Abstract
The wide-temperature-range (4.2–300 K) electron transport had being studied in tungsten–carbon nanocomposites in tungsten concentration interval 0.1–0.45. It is shown that electron transport in the nanocomposites possesses the features of the universality, manifested in the form of power-law dependences of the conductivity on temperature in the two characteristic temperature intervals. The critical temperature separating the intervals is about 25–30 K and has no appreciable dependence on the value of tungsten concentration in nanocomposites. The power exponents of the temperature dependences of the conductivity in both temperature intervals are the non-monotonic functions of the tungsten concentration and vary in the range 0–2 with a wide minimum at 0.2 and 0.25 of tungsten content in the high- and low-temperature intervals, respectively. The observed power-law temperature corrections to the conductivity are simulated and discussed within the effective medium approximation in the framework of the model of the inelastic tunneling of the electrons between the conducting clusters in the tungsten–carbon nanocomposites.
Similar content being viewed by others
References
I.I. Kang, M.J. Schulz, J.H. Kim, V. Shanev, D. Shi, A carbon nanotube strain sensor for structural health monitoring. Smart Mater. Struct. 15, 737–748 (2006)
J. Hrbac, V. Halouzka, R. Zboril, K. Papadopoulos, T. Triantis, Carbon electrodes modified by nanoscopic iron(III) oxides to assemble chemical sensors for the hydrogen peroxide amperometric detection. Electroanalysis 19, 1850–1854 (2007)
T. Sen, N.G. Shimpi, S. Mishra, Room temperature CO sensing by polyaniline/Co3O4 nanocomposite. J. Appl. Polym. Sci. 133, 44115(1)–44115(8) (2016)
F. Gyger, A. Sackmann, M. Hübner, P. Bockstaller, D. Gerthsen, H. Lichtenberg, J.-D. Grunwaldt, N. Barsan, U. Weimar, C. Feldmann, Pd@SnO2 and SnO2@Pd Core@Shell nanocomposite sensors. Part. Part. Syst. Char. 31, 591–596 (2014)
L. Dong, D. Liang, R. Gong, In situ photoactivated AgCl/Ag nanocomposites with enhanced visible light photocatalytic and antibacterial activity. Eur. J. Inorg. Chem. 19, 3200–3208 (2012)
N. Myung, W. Lee, C. Lee, S. Jeong, K. Rajeshwar, Synthesis of Au-BiVO4 nanocomposite through anodic electrodeposition followed by galvanic replacement and its application to the photocatalytic decomposition of methyl orange. ChemPhysChem 15, 2052–2057 (2014)
Y. Lin, Z. Geng, H. Cai, L. Ma, J. Chen, J. Zeng, N. Pan, X. Wang, Ternary graphene–TiO2–Fe3O4 nanocomposite as a recollectable photocatalyst with enhanced durability. Eur. J. Inorg. Chem. 28, 4439–4444 (2012)
Aaryashree, S. Biswas, P. Sharma, V. Awasthi, B.S. Sengar, A.K. Das, S. Mukherjee, Photosensitive ZnO-graphene quantum dot hybrid nanocomposite for optoelectronic applications. ChemistrySelect 1, 1503–1509 (2016)
Y.-H. Kim, W.-J. Cho, S.-I. Kim, Cathodoluminescence of ZnSiOx nanocomposite films prepared on Si substrates. Phys. Status Solidi C 6, 894–897 (2009)
D. Chen, Z. Luo, N. Li, J.Y. Lee, J. Xie, J. Lu, Amphiphilic polymeric nanocarriers with luminescent gold nanoclusters for concurrent bioimaging and controlled drug release. Adv. Funct. Mater. 23, 4324–4331 (2013)
J. Arjomandi, N. Keramat, I. Mossa, B. Jaleh, Electrochemical synthesis and in situ spectroelectrochemistry of conducting NMPy-TiO2 and ZnO polymer nanocomposites for Li secondary battery applications. J. Appl. Polym. Sci. 132, 41526(1)–41526(11) (2015)
M. Nanu, J. Schoonman, A. Goossens, Solar-energy conversion in TiO2/CuInS2 nanocomposites. Adv. Funct. Mater. 15, 95–100 (2005)
J. Robertson, Diamond-like amorphous carbon. Mater. Sci. Eng. R37, 129–281 (2002)
E.G. Gerstner, P.B. Lukins, D.R. McKenzie, D.G. McCulloch, Substrate bias effects on the structural and electronic properties of tetrahedral amorphous carbon. Phys. Rev. B 54, 14504–14510 (1996)
P.J. Fallon, V.S. Veerasamy, C.A. Davis, J. Robertson, G.A.J. Amaratunga, W.I. Milne, J. Koskinen, Properties of filtered-ion-beam-deposited diamondlike carbon as a function of ion energy. Phys. Rev. B 48, 4777–4782 (1993)
M. Ghowalla, A.C. Ferrari, J. Robertson, C.A.J. Amaratunga, Evolution of sp2 bonding with deposition temperature in tetrahedral amorphous carbon studied by Raman spectroscopy. Appl. Phys. Lett. 76, 1419–1421 (2000)
S. Sattel, J. Robertson, H. Ehrhardt, Effects of deposition temperature on the properties of hydrogenated tetrahedral amorphous carbon. J. Appl. Phys. 82, 4566–4576 (1997)
A.C. Ferrari, B. Kleinsorge, N.A. Morrison, A. Hart, V. Stolojan, J. Robertson, Stress reduction and bond stability during thermal annealing of tetrahedral amorphous carbon. J. Appl. Phys. 85, 7191–7197 (1999)
S. Prawer, R. Kalish, M. Adel, V. Richter, Effects of heavy ion irradiation on amorphous hydrogenated (diamondlike) carbon films. J. Appl. Phys. 61, 4492–4500 (1987)
T. Mori, Y. Futagami, E. Kishimoto, A. Shirakura, T. Suzuki, Synthesis of hard hydrogenated amorphous carbon films by atmospheric pressure filamentary dielectric barrier discharge. J. Vac. Sci. Technol. A33, 060607 (2015)
A. Carl, G. Dumpich, E.F. Wassermann, Structural properties of granular PdxC1−x films. Phys. Rev. B 50, 7838–7844 (1994)
Ph Gouy-Pailler, Y. Pauleau, Tungsten and tungsten–carbon thin films deposited by magnetron sputtering. J. Vac. Sci. Technol. A11, 96–102 (1993)
Q.F. Huang, S.F. Yoon, H. Yang, J. Ahn, Q. Zhang, Molybdenum-containing carbon films deposited using the screen grid technique in an electron cyclotron resonance chemical vapor deposition system. Diam. Relat. Mater. 9, 534–538 (2000)
D. Li, W.F. Li, S. Ma, Z.D. Zhang, Electronic transport properties of NbC(C)–C nanocomposites. Phys. Rev. B 73, 193402–193404 (2006)
L. Zeng, H. Zutz, F. Hellman, E. Helgren, J.W. Ager, C. Ronning, Magnetoelectronic properties of Gd-implanted tetrahedral amorphous carbon. Phys. Rev B 84, 134419 (2011)
K. Tang, X. Wu, G. Wang, L. Li, S. Wu, X. Dong, Z. Liu, B. Zhao, One-step preparation of silver nanoparticle embedded amorphous carbon for nonenzymatic hydrogen peroxide sensing. Electrochem. Commun. 68, 90–94 (2016)
K. Nygren, M. Andersson, J. Högström, W. Fredriksson, K. Edström, L. Nyholm, U. Jansson, Influence of deposition temperature and amorphous carbon on microstructure and oxidation resistance of magnetron sputtered nanocomposite Cr–C films. Appl. Surf. Sci. 305, 143–153 (2014)
W.Q. Bai, L.L. Li, X.L. Wang, F.F. He, D.G. Liu, G. Jin, J.P. Tu, Effects of Ti content on microstructure, mechanical and tribological properties of Ti-doped amorphous carbon multilayer films. Surf. Coat. Technol. 266, 70–78 (2015)
I.S. Beloborodov, A.V. Lopatin, V.M. Vinokur, K.B. Efetov, Granular electronic systems. Rev. Mod. Phys. 79, 469–518 (2007)
K.B. Efetov, A. Tschersich, Coulomb effects in granular materials at not very low temperatures. Phys. Rev. B 67, 174205–174215 (2003)
I.S. Beloborodov, A.V. Lopatin, V.M. Vinokur, Universal description of granular metals at low temperatures: granular Fermi liquid. Phys. Rev. B 70, 205120–205125 (2004)
L. Rotkina, S. Oh, J.N. Eckstein, S.V. Rotkin, Logarithmic behavior of the conductivity of electron-beam deposited granular Pt∕C nanowires. Phys. Rev. B 72, 233407 (2005)
R. Sachser, F. Porrati, C.H. Schwalb, M. Huth, Universal conductance correction in a tunable strongly coupled nanogranular metal. Phys. Rev. Lett. 107, 206803–206805 (2011)
Y.-C. Sun, S.-S. Yeh, J.-J. Lin, Conductivity and tunneling density of states in granular Cr films. Phys. Rev. B 82, 054203–054207 (2010)
Y.-J. Zhang, Z.-Q. Li, J.-J. Lin, Logarithmic temperature dependence of Hall transport in granular metals. Phys. Rev. B 84, 052202–052204 (2011)
M. Salvato, M. Lucci, I. Ottaviani, M. Cirillo, E. Tamburri, S. Orlanducci, M.L. Terranova, M. Notarianni, C.C. Young, N. Behabtu, M. Pasquali, Transport mechanism in granular Ni deposited on carbon nanotubes fibers. Phys. Rev B 86, 115117 (2012)
Y.-N. Wu, Y.-F. Wei, Z.-Q. Li, J.-J. Lin, Electron–electron interaction effect on longitudinal and Hall transport in thin and thick Agx(SnO2)1−x granular metals. Phys. Rev. B 91, 104201–104207 (2015)
A.R. Akhmerov, A.S. Ioselevich, Universal temperature dependence of the conductivity of a strongly disordered granular metal. JETP Lett. 83, 211–216 (2006)
B.F. Dorfman, Stabilized sp2/sp3 carbon and metal-carbon composites of atomic scale as interface and surface-controlling dielectric and conducting materials, in Handbook of Surfaces and Interfaces of Materials, ed. by H.S. Nalwa (Academic Press, San Diego, 2001), pp. 447–509
B.F. Dorfman, Critical parameters of percolation in metal-dielectric diamond-like composites of atomic scale. Thin Solid Films 330, 76–82 (1998)
V.F. Dorfman, A. Bozhko, B.N. Pypkin, R.T. Borra, A.R. Srivatsa, H. Zhang, T.A. Skotheim, I. Khan, D. Rodichev, G. Kirpilenko, Diamond-like nanocomposites: electronic transport mechanisms and some applications. Thin Solid Films 212, 274–281 (1992)
A. Bozhko, A. Ivanov, M. Berrettoni, S. Chudinov, S. Stizza, V. Dorfman, B. Pypkin, Electroconductivity of amorphous carbon films containing silicon and tungsten. Diam. Relat. Mater. 4, 488–491 (1995)
J.Z. Wan, F.H. Pollak, B.F. Dorfman, Micro-Raman study of diamondlike atomic-scale composite films modified by continuous wave laser annealing. J. Appl. Phys. 81, 6407–6414 (1997)
B. Abeles, P. Sheng, M.D. Coutts, Y. Arie, Structural and electrical properties of granular metal films. Adv. Phys. 24(3), 407–461 (1975)
H. Miki, T. Takeno, T. Takagi, A. Bozhko, M. Shupegin, H. Onodera, T. Komiyama, T. Aoyama, Superconductivity in W-containing diamond-like nanocomposite films. Diam. Relat. Mater. 15, 1898–1901 (2006)
A. Bozhko, S. Chudinov, S. Stizza, B. Pypkin, M. Shupeggin, Cluster superconductivity in diamond-like carbon–silicon nanocomposites containing tungsten. J. Phys.: Condens. Matter 10, 1855–1862 (1998)
G. Ambrosetti, I. Balberg, C. Grimaldi, Percolation-to-hopping crossover in conductor-insulator composites. Phys. Rev B 82, 134201–134207 (2010)
L.I. Glazman, K.A. Matveev, Inelastic tunneling across thin amorphous films. Sov. Phys.-JETP 67, 1276–1282 (1988)
L.I. Glazman, R.I. Shekhter, Inelastic resonant tunneling of electrons through a potential barrier. Sov. Phys.-JETP 67, 163–170 (1988)
R. Zallen, Polychromatic percolation: coexistence of percolating species in highly connected lattices. Phys. Rev. B 16, 1426–1435 (1977)
D.A.G. Von Bruggeman, Berechnung vershiedener physikalischer Konstanten von heterogenen Substanzen. Ann. Phys. 5, 636–664 (1935)
N. Li, Y.-Y. Zhang, G.-J. Jin, Effective-medium approach for conductivities in multi-component granular mixtures. Chin. Phys. Lett. 25, 4395–4398 (2008)
J.G. Simmons, Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film. J. Appl. Phys. 34, 1793–1803 (1963)
A. Bozhko, T. Takagi, T. Takeno, M. Shupegin, Electron transport in W-containing amorphous carbon–silicon diamond-like nanocomposites. J. Phys.: Condens. Matter 16, 8447–8458 (2004)
A. Bozhko, T. Takagi, T. Takeno, M. Shupegin, Electron transport in amorphous carbon–silicon nanocomposites containing Nb. Jap. J. Appl. Phys. 43, 7566–7571 (2004)
A.D. Bozhko, Logarithmic conductivity of Cr–C nanocomposites. Physics Procedia 71, 343–347 (2016)
A.D. Bozhko, Power-like corrections to the conductivity of Mo–C nanocomposites. Nanosyst. Phys. Chem. Math. 7, 169–174 (2016)
Acknowledgements
The authors thank Dr. L.D. Iskhakova (Fiber Optics Center of RAS) for her kind assistance in the tungsten concentration measurements, Prof. V.V. Glushkov, and Dr. A.N. Samarin (Prokhorov General Physics Institute of RAS) for valuable discussions. VVB (electron microscopy data, discussion of the results) is grateful to RSF (14-22-00093) for the financial support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bozhko, A.D., Brazhkin, V.V. & Shupegin, M.L. Universal Features of the Electron Transport in Tungsten–Carbon Nanocomposites. J Low Temp Phys 192, 299–314 (2018). https://doi.org/10.1007/s10909-018-1975-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10909-018-1975-3