Table 1 \(b_l^+(\epsilon )\) as in (92) and corresponding pressure \(p_l^+(\epsilon )\) in dependence of \(p_{\max }\) for different adsorptives and temperatures and vanishing step size h. Here the parameters \(u_{\min }=4\,{\text {kJ/mol}}\) and \(u_{\max }=24\,{\text {kJ/mol}}\) are used. \(\xi _0\) and \(p_l^+(\epsilon )\) are calculated by \(p_{\max }\) and \(b_l^+(\epsilon )\) according to equations (5) and (6). Note that for \(h=0\,{\text {kJ/mol}}\), \(b_l^+(\epsilon )\) and thus also \(p_l^+(\epsilon )\) are independent of l. \(p_l^+(\epsilon )\) can then be taken as a guide value for \(p_{\min }\). As with real measurements, pressures are given in the unit Torr
\(p_{\max }\) [Torr] | \(\xi _0\) \(\left[ \frac{\textrm {kJ}}{\text{mol}}\right]\) | \(b_l^+(\epsilon )\) \(\left[ \frac{\textrm {kJ}}{\text{mol}}\right]\) | \(p_l^+ (\epsilon )\) [Torr] | T [K] | \(\epsilon\) | Adsorptive |
|---|---|---|---|---|---|---|
760 | 7.468 | 24.215 | 3.731 \(\cdot 10^{-9}\) | 77.355 | 0.100 | \(\text {N}_2\) |
760 | 7.468 | 25.860 | 2.892 \(\cdot 10^{-10}\) | 77.355 | 0.010 | \(\text {N}_2\) |
760 | 7.468 | 27.357 | 2.822 \(\cdot 10^{-11}\) | 77.355 | 0.001 | \(\text {N}_2\) |
760 | 8.601 | 25.979 | 3.041\(\cdot 10^{-8}\) | 87.302 | 0.010 | Ar |
760 | 0.322 | 27.839 | \(2.806\cdot 10^{-338}\) | 4.222 | 0.010 | He |
152000 | 2.129 | 27.788 | 2.382 \(\cdot 10^{-22}\) | 50.000 | 0.010 | He |
152000 | 3.807 | 27.655 | 3.364\(\cdot 10^{-10}\) | 85.000 | 0.010 | He |