Journal of Polymers and the Environment

, Volume 21, Issue 1, pp 160–165 | Cite as

Preparation and Application of PEG/PVP Copolymers

  • Yin-Chun Chao
  • Shuenn-Kung Su
  • Ya-Wun Lin
  • Wan-Ting Hsu
  • Kuo-Shien Huang
Original Paper

Abstract

In this study, we produced a series of environmentally friendly multifunctional additives by polymerization of biodegradable polyethylene glycol (PEG) and N-Vinyl-2-pyrrolidone in different proportions. The copolymer molecular structure was confirmed by Fourier transform infrared spectroscopy, and the impact of the copolymers on dye absorption and dye interaction was investigated. The results showed that the series of copolymers produced displayed enhanced dye decolorization with increasing copolymer dose and time. Additionally, the PEG/polyvinylpyrrolidone (PVP) copolymers and dye molecules interacted; addition of copolymer enabled shifts of the dye λmax toward shorter wavelengths and decreased the UV absorbance. The addition of copolymers reduced the overall Zeta potential of the dye and increased the particle sizes, facilitating dye decolorization. In particular, the dye decolorization effect was the best when the PEG/PVP molar ratio was 8:1.

Keywords

Polyethylene glycol Biodegradable material Compound Decolorization 

References

  1. 1.
    Rivard C (1991) J Environ Health 53(4):24–26Google Scholar
  2. 2.
    Jiao J, Xiao M, Shu D, Li L, Meng YZ (2006) J Appl Polym Sci 102(6):5240–5247CrossRefGoogle Scholar
  3. 3.
    Wang XL, Du FG, Jiao J, Meng YZ, Li RKY (2007) J Biomed Mater Res B Appl Biomater 83(2):373–379Google Scholar
  4. 4.
    Ge XC, Li XH, Zhu Q, Li L, Meng YZ (2004) Polym Eng Sci 44(11):2134–2140CrossRefGoogle Scholar
  5. 5.
    Inui O, Teramura Y, Iwata H (2010) ACS Appl Mater Interfaces 2(5):1514–1520CrossRefGoogle Scholar
  6. 6.
    Zhao A, Zhou Q, Chen T, Weng J, Zhou S (2010) J Appl Polym Sci 118(6):3576–3585CrossRefGoogle Scholar
  7. 7.
    Sawant RR, Torchilin VP (2010) Methods Mol Biol 624:131–149CrossRefGoogle Scholar
  8. 8.
    Mangold C, Wurm F, Obermeier B, Frey H (2010) Macromolecules 43(20):8511–8518CrossRefGoogle Scholar
  9. 9.
    Naguib HF, Aziz MSA, Sherif SM, Saad GR (2011) J Polym Res 18:1217–1227Google Scholar
  10. 10.
    Zhang C, Bai Y, Sun Y, Gu J, Xu Y (2010) J Membr Sci 365(1–2):216–224CrossRefGoogle Scholar
  11. 11.
    Kitagawa F, Kubota K, Sueyoshi K, Otsuka K (2010) J Pharm Biomed Anal 53(5):1272–1277CrossRefGoogle Scholar
  12. 12.
    McMillin DW, Ooi M, Delmore J, Negri J, Hayden P, Mitsiades N, Jakubikova J, Maira S-M, Garcia-Echeverria C, Schlossman R, Munshi NC, Richardson PG, Anderson KC, Mitsiades CS (2009) Cancer Res 69(14):5835–5842CrossRefGoogle Scholar
  13. 13.
    Schwarzer M, Faerber G, Rueckauer T, Blum D, Pytel G, Mohr FW, Doenst T (2009) Basic Res Cardiol 104(5):547–557CrossRefGoogle Scholar
  14. 14.
    Lim DW, Park TG (2000) Polym Prepr (Am Chem Soc, Div Polym Chem) 41(1):1008–1009Google Scholar
  15. 15.
    Son YK, Kim J-H, Jeon YS, Chung DJ (2007) Macromol Res 15(6):527–532CrossRefGoogle Scholar
  16. 16.
    Ravichandran P, Shantha KL, Rao KP (1997) Int J Pharm 154(1):89–94CrossRefGoogle Scholar
  17. 17.
    Ming J, Zhao YJ, Zhang Y, Zhong H, Li RQ (2000) Technol Water Treat 26(4):245–248Google Scholar
  18. 18.
    Zhimei S, Runliang F, Min S, Chenyu G, Yan G, Lingbing L, Guangxi Z (2011) J Colloid Interface Sci 354:116–123CrossRefGoogle Scholar
  19. 19.
    Hong Y, Liutao L, Liqiang W, Zhiguo Z, Shiping Y (2010) Inorg Chem Commun 13:1387–1390CrossRefGoogle Scholar
  20. 20.
    Philip WL, Maya JJ, Rotimi ES (2010) J Supercrit Fluids 54:81–88CrossRefGoogle Scholar
  21. 21.
    Yongchun D, Enpu W (2003) Industrial Water Treat 23(8):39–42Google Scholar
  22. 22.
    Sergey VS, Nikolay OMP, Christian R (2010) Tetrahedron Lett 51:4347–4349CrossRefGoogle Scholar
  23. 23.
    Safavi A, Abdollahi H, Maleki N, Zeinali S (2008) J Colloid Interface Sci 322(1):274–280CrossRefGoogle Scholar
  24. 24.
    Sis H, Birinci M (2009) Colloids Surf A 341(1–3):60–67CrossRefGoogle Scholar
  25. 25.
    Ofir E, Oren Y, Adin A (2007) Desalination 204:33–38CrossRefGoogle Scholar
  26. 26.
    Wanwisa K, Satit P, Thomas R, Thaned P (2008) Int J Pharm 351:227–235CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Yin-Chun Chao
    • 1
  • Shuenn-Kung Su
    • 1
  • Ya-Wun Lin
    • 2
  • Wan-Ting Hsu
    • 2
  • Kuo-Shien Huang
    • 2
  1. 1.Department of Materials Science and EngineeringNational Taiwan University of Science and TechnologyTaipeiTaiwan
  2. 2.Department of Materials EngineeringKun Shan UniversityYung Kang, TainanTaiwan

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