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Preparation and Electrochemical Investigation of NiO Hollow Sphere from Bio Waste (Sugarcane Bagasse) Extract for Energy Storage Applications

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Abstract

This work describes how to easily make NiO hollow sphere composites using waste sugarcane bagasse for use in supercapacitor applications. NiO hollow spheres (NOHSs) nanomaterialis effectively synthesized through the nano carbon sphere (CS) template. A core-shell structure was created on the carbon sphere’s surface by NiO nanoparticles that were several nanometers in size. The structural and morphological of the synthesized materials were investigated by X-ray diffraction (XRD) and Scanning electron microscope (SEM). The energy-dispersive X-ray spectroscopy (EDS) was used to confirm the presence of the elements in NOHS. The electrochemical behaviour of hierarchical CSs and NOHSs electrode was examined through cyclic voltammetry (CV), Galvanostatic charge/discharge (SC) and electrochemical impedance spectroscopy (EIS). In GCD analysis, NOHSs electrode showed a concentrated specific capacitance (Csp) of 913.79 F/g at 5 A/g current density. The porous conductive carbon with macro pores that speeds up the transit of electron and electrolyte ions causes noticeably better capacitive behavior.

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References

  1. S. Iqbal, H. Khatoon, A. Hussain Pandit, S. Ahmad, Mater. Sci. Energy Technol. 2, 417 (2019)

    Google Scholar 

  2. H. Wei, H. Gu, J. Guo, D. Cui, X. Yan, J. Liu, D. Cao, X. Wang, S. Wei, Z. Guo, Adv. Compos. Hybrid. Mater. 1, 127 (2018)

    Article  CAS  Google Scholar 

  3. Z. Le, F. Liu, P. Nie, X. Li, X. Liu, Z. Bian, G. Chen, H.B. Wu, Y. Lu, ACS Nano. 11, 2952 (2017)

    Article  CAS  PubMed  Google Scholar 

  4. N. Xu, X. Sun, F. Zhao, X. Jin, X. Zhang, K. Wang, K. Huang, Y. Ma, Electrochim. Acta. 236, 443 (2017)

    Article  CAS  Google Scholar 

  5. A.S. Dobrota, I.A. Pašti, S.V. Mentus, B. Johansson, N.V. Skorodumova, Electrochim. Acta. 250, 185 (2017)

    Article  CAS  Google Scholar 

  6. P. Thomas, C.W. Lai, M.R. Bin, Johan, J. Anal. Appl. Pyrol. 140, 54 (2019)

    Article  CAS  Google Scholar 

  7. Z. Li, K. Xu, Y. Pan, Nanotechnol Rev. 8, 35 (2019)

    Article  Google Scholar 

  8. Y. Gao, D. Wu, T. Wang, D. Jia, W. Xia, Y. Lv, Y. Cao, Y. Tan, P. Liu, Electrochim. Acta. 191, 275 (2016)

    Article  CAS  Google Scholar 

  9. Z.S. Wu, G. Zhou, L.C. Yin, W. Ren, F. Li, H.M. Cheng, Nano Energy. 1, 107 (2012)

    Article  CAS  Google Scholar 

  10. M. Vujković, N. Gavrilov, I. Pašti, J. Krstić, J. Travas-Sejdic, G. Ćirić-Marjanović, S. Mentus, Carbon N Y. 64, 472 (2013)

    Article  Google Scholar 

  11. R. Barik, B.K. Jena, A. Dash, M. Mohapatra, RSC Adv. 4, 18827 (2014)

    Article  CAS  Google Scholar 

  12. S.A.U. Portia, R. Srinivasan, E. Elaiyappillai, P.M. Johnson, K. Ramamoorthy, Ionics (Kiel). 26, 3543 (2020)

    Article  CAS  Google Scholar 

  13. M.D. Angelin, S. Rajkumar, J.P. Merlin, A.R. Xavier, M. Franklin, A.T. Ravichandran, Ionics (Kiel). 26, 5757 (2020)

    Article  CAS  Google Scholar 

  14. M.D. Angelin, S. Rajkumar, A.T. Ravichandran, J.P. Merlin, J. Phys. Chem. Solids. 161, 110486 (2022)

    Article  CAS  Google Scholar 

  15. A.R. Xavier, A.T. Ravichandran, S. Vijayakumar, M.D. Angelin, S. Rajkumar, J.P. Merlin, J. Mater. Sci. Mater. Electron. 33, 8426 (2022)

    Article  CAS  Google Scholar 

  16. T. Arun, K. Prabakaran, R. Udayabhaskar, R.V. Mangalaraja, A. Akbari-Fakhrabadi, Appl. Surf. Sci. 485, 147 (2019)

    Article  CAS  Google Scholar 

  17. J. Alex, S. Rajkumar, J. PrincyMerlin, A. Aravind, D. Sajan, C.S. Praveen, J. Alloys Compd. 882, 160409 (2021)

    Article  CAS  Google Scholar 

  18. J.W. Long, K.E. Swider, C.I. Merzbacher, D.R. Rolison, Langmuir  15(3), 780 (1999)

    Article  CAS  Google Scholar 

  19. S.K. Balasingam, A. Thirumurugan, J.S. Lee, Y. Jun, Nanoscale. 8, 11787 (2016)

    Article  CAS  PubMed  Google Scholar 

  20. M. Lee, S.K. Balasingam, H.Y. Jeong, W.G. Hong, H. Lee, B.H. Kim, Sci. Rep. 5(1), 1–8 (2015)

    Google Scholar 

  21. C. Zhu, L. Yang, J.K. Seo, X. Zhang, S. Wang, J. Shin, D. Chao, H. Zhang, Y.S. Meng, H.J. Fan, Mater. Horizons 4, 415 (2017)

  22. Q.X. Low, G.W. Ho, Nano Energy 5(28), 35 (2014)

    Google Scholar 

  23. C. Wu, Q. Shen, R. Mi, S. Deng, Y. Shu, H. Wang, J. Mater. Chem. Mater. Energy Sustain. 2, 15987 (2014)

    Article  CAS  Google Scholar 

  24. P. Sun, Z. Deng, P. Yang, X. Yu, Y. Chen, Z. Liang, H. Meng, W. Xie, S. Tan, W. Mai, J. Mater. Chem. Mater. Energy Sustain. 00, 1 (2015)

    Google Scholar 

  25. Y. Hwang, E. Gyoung, K. Sohn, S. Shim, X. Song, J. Power Sources. 240, 683 (2013)

    Article  CAS  Google Scholar 

  26. B. Zhao, H. Zhuang, T. Fang, Z. Jiao, R. Liu, X. Ling, B. Lu, Y. Jiang, J. Alloys Compd. 597, 291 (2014)

    Article  CAS  Google Scholar 

  27. L. Jiang, X. Lu, C. Xie, G. Wan, H. Zhang, T. Youhong, J. Phys. Chem. C 119, 3903 (2015)

    Article  CAS  Google Scholar 

  28. C. Hsieh, J. Lin, Y. Chen, C. Lin, W. Li, Mater. Chem. Phys. 143, 853 (2014)

    Article  CAS  Google Scholar 

  29. C.K. Chan, H. Peng, G.A.O. Liu, K. Mcilwrath, X.F. Zhang, R.A. Huggins, Y.I. Cui, Nat. Nanotechnol. 3, 31 (2007)

    Article  PubMed  Google Scholar 

  30. M. Park, G. Wang, Y. Kang, D. Wexler, S. Dou, Angew Chemie - Int. Ed. 46, 750 (2007)

    Article  CAS  Google Scholar 

  31. Y.J. Lee, H. Yi, W.-J. Kim, K. Kang, D.S. Yun, M.S. Strano, G. Ceder, A.M. Belcher, Science. 324, 80 (2009)

    Google Scholar 

  32. R.R. Salunkhe, J. Tang, Y. Kamachi, T. Nakato, J.H. Kim, Y. Yamauchi, ACS Nano. 9, 6288 (2015)

    Article  CAS  PubMed  Google Scholar 

  33. R.R. Salunkhe, Y.V. Kaneti, Y. Yamauchi, ACS Nano. 11, 5293 (2017)

    Article  CAS  PubMed  Google Scholar 

  34. Y. Tian, Y. An, H. Wei, C. Wei, Y. Tao, Y. Li, B. Xi, S. Xiong, J. Feng, Y. Qian, Chem. Mater. 32, 4054 (2020)

    Article  CAS  Google Scholar 

  35. X. Wu, M. Lian, J. Power Sources. 362, 184 (2017)

    Article  CAS  Google Scholar 

  36. H. Jiang, P.S. Lee, C. Li, Energy Environ. Sci. 6, 41 (2013)

    Article  CAS  Google Scholar 

  37. P. Farid, N. Ani, F. Nasir, S. Faraji, Y. Chen, Renew. Sustain. Energy Rev. 42, 8823 (2015)

    Google Scholar 

  38. L.-S. Zhong, J.-S. Hu, H.-P. Liang, A.-M. Cao, W.-G. Song, L.-J. Wan, Adv. Mater. 18, 2426 (2006)

    Article  CAS  Google Scholar 

  39. R. Yuan, X. Fu, X. Wang, P. Liu, L. Wu, Y. Xu, X. Wang, Z. Wang, Chem. Mater. 18, 4700 (2006)

    Article  CAS  Google Scholar 

  40. S. Ding, T. Zhu, J.S. Chen, Z. Wang, C. Yuan, X.W. David, Lou, J. Mater. Chem. 21, 6602 (2011)

    Article  CAS  Google Scholar 

  41. G. Zhang, L. Yu, H.E. Hoster (eds.), and X. W. (David) Lou, Nanoscale 5, 877 (2013)

  42. Y. Ding, P. Zhang, Z. Long, Y. Jiang, J. Huang, W. Yan, G. Liu, Mater. Lett. 62, 3410 (2008)

    Article  CAS  Google Scholar 

  43. Y. Sun, X. Hu, W. Luo, Y. Huang, ACS Nano. 5, 7100 (2011)

    Article  CAS  PubMed  Google Scholar 

  44. C. Sun, S. Rajasekhara, Y. Chen, J.B. Goodenough, Chem. Commun. 47, 12852 (2011)

    Article  CAS  Google Scholar 

  45. S. Shang, K. Xue, D. Chen, X. Jiao, CrystEngComm. 13, 5094 (2011)

    Article  CAS  Google Scholar 

  46. R.S. Santos, R. Suresh Babu, T.S. Lessa, L.M. Samyn, R. Vinodh, R. Vivekananth, A.L.F. de Barros, J. Ind. Eng. Chem. (2023). https://doi.org/10.1016/j.jiec.2023.12.015

    Article  Google Scholar 

  47. R.S. Santos, R. Suresh Babu, M. Devendiran, D.B. Haddad, A.L.F. de Barros, Mater. Lett. 308, 131156 (2022)

    Article  CAS  Google Scholar 

  48. J. Zhu, Y.K. Sharma, Z. Zeng, X. Zhang, M. Srinivasan, S. Mhaisalkar, H. Zhang, H.H. Hng, Q. Yan, J. Phys. Chem. C 115, 8400 (2011)

    Article  CAS  Google Scholar 

  49. R. Vinodh, R.S. Babu, R. Atchudan, H.-J. Kim, M. Yi, L.M. Samyn, Catalysts 12(4), 375 (2022)

    Article  CAS  Google Scholar 

  50. S. Xiong, J.S. Chen, X.W. Lou, H.C. Zeng, Adv. Funct. Mater. 22, 861 (2012)

  51. A.M. Puziy, A. Herbst, O.I. Poddubnaya, J. Germanus, P. Harting, Langmuir. 19, 314 (2003)

    Article  CAS  Google Scholar 

  52. C. Wang, H. Li, J. Zhao, Y. Zhu, W.Z. Yuan, Y. Zhang, Int. J. Hydrogen Energy. 38, 13230 (2013)

    Article  CAS  Google Scholar 

  53. S. Akshatha, S. Sreenivasa, L. Parashuram, V. Udaya kumar, F.A. Alharthi, T.M. Chakrapani Rao, S. kumar, Mater. Sci. Semicond. Process. 121, 105432 (2021)

    Article  CAS  Google Scholar 

  54. M. Molina-Sabio, F. RodRíguez-Reinoso, F. Caturla, M.J. Sellés, Carbon N Y. 33, 1105 (1995)

    Article  CAS  Google Scholar 

  55. M.M. Moarefdoust, S. Jahani, M. Moradalizadeh, M.M. Motaghi, M.M. Foroughi, Anal. Methods. 13, 2396 (2021)

    Article  CAS  PubMed  Google Scholar 

  56. R. Yuvakkumar, S. Lee, G.W. Lee, S.I. Hong, Microporous Mesoporous Mater. 207, 185 (2015)

    Article  CAS  Google Scholar 

  57. E.Y.L. Teo, L. Muniandy, E.P. Ng, F. Adam, A.R. Mohamed, R. Jose, K.F. Chong, Electrochim. Acta. 192, 110 (2016)

    Article  CAS  Google Scholar 

  58. S.A. Ansari, N. Parveen, M.A.S. Al-othoum, M.O. Ansari, Nanomaterials 11(6), 1596 (2021)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  59. Y. Fan, P.F. Liu, Z.Y. Huang, T.W. Jiang, K.L. Yao, R. Han, J. Power Sources. 280, 30 (2015)

    Article  CAS  Google Scholar 

  60. S. Gao, Y. Chen, H. Fan, X. Wei, C. Hu, H. Luo, L. Qu, J. Mater. Chem. A 2, 3317 (2014)

    Article  CAS  Google Scholar 

  61. Z. Wang, X. Xie, S. Xiao, J. Liu, Hydrometallurgy. 102, 87 (2010)

    Article  CAS  Google Scholar 

  62. C. Petibois, V. Rigalleau, A.M. Melin, A. Perromat, G. Cazorla, H. Gin, G. Déléris, Clin. Chem. 45, 1530 (1999)

    Article  CAS  PubMed  Google Scholar 

  63. S. Vijayakumar, S. Nagamuthu, G. Muralidharan, ACS Sustain. Chem. Eng. 1, 1110 (2013)

    Article  CAS  Google Scholar 

  64. Y.S. Wei, L. Zou, H.F. Wang, Y. Wang, Q. Xu, Adv. Energy Mater. 12, 1 (2022)

    CAS  Google Scholar 

  65. C. Kingston, M.D. Palkowitz, Y. Takahira, J.C. Vantourout, B.K. Peters, Y. Kawamata, P.S. Baran, Acc. Chem. Res. 53, 72 (2020)

    Article  CAS  PubMed  Google Scholar 

  66. J. Xu, L. Li, F. He, R. Lv, P. Yang, Electrochim. Acta. 148, 211 (2014)

    Article  CAS  Google Scholar 

  67. J. Xiao, L. Wan, S. Yang, F. Xiao, S. Wang, Nano Lett. 14, 831 (2014)

    Article  CAS  PubMed  Google Scholar 

  68. J. Zhu, S. Chen, H. Zhou, X. Wang, Nano Res. 5, 11 (2012)

    Article  CAS  Google Scholar 

  69. L. Wang, X.Y. Qin, Bull.  Mater. Sci. 37, 649–654 (2014)

    Article  CAS  Google Scholar 

  70. S. Vijayakumar, S. Nagamuthu, G. Muralidharan, ACS Appl. Mater. Interfaces 5, 2188 (2013)

  71. S.K. Meher, P. Justin, G. Ranga Rao, Nanoscale. 3, 683 (2011)

    Article  CAS  PubMed  Google Scholar 

  72. D.-W. Wang, F. Li, M. Liu, G.Q. Lu, H.-M. Cheng, Angew Chemie. 120, 379 (2008)

    Article  Google Scholar 

  73. S.K. Meher, P. Justin, G.R. Rao, ACS Appl. Mater. Interfaces 3(6), 2063 (2063)

    Article  Google Scholar 

  74. H. Xiao, S. Yao, H. Liu, F. Qu, X. Zhang, X. Wu, Prog. Nat. Sci. Mater. Int. 26(6), 271–275 (2016)

    Article  CAS  Google Scholar 

  75. F. Lei, T. Le, G. Rong, CrystEngComm 13, 7246 (2011)

  76. A. Majeed, P.-X. Hou, S. Jiang, J.-C. Li, L.-Q. Ping, G.-X. Li, F. Zhang, C. Liu, H.-M. Cheng, J. Mater. Chem. A 5, 24813 (2017)

    Article  CAS  Google Scholar 

  77. A. Roy, A. Ray, S. Saha, M. Ghosh, T. Das, B. Satpati, M. Nandi, S. Das, Electrochim. Acta. 283, 327 (2018)

    Article  CAS  Google Scholar 

  78. V.A. Online, Y. Qian, R. Liu, Q. Wang, J. Xu, D. Chen, G. Shen, J. Mater. Chem. A 2, 10917 (2014)

    Article  Google Scholar 

  79. D. Du, Z. Hu, Y. Liu, Y. Deng, J. Liu, J. Alloys Compd. 589, 82 (2014)

    Article  CAS  Google Scholar 

  80. X. Li, J. Li, Y. Zhang, P. Zhao, Colloids Surfaces A Physicochem. Eng. Asp. 622, (2021)

  81. S. Zhang, Y. Pang, Y. Wang, B. Dong, S. Lu, M. Li, S. Ding, J. Alloys Compd. 735, 1722 (2018)

    Article  CAS  Google Scholar 

  82. S.-R. Wu, J.-B. Liu, H. Wang, H. Yan, Ionics (Kiel). 25, 1 (2019)

  83. Z. Qiu, T. Huang, C. Zhao, J. Luo, Z. Hu, Micro Nano Lett. 12, 231 (2017)

    Article  CAS  Google Scholar 

  84. C. Sambathkumar, V. Manirathinam, A. Manikandan, M.K. Kumar, J. Mater. Sci. Mater. Electron. 32, 20827 (2021)

    Article  CAS  Google Scholar 

  85. K.-C. Pham, Y.-H. Chang, D.S. McPhail, C. Mattevi, A.T.S. Wee, D.H.C. Chua, ACS Appl. Mater. Interfaces 8, 5961 (2016)

  86. M. Wu, H. Hsieh, Electrochim. Acta. 53, 3427 (2008)

    Article  CAS  Google Scholar 

  87. J. Zhang, L. Kong, J. Cai, H. Li, Y. Luo, L. Kang, Microporous Mesoporous Mater. 132, 154 (2010)

    Article  CAS  Google Scholar 

  88. R. Packiaraj, K.S. Venkatesh, P. Devendran, S.A. Bahadur, N. Nallamuthu, Mater. Sci. Semicond. Process. 115, 105122 (2020)

    Article  CAS  Google Scholar 

  89. R. de Souza, R.S. Santos, R. Babu, L.M. Vinodh, B.G. Samyn, F. Pollet, A.L.F. de Barros et al., Diam. Relat. Mater. 136, 110005 (2023)

    Article  Google Scholar 

  90. C. Du, N. Pan, Nanotechnology. 17, 5314 (2006)

    Article  CAS  Google Scholar 

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Acknowledgements

M. Murugesan wishes to thank the, International Research Centre, Kalasalingam Academy of Research and Education, Tamil Nadu, INDIA for providing research characterization facilities and University Research Fellowship.

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Authors and Affiliations

  1. Department of Physics, Kalasalingam Academy of Research and Education, Krishnankoil, Virudhunagar, Tamilnadu, 626 126, India

    M. Murugesan, K. R. Nagavenkatesh & P. Devendran

  2. Department of Physics, Dayananda Sagar Academy of Technology and Management, Udayapura, Bangalore, Karnataka, 560 082, India

    N. Nallamuthu

  3. Department of Physics, CHRIST (Deemed to be University), Bangalore, 560029, India

    M. Krishna Kumar

  4. Department of Physics, Indian Institute of Science, Bangalore, India

    K. Ramesh

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  1. M. Murugesan
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Contributions

MM : Conceptualization and draft writing. KRN : Editing and Formal analysis. MKK : Formal analysis. NN : Critical analysis and Resources. KR : Validation. PD : Supervision and Final draft prepared.

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Murugesan, M., Nagavenkatesh, K.R., Devendran, P. et al. Preparation and Electrochemical Investigation of NiO Hollow Sphere from Bio Waste (Sugarcane Bagasse) Extract for Energy Storage Applications. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-024-03044-0

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