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Design of an Efficient Supercapacitor Binder-Free Electrode Using a Two-Step In-Situ Hydrothermal Synthesis of Hierarchical Ni–Co LDH/Ni2SnO4 Nanosheets Stacks on Ni Foam

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Abstract

Improving the electrochemical performance of electrode materials via structural design is critical in developing energy storage technologies. In this investigation, a nanoarray electrode composed of Co–Ni layered double hydroxide (Ni–Co LDH) nanosheets and Ni2SnO4 nanosheets (Ni2SnO4 NSs) stabilized on Ni foam (NF) is developed utilizing an in-situ growth method to its electrochemical properties in supercapacitors can be evaluated. The Ni2SnO4 was created in the first stage using a light hydrothermal reaction as the core. The Ni–Co LDH was then hydrothermally immobilized using the electrode, which had been made as a skeleton. The structural and textural study of the material was described using energy dispersive X-ray analysis (XRD), Fourier transforms infrared (FT–IR), field-emission scanning electron microscopy, and transmission electron microscopy. When the developed Ni–Co LDH/Ni2SnO4/NF electrode is compared to the Ni2SnO4/NF electrode, the electrochemical result shows a specific capacitance of up to 3,924 F g−1 at 1 A g−1 in a 2 mol L−1 KOH electrolyte, as well as a capacitance retention of 95% after 3000 cycles. Unsymmetrical supercapacitors made of Ni–Co LDH/Ni2SnO4/NF and activated carbon demonstrated exceptional electrochemical properties, including high rate capability, high energy, and power density (91.03 Wh kg−1 and 9.0 kW kg−1, respectively), and long cycle life. Due to its unique core/shell structural system, which facilitates ion diffusion and offers a fast electron transport kinetic model and good strain lodging, the rising pseudocapacitive behaviors render it an intriguing candidate for electrochemical energy storage.

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Acknowledgements

The authors are thankful to the post-graduate office of Technical and Vocational University for the support of this work.

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  1. Department of Chemical Engineering, Faculty of Chamran, Guilan Branch, Technical and Vocational University (TVU), Tehran, Iran

    Issa Mousazadeh Moghaddampour & Rasoul Shemshadi

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  1. Issa Mousazadeh Moghaddampour
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  2. Rasoul Shemshadi
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IMM: Methodology, Investigation, Writing—original draft. RS: Conceptualization, Visualization, Supervision, Writing—review and editing.

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Correspondence to Issa Mousazadeh Moghaddampour.

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Mousazadeh Moghaddampour, I., Shemshadi, R. Design of an Efficient Supercapacitor Binder-Free Electrode Using a Two-Step In-Situ Hydrothermal Synthesis of Hierarchical Ni–Co LDH/Ni2SnO4 Nanosheets Stacks on Ni Foam. J Inorg Organomet Polym 34, 1876–1886 (2024). https://doi.org/10.1007/s10904-023-02929-w

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