Abstract
This brief note presents the exact analytical solution of an example class of dynamical systems, realized by differential equations. These problems occur in quantum mechanics and their generalizations in theoretical physics, but they particularly find application to chemical systems. Addressed is the exact analytical solution of the radial Schrodinger equation for the nonrelativistic N-particle system with pairwise \({\frac{1}{r_{ij}}}\) radial potential dynamics in the quantum phase space representation (QPSR) (Torres-Vega, Frederick, J. Chem. Phys. 98 3103, 1993). Applying the formal symbolic solution scheme Heaviside Operational Ansatz (heretofore, HOA) put forward in (Electron. J. Theor. Phys. 1 , 10–16, 2004), reduces solution of the radial Schrodinger equation to exact quadratures.
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References
Torres-Vega Go. and Frederick J.H. (1993). J. Chem. Phys. 98: 3103
Li Q.S. and Lu J. (2000). J. Chem. Phys. 113(11): 4565–4571
Hu X.-G. and Li Q.S. (1999). J. Phys. A Math. Gen. 32(1): 139–146
Li Q.S. and Lu J. (2001). Chem. Phys. Lett. 336(1,2): 118–122
Li Q.S., Wei G.M. and Lu L.Q. (2004). Phys. Rev. A Atom. Mol. Opt. Phys. 70(2): 022105/1–022105/5
Yariv A. (1982). Theory and Applications of Quantum Mechanics. Wiley and Sons, NY
Moss R.E. (1973). Advanced Molecular Quantum Mechanics. Wiley and Sons, NY
I. Lindgren, in Lecture Notes in Chemistry, vol. 52: Many-Body Methods in Quantum Chemistry, ed. by U. Kaldor (Springer, Berlin, 1989), pp. 293–306
Simpao V.A. (2006). Majorana special issue. Electron. J. Theor. Phys. 3(10): 239
V.A. Simpao, Exact analysis of He atom via Heaviside operational Ansatz (in preparation)
V.A. Simpao, Exact analysis of H Dimer via Heaviside operational Ansatz (in preparation)
G.E. Roberts, H. Kaufmann, Table of Laplace Transforms (W.B. Saunders, 1966)
I. Sneddon, The Use of Integral Transforms (McGraw-Hill, 1972)
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An erratum to this article can be found at http://dx.doi.org/10.1007/s10910-008-9400-9
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Simpao, V.A. Toward chemical applications of Heaviside Operational Ansatz: exact solution of radial Schrodinger equation for nonrelativistic N-particle system with pairwise \({\frac{1}{r_{ij}}}\) radial potential in quantum phase space. J Math Chem 45, 129–140 (2009). https://doi.org/10.1007/s10910-008-9372-9
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DOI: https://doi.org/10.1007/s10910-008-9372-9