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Cellulose Fiber/Bentonite Clay/Biodegradable Thermoplastic Composites

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Abstract

Adding cellulose fiber reinforcement can improve mechanical properties of biodegradable plastics, but fiber must be well dispersed to achieve any benefit. The approach to dispersing fiber in this study was to use aqueous gels of sodium bentonite clay. These clay-fiber gels were combined with powdered compostable thermoplastics and calcium carbonate filler. The composite was dried, twin-screw extruded, and injection molded to make thin parts for tensile testing. An experimental design was used to determine the effect of fiber concentration, fiber length, and clay concentration. Polybutylene adipate/terephthalate copolymer (PBAT) and 70/30 polylactic acid (PLA)/PBAT blend were the biodegradable plastics studied. The composite strength decreased compared to the thermoplastics (13 vs. 19 MPa for PBAT, 27 vs. 38 MPa for the PLA/PBAT blend). The composite elongation to break decreased compared to the thermoplastics (170% vs. 831% for PBAT, 4.9% vs. 8.7% for the PLA/PBAT blend). The modulus increased for the composites compared to the thermoplastic standards (149 vs. 61 MPa for PBAT, 1328 vs. 965 MPa for the PLA/PBAT blend). All composite samples had good water resistance.

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Authors and Affiliations

  1. Department of Agriculture, Bioproduct Chemistry and Engineering Research, Western Regional Research Center, Agricultural Research Service, 800 Buchanan St., Albany, CA, 94710, USA

    C. N. Ludvik, G. M. Glenn, A. P. Klamczynski & D. F. Wood

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  1. C. N. Ludvik
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  2. G. M. Glenn
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  3. A. P. Klamczynski
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  4. D. F. Wood
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Correspondence to C. N. Ludvik.

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Ludvik, C.N., Glenn, G.M., Klamczynski, A.P. et al. Cellulose Fiber/Bentonite Clay/Biodegradable Thermoplastic Composites. J Polym Environ 15, 251–257 (2007). https://doi.org/10.1007/s10924-007-0072-5

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  • DOI: https://doi.org/10.1007/s10924-007-0072-5

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