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Table 1 \(b_l^+(\epsilon )\) as in (92) and corresponding pressure \(p_l^+(\epsilon )\) in dependence of \(p_{\max }\) for different adsorptives and temperatures and vanishing step size h. Here the parameters \(u_{\min }=4\,{\text {kJ/mol}}\) and \(u_{\max }=24\,{\text {kJ/mol}}\) are used. \(\xi _0\) and \(p_l^+(\epsilon )\) are calculated by \(p_{\max }\) and \(b_l^+(\epsilon )\) according to equations (5) and (6). Note that for \(h=0\,{\text {kJ/mol}}\), \(b_l^+(\epsilon )\) and thus also \(p_l^+(\epsilon )\) are independent of l. \(p_l^+(\epsilon )\) can then be taken as a guide value for \(p_{\min }\). As with real measurements, pressures are given in the unit Torr

From: The numerical solution of the adsorption integral equation with Langmuir-kernel Part 1: approximations

\(p_{\max }\) [Torr]

\(\xi _0\) \(\left[ \frac{\textrm {kJ}}{\text{mol}}\right]\)

\(b_l^+(\epsilon )\) \(\left[ \frac{\textrm {kJ}}{\text{mol}}\right]\)

\(p_l^+ (\epsilon )\) [Torr]

T [K]

\(\epsilon\)

Adsorptive

760

7.468

24.215

3.731 \(\cdot 10^{-9}\)

77.355

0.100

\(\text {N}_2\)

760

7.468

25.860

2.892 \(\cdot 10^{-10}\)

77.355

0.010

\(\text {N}_2\)

760

7.468

27.357

2.822 \(\cdot 10^{-11}\)

77.355

0.001

\(\text {N}_2\)

760

8.601

25.979

3.041\(\cdot 10^{-8}\)

87.302

0.010

Ar

760

0.322

27.839

\(2.806\cdot 10^{-338}\)

4.222

0.010

He

152000

2.129

27.788

2.382 \(\cdot 10^{-22}\)

50.000

0.010

He

152000

3.807

27.655

3.364\(\cdot 10^{-10}\)

85.000

0.010

He