Guía técnica para el diseño y cálculo del aislamiento térmico de conducciones, aparatos y equipos. Madrid

  28. IHOBE (1997) Libro Blanco para la minimización de Residuos y emisiones. Recubrimientos electrolíticos. IHOBE, Madrid

    Google Scholar 

  29. Poulsen PB, Gram LK, Jensen AA et al (2011) Substitution of PFOS for use in non-decorative hard chrome plating. Environmental Protection Agency, Washington

    Google Scholar 

  30. EPA (1991) Chemical engineering branch manual for the preparation of engineering assessments. Cincinnati

  31. Sander R (1999) Compilation of Henry’s law constants for inorganic and organic species of potential importance in environmental chemistry

  32. Wang LK, Yung-Tse H, Nazih KS (2009) Handbook of advanced industrial and hazardous wastes treatment. CRC Press Book, Boca Raton

    Book  Google Scholar 

  33. Doka G (2009) Life cycle inventories of waste treatment services. Dübendorf

  34. Rosenbaum R, Bachmann T, Gold L et al (2008) USEtox—the UNEP-SETAC toxicity model: recommended characterisation factors for human toxicity and freshwater ecotoxicity in life cycle impact assessment. Int J Life Cycle Assess 13:532–546. doi:10.1007/s11367-008-0038-4

    Article  CAS  Google Scholar 

  35. Hauschild MZ, Goedkoop M, Guinée J et al (2013) Identifying best existing practice for characterization modeling in life cycle impact assessment. Int J Life Cycle Assess 18:683–697. doi:10.1007/s11367-012-0489-5

    Article  CAS  Google Scholar 

  36. Pizzol M, Christensen P, Schmidt J, Thomsen M (2011) Impacts of “metals” on human health: a comparison between nine different methodologies for Life Cycle Impact Assessment (LCIA). J Clean Prod 19:646–656. doi:10.1016/j.jclepro.2010.05.007

    Article  CAS  Google Scholar 

  37. Guinee JB (2002) Handbook on life cycle assessment operational guide to the ISO standards. Int J Life Cycle Assess 7:311–313. doi:10.1007/BF02978897

    Article  Google Scholar 

  38. Frischknecht R, Jungbluth N, Althaus H-J et al (2004) The ecoinvent database: overview and methodological framework (7 pp). Int J Life Cycle Assess 10:3–9. doi:10.1065/lca2004.10.181.1

    Article  Google Scholar 

  39. Forster P, Ramaswamy V, Artaxo P et al (2007) Changes in atmospheric constituents and in radiative forcing. In: Solomon S, Qin D, Manning M, Chen Z, et al (eds) Climate change 2007: the physical science basis. Cambridge University Press.

  40. Cherubini F, Strømman AH (2011) Life cycle assessment of bioenergy systems: state of the art and future challenges. Bioresour Technol 102:437–451. doi:10.1016/j.biortech.2010.08.010

    Article  CAS  Google Scholar 

  41. US EPA (1996) Emission factor documentation for AP-42 section 12.20. United States Environmental Protection Agency, Washington

    Google Scholar 

  42. Kuo YM, Sen Wang C (2002) Effect of rise distance on droplets generated from bubble bursting on the surface of chromic acid solutions. Am Ind Hyg Assoc J 63:5–10

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Authors gratefully appreciate the financial support from Eco-innovation Initiative of the European Union for the project ECO/11/304394 “Cost effective industrialization of an eco-friendly pre-treatment for plastic chrome plating using self-assembly nanotechnology”.

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Correspondence to Rosario Vidal.

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Vidal, R., Alberola-Borràs, JA., Gómez-Cordón, J. et al. LCA to Evaluate the Environmental Impact for Chemical Pre-treatment in Plastics Metallization. J Polym Environ 25, 961–972 (2017). https://doi.org/10.1007/s10924-016-0872-6

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