Abstract
Slow release agrochemicals are a class of agrochemical inputs that deliver their active chemicals or ingredients slowly over time. The majority of formulation consists of an outer medium and a core ingredient, the outer layer progressively degrades over time, enabling the slow release of the active substances to the earth. Bionanocomposites have obtained prominence as outer medium of slow release formulation. Bionanocomposites are a family of hybrid materials made by combining the biopolymer matrix and the nanofiller. Although traditional agrochemicals such as herbicides, insecticides, liming, pesticides, fertilizers etc. are frequently employed in field to improve crop productivity, their excessive use can have noxious effect on the environment and living organisms. These problems can be mitigated by the application of agrochemicals employing bionanocomposites, which increase bio-efficacy and reduces the danger of leaching. This comprehensive review highlights the significance of biobased nanocomposites, their synthesis techniques, applications in agriculture industry and their slow release efficiency in water and soil. It also focus on the remarkable contributions of various research in the slow and controlled release of nanofertilizers, nanopesticides and nanoherbicides which marks a sustainable way of developing agricultural practices aiming at the enhancement of yield.
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H. M. M. Abdel-Aziz, M. N. A. Hasaneen, A. M. Omer, Impact of engineered nanomaterials either alone or loaded with NPK on growth and productivity of French bean plants: Seed priming vs foliar applications. J.SAJB. 125,102–108 (2019). https://doi.org/10.1016/j.sajb.2019.07.005
N.N.R. Ahmad, W.J.N. Fernando, M.H. Uzir, Parametric evaluation using mechanistic model for release rate of phosphate ions from chitosan-coated phosphorus fertilizer pellets. Biosyst. Eng. 129, 78–86 (2015). https://doi.org/10.1016/j.biosystemseng.2014.09.015
S. Ahmad, M. Ahmad, K. Manzoor, R. Purwar and S. Ikram, A review on latest innovations in natural gums based hydrogels: Preparations and applications. Int. J. Biolo. Macromole. 136, 870–890 (2019). https://doi.org/10.1016/j.ijbiomac.2019.06.113
T. Ahmed Khan, M.E.T. Zakaria, H.J. Kim, S. Ghazali, S.S. Jamari, Carbonaceous microsphere-based superabsorbent polymer as filler for coating of NPK fertilizer: fabrication, properties, swelling, and nitrogen release characteristics. J. Appl. Polym. Sci. 137, 48396 (2019).
K. Alharbi, A. Ghoneim, A. Ebid, H. El-Hamshary, M.H. El-Newehy, Controlled release of phosphorous fertilizer bound to carboxymethyl starch-g-polyacrylamide and maintaining a hydration level for the plant. J. Biolo. Macro. 116, 224–231 (2018). https://doi.org/10.1016/j.ijbiomac.2018.04.182
K. Al Rohily, H. El-Hamshary, A. Ghoneim, A. Modaihsh, Controlled release of phosphorus from superabsorbent phosphate-bound alginate-graft-polyacrylamide: resistance to soil cations and release mechanism. ACS. Omega. 5(51), 32919–32929 (2020). https://doi.org/10.1021/acsomega.0c03740
F. Amalina, A.S. Abd Razak, S. Krishnan, A.W. Zularisam, M. Nasrullah, A comprehensive assessment of the method for producing biochar, its characterization, stability, and potential applications in regenerative economic sustainability—a review. Clean. Matals. 3, 100045 (2020)
G. Andani, H. Helmiyati, Synthesis and characterization of hydrogel NaCMC-g-poly (AA-co-AAm) modified by rice husk ash as macronutrient NPK slow-release fertilizer superabsorbent. In: IOP pub, Mater. Sci. Eng. vol. 763, pp. 012005 (2020). https://doi.org/10.1088/1757-899X/763/1/012005
F. Barahona, C.L. Bardliving, A. Phifer, J.G. Bruno, C.A. Batt, An aptasensor based on polymer-gold nanoparticle composite microspheres for the detection of malathion using surface-enhanced raman spectroscopy. Ind. Biotechnol. 9, 42 (2013). https://doi.org/10.1089/ind.2012.0029
C.R. Bauli, G.F. Lima, A.G. de Souza, R.R. Ferreira, and D.S. Rosa, Eco-friendly carboxymethyl cellulose hydrogels filled with nanocellulose or nanoclays for agriculture applications as soil conditioning and nutrient carrier and their impact on cucumber growing. J. Col. Surfa. 623, 126771 (2021). https://doi.org/10.1016/j.colsurfa.2021.126771
P. Boonying, K. Boonpavanitchakul, S. Amnuaypanich, W. Kangwansupamonkon, Natural rubber-lignin composites modified with natural rubber-graft-polyacrylamide as an effective coating for slow-release fertilizers. Ind. Crops Prod. 191, 116018 (2023). https://doi.org/10.1016/j.indcrop.2022.116018
F. Bruna, I. Pavlovic, R. Celis, C. Barriga, J. Cornejo, M.A. Ulibarri, Organohydrotalcites as novel supports for the slow release of the herbicide terbuthylazine. App. Clay Sci. 42, 194–200 (2008). https://doi.org/10.1016/j.clay.2008.02.001
V. Bueno, X. Gao, A. Abdul Rahim, P. Wang, S. Bayen, S. Ghoshal, Uptake and translocation of a silica nanocarrier and an encapsulated organic pesticide following foliar application in tomato plants. Environ. Sci. Technol. 56(10), 6722–6732 (2022). https://doi.org/10.1021/acs.est.1c00447
E.V.R. Campos, J.L.D. Oliveira, C.M.G. da Silva, M. Pascoli, T. Pasquoto, R. Lima, L. Fernandes Fraceto, Polymeric and solid lipid nanoparticles for sustained release of carbendazim and tebuconazole in agricultural applications. Sci. Rep. 5, 13809 (2015)
Y. Cao, L. Huang, J. Chen, J. Liang, S. Long, Y. Lu, Development of a controlled release formulation based on a starch matrix system. Inter. J. Pharm. 298(1), 108–116 (2005)
N.D. Chakkalakkal, M. Thomas, P.S. Chittillapilly, A. Sujith, P.D. Anjali, Electrospun polymer nanocomposite membrane as a promising seed coat for controlled release of agrichemicals and improved germination: Towards a better agricultural prospect. J. Clean. Prodn., 377, 134479 (2022). https://doi.org/10.1016/j.jclepro.2022.134479
C. Chen, Z. Yuan, H.T. Chang, F. Lu, Z. Li, C. Lu, Silver nanoclusters as fluorescent nanosensors for selective and sensitive nitrite detection. Anal. Methods. 8(12), 2628–2633 (2016). https://doi.org/10.1039/C6AY00214E
J. Chen, W. Wang, Y. Xu, X. Zhang, Slow-release formulation of a new biological pesticide, pyoluteorin, with mesoporous silica. J. Agric. Food Chem. 59(1), 307–311 (2011). https://doi.org/10.1021/jf103640t
T.S. Daitx, M. Giovanela, L.N. Carli, R.S. Mauler, Biodegradable polymer/clay systems for highly controlled release of NPK fertilizer. Pol. Adv. Tech. 30(3), 631–639 (2018). https://doi.org/10.1002/pat.4499
M.Del Carmen Galán-Jiménez, E. Morillo, F. Bonnemoy, C. Mallet, T. Undabeytia, A sepiolite-based formulation for slow release of the herbicide mesotrione. App. Clay. Sci. 189, 105503 (2020). https://doi.org/10.1016/j.clay.2020.105503
A.D. De Oliveira, C.A.G. Beatrice, Polymer nanocomposites with different types of nanofiller. In S. Subbarayan (eds) Nanocomposites: Recent Evolutions, pp. 103–104, BoD (2018)
G. Dong, Z. Mu, D. Liu, L. Shang, W. Zhang, Y. Gao, M. Zhao, X. Zhang, S. Chen, M. Wei, Starch phosphate carbamate hydrogel based slow-release urea formulation with good waterretentivity. J. Biol. Macromol. 190, 189–197 (2021). https://doi.org/10.1016/j.ijbiomac.2021.08.234
K. Dos Santos Caetano, D. S. da Rosa, T. M. Pizzolato, P. A. M. dos Santos, R. Hinrichs, E. V. Benvenutti, T. M. H. Costa, MWCNT/zirconia porous composite applied as electrochemical sensor for determination of methyl parathion. Microporous. Mesopo. Mater. 309, 110583 (2020). https://doi.org/10.1016/j.micromeso.2020.110583
S.M. Dourado Junior, E.S. Nunes, R.P. Marques, L.S. Rossino, F.J. Quites, J.R. Siqueira, J.A. Moreto, Controlled release behavior of sulfentrazone herbicide encapsulated in Ca-ALG microparticles: preparation, characterization, mathematical modeling and release tests in field trial weed control. J. Materi. Sci. 52, 9491–9507 (2017)
T. El Assimi, M. Chaib, M. Raihane, A. El Meziane, M. Khouloud, R. Benhida, M. Lahcini, Poly (ε-caprolactone)-g-guar gum and poly (ε-caprolactone)-g-halloysite nanotubes as coatings for slow-release DAP fertilizer. J. Polym. Environ. 28, 2078–2090 (2020)
T. El Assimi, M. Raihane, R. Beniazza, H. B. Youcef, M. Khouloud, M. H. V. Baouab, M. Lahcini, Polymethyl methacrylate-g-carboxy-methylcellulose as an amphiphilic coating material for slow-release fertilizer. Prog. Org. Coat. 172, 107102 (2022). https://doi.org/10.1016/j.porgcoat.2022.107102
S. Fertahi, I. Bertrand, M. Ilsouk, A. Oukarroum, Y. Zeroual, A. Barakat, New generation of controlled release phosphorus fertilizers based on biological macromolecules: effect of formulation properties on phosphorus release. J. Bio. Marco. 143, 153–162 (2021). https://doi.org/10.1016/j.ijbiomac.2019.12.005
R. Grillo, A.E. Pereira, C.S. Nishisaka, R. De Lima, K. Oehlke, R. Greiner, L.F. Fraceto, Chitosan/tripolyphosphate nanoparticles loaded with paraquat herbicide: an environmentally safer alternative for weed control. J. Hazard. Mater. 278, 163–171 (2014). https://doi.org/10.1016/j.jhazmat.2014.05.079
D.T. Gungula, F.P. Andrew, J. Joseph, S.A. Kareem, J.T. Barminas, E.F. Adebayo, A.M. Saddiq, V.T. Tame, I. Dere, W.J. Ahinda, R. Ator, Formulation and characterization of water retention and slow-release urea fertilizer based on Borassus aethiopum starch and Maesopsis eminiihydrogels. Result. Mater. 12, 100223 (2021). https://doi.org/10.1016/j.rinma.2021.100223
M.S. Haydar, S. Ghosh, P. Mandal, Application of iron oxide nanoparticles as micronutrient fertilizer in mulberry propagation. J Plant Growth Regul 41, 1726–1746 (2021). https://doi.org/10.1007/s00344-021-10413-3
F. He, Q. Zhou, L. Wang, G. Yu, J. Li, Y. Feng, Fabrication of a sustained release delivery system for pesticides using interpenetrating polyacrylamide/alginate/montmorillonite nanocompositehydrogels. App.Clay.Sci. 183,105347 (2019). https://doi.org/10.1016/j.clay.2019.105347
B. Huang, F. Chen, Y. Shen, C. An, N. Li, J. Jiang, C. Wang, C. Sun, X. Zhao, B. Cui, Z. Zeng, Preparation, characterization, and evaluation of Pyraclostrobin Nanocapsules by in situ polymerization. Nanomaterials 12(3), 549 (2022). https://doi.org/10.3390/nano12030549
K.R.M. Ibrahim, F.E. Babadi, R. Yunus, Comparative performance of different urea coating materials for slow release. Particuology 17, 165–172 (2014)
T. Jamnongkan, S. J. S. J. U. Kaewpirom, Controlled-release fertilizer based on chitosan hydrogel: phosphorus release kinetics. Sci. J. UBU. 1(1), 43–50 (2010)
L. Javazmi, A. Young, G.J. Ash, T. Low, Kinetics of slow release of nitrogen fertilizer from multi-layered nanofibrous structures. Sci. Rep. 11(1), 1–8 (2021). https://doi.org/10.1038/s41598-021-84460-x
H. Kalita, V.S. Palaparthy, M.S. Baghini, M. Aslam, Electrochemical synthesis of graphene quantum dots from graphene oxide at room temperature and its soil moisture sensing properties. Carbon 165, 9–17 (2020). https://doi.org/10.1016/j.carbon.2020.04.021
S.A. Kareem, I. Dere, D.T. Gungula, F.P. Andrew, A.M. Saddiq, E.F. Adebayo, V.T. Tame, H.M. Kefas, J. Joseph, D.O. Patrick, Synthesis and characterization of slow-release fertilizer hydrogel based on hydroxy propyl methyl cellulose, polyvinyl alcohol, glycerol and blended paper. Gels. 7(4), 262 (2021)
M. Z. H. Khan, M. R. Islam, N. Nahar, M. R. Al-Mamun, M. A. S. Khan, M. A. Matin, Synthesis and characterization of nanozeolite based composite fertilizer for sustainable release and use efficiency of nutrients. Heliyon, 7(1), e06091 (2021). https://doi.org/10.1016/j.heliyon.2021.e06091
V. Krishnamoorthy, S. Rajiv, Tailoring electrospun polymer blend carriers for nutrient delivery in seed coating for sustainable agriculture. J. Clean. Prod. 177, 69–78 (2018) https://doi.org/10.1016/j.jclepro.2017.12.141
S. Kumar, B. Gaurav, S. Amit, M. C. Sidhu, D. Neeraj, Herbicide loaded carboxymethyl cellulose nanocapsules as potential carrier in agri nanotechnology. Sci. Adv. Mater. 7(6), 1143–1148 (2015). https://doi.org/10.1166/sam.2015.2243
Y. Kumar, K.N. Tiwari, T. Singh, R. Raliya, Nanofertilizers and their role in sustainable agriculture. Ann Plant Soil Res. 23(3), 238–255 (2021)
Y. Kusumastuti, A. Istiani, C.W. Purnomo, Chitosan-based polyion multilayer coating on NPK fertilizer as controlled released fertilizer. Adv. Mat. Sci. Eng. (2019). https://doi.org/10.1155/2019/2958021
A. Lateef, R. Nazir, N. Jamil, S. Alam, R. Shah, M.N. Khan, M. Saleem, Synthesis and characterization of zeolite based nano–composite: an environment friendly slow release fertilizer. Micro. Meso. Mater. 232, 174–183 (2016). https://doi.org/10.1016/j.micromeso.2016.06.020
D. Liang, Y. Wang, H. Shi, Z. Luo, R. L. Quirino, Q. Lu, C. Zhang, Controllable release fertilizer with low coating content enabled by superhydrophobic castor oil-based polyurethane nanocomposites prepared through a one-step synthetic strategy. Ind. Crop. Prod. 189, 115803 (2022). https://doi.org/10.1016/j.indcrop.2022.115803
D. Liang, C. Xia, H. Huang, Y. Liu, Z. Ma, S. Li, Z. Meng, Weed control and slow-release behavior of 2-methyl-4-chlorophenoxyacetate intercalated layered double hydroxide. Coll. Surf. 658, 130661 (2022). https://doi.org/10.1016/j.colsurfa.2022.130661
L.T. Lim, R. Auras, M. Rubino, Processing technologies for poly (lactic acid). Prog. Polym. Sci. 33(8), 820–852 (2008). https://doi.org/10.1016/j.progpolymsci.2008.05.004
S.M. Lohmousavi, H.H.S. Abad, G. Noormohammadi, B. Delkhosh, Synthesis and characterization of a novel controlled release nitrogen-phosphorus fertilizer hybrid nanocomposite based on banana peel cellulose and layered double hydroxides nanosheets. Arab. J. Chem. 13(9), 6977–6985 (2020)
Y. Lu, K. Xu, L. Zhang, M. Deguchi, H. Shishido, T. Arie, K. Takei, Multimodal plant healthcare flexible sensor system. ACS Nano 14(9), 10966–10975 (2020). https://doi.org/10.1021/acsnano.0c03757
J. Martinazzo, D.K. Muenchen, A.N. Brezolin, A.M. Cezaro, A.A. Rigo, A. Manzoli, C. Steffens, Cantilever nanobiosensor using tyrosinase to detect atrazine in liquid medium. J. Environ. Sci. Health. B 53(4), 229–236 (2018). https://doi.org/10.1080/03601234.2017.1421833
S. Mohammadi‐Khoo, P. N. Moghadam, A. R. Fareghi, N. Movagharnezhad, Synthesis of a cellulose‐based hydrogel network: Characterization and study of urea fertilizer slow release. J. Appl. Polym. Sci. 133(5), (2016). https://doi.org/10.1002/app.42935
R.R. Mohamed, M.E. Fahim, S. Soliman, Development of hydrogel based on Carboxymethyl cellulose/poly (4-vinylpyridine) for controlled releasing of fertilizers. BMC Chem. 16, 52 (2022). https://doi.org/10.1186/s13065-022-00846-6
D.M. Nascimento, Y.L. Nunes, M.C. Figueirêdo, H.M. de Azeredo, F.A. Aouada, J.P. Feitosa, M.F. Rosa, A. Dufresne, Nanocellulose nanocomposite hydrogels: technological and environmental issues. Green Chem. 20(11), 2428–2448 (2018)
N. Nachev, M. Spasova, P. Tsekova, N. Manolova, I. Rashkov, M. Naydenov, Electrospun polymer-fungicide nanocomposites for grapevine protection. Polymers. 13(21), 3673 (2021) https://doi.org/10.3390/polym13213673
N. Nesakumar, S. Sethuraman, U.M. Krishnan, J.B.B. Rayappan, Electrochemical acetylcholinesterase biosensor based on ZnO nanocuboids modified platinum electrode for the detection of carbosulfan in rice. Biosens. Bioelectron. 77, 1070–1077 (2016)
R. Noor, H. Yasmin, N. Ilyas, A. Nosheen, M. N. Hassan, S. Mumtaz, N. Khan, A. Ahmad, P. Ahmad, Comparative analysis of iron oxide nanoparticles synthesized from ginger (Zingiber officinale) and cumin seeds (Cuminum cyminum) to induce resistance in wheat against drought stress. Chemosphere 292, 133201 (2022)
A. B. Nörnberg, V. R. Gehrke, H. P. Mota, E. R. Camargo, A. R. Fajardo, Alginate-cellulose biopolymeric beads as efficient vehicles for encapsulation and slow-release of herbicide. Coll. Surf. 583, 123970 (2019). https://doi.org/10.1016/j.colsurfa.2019.123970
V. Ojijo, S.S. Ray, Processing strategies in bionanocomposites. Prog. Polym. Sci. 38, 1543–1589 (2013)
A. Olad, H. Gharekhani, A. Mirmohseni, A. Bybordi, Superabsorbent nanocomposite based on maize bran with integration of water-retaining and slow-release NPK fertilizer. Adv. Polym. Technol. 37(6), 1682–1694 (2018)
A. Olad, H. Zebhi, D. Salari, A. Mirmohseni, A.R. Tabar, Slow-release NPK fertilizer encapsulated by carboxymethyl cellulose-based nanocomposite with the function of water retention in soil. Mater. Sci. Eng. 90, 333–340 (2018). https://doi.org/10.1016/j.msec.2018.04.083
K. Pal, S. Chakroborty, P. Panda, N. Nath, S. Soren, Environmental assessment of wastewater management via hybrid nanocomposite matrix implications—an organized review. Environ. Sci. Pollut. Res. 29(51), 76626–76643 (2022)
S. Patel, J. Bajpai, R. Saini, A. K. Bajpai, S. Acharya, Sustained release of pesticide (Cypermethrin) from nanocarriers: an effective technique for environmental and crop protection. Process. Saf. Environ. Prot, 117, 315325 (2018). https://doi.org/10.1016/j.psep.2018.05.012
A.E. Pereira, R. Grillo, N.F. Mello, A.H. Rosa, L.F. Fraceto, Application of poly (epsilon-caprolactone) nanoparticles containing atrazine herbicide as an alternative technique to control weeds and reduce damage to the environment. J. Hazard. Mater. 268, 207–215 (2014). https://doi.org/10.1016/j.jhazmat.2014.01.025
P. Pichetsurnthorn, K. Vattipalli, S. Prasad, Nanoporous impedemetric biosensor for detection of trace atrazine from water samples. Biosens. Bioelectron. 32(1), 155–162 (2012). https://doi.org/10.1016/j.bios.2011.11.055
P.N. Praseetha, A Unique Perspective in Precision of Nano-biotechnology for Sustainable Agricultural Fields. In: Pal K. (eds) Bio-manufactured Nanomaterials Perspectives and Promotion, pp 299–320 (2021). https://doi.org/10.1007/978-3-030-67223-2_14
A. Priyam, N. Yadav, P.M. Reddy, L.O. Afonso, A.G. Schultz, P.P. Singh, Fertilizing benefits of biogenic phosphorous nanonutrients on Solanum lycopersicum in soils with variable pH. Heliyon (2022). https://doi.org/10.1016/j.heliyon.2022.e09144
D. Qiao, H. Liu, L. Yu, X. Bao, G.P. Simon, E. Petinakis, L. Chen, Preparation and characterization of slow-release fertilizer encapsulated by starch-based superabsorbent polymer. Carbohydr. Polym. 147, 146–154 (2016). https://doi.org/10.1016/j.carbpol.2016.04.010
G.B. Ramírez-Rodríguez, C. Miguel-Rojas, G.S. Montanha, F.J. Carmona, G. Dal Sasso, J.C. Sillero, J. Skov Pedersen, N. Masciocchi, A. Guagliardi, A. Pérez-de-Luque, J.M. Delgado-López, Reducing nitrogen dosage in Triticum durum plants with urea-doped nanofertilizers. Nanomaterials. 10(6), 1043 (2020). https://doi.org/10.3390/nano10061043
A. Rashidzadeh, A. Olad, Slow-released NPK fertilizer encapsulated by NaAlg-g-poly (AA-co-AAm)/MMT superabsorbent nanocomposite. Carbohydr. Polym. 114, 269–278 (2014). https://doi.org/10.1016/j.carbpol.2014.08.010
I. Saleem, M. A. Maqsood, M. Z. ur Rehman, T. Aziz, I. A. Bhatti, S. Ali, Potassium ferrite nanoparticles on DAP to formulate slow release fertilizer with auxiliary nutrients. Ecotoxicol. Environ. Saf. 215, 112148 (2021). https://doi.org/10.1016/j.ecoenv.2021.112148
M. Salimi, E. Motamedi, B. Motesharezedeh, H.M. Hosseini and H.A. Alikhani, Starch-g-poly (acrylic acid-co-acrylamide) composites reinforced with natural char nanoparticles toward environmentally benign slow-release urea fertilizers. J. Environ. Chem. Eng. 8(3), 103765 (2020). https://doi.org/10.1016/j.jece.2020.103765
B. Singh, D.K. Sharma, S. Negi, A. Dhiman, Synthesis and characterization of agar-starch based hydrogels for slow herbicide delivery applications. Int. J. Plast. Technol. 19, 263–274 (2015). https://doi.org/10.1007/s12588-015-9126-z
C. Steffens, S. C. Ballen, E. Scapin, D. M. da Silva, J. Steffens, R. A. Jacques, Advances of nanobiosensors and its application in atrazine detection in water: a review. Sens. Actuator. Rep.100096 (2022). https://doi.org/10.1016/j.snr.2022.100096
H. Tan, Y. Zhang, L. Sun, Y. Sun, H. Dang, Y. Yang, D. Jiang, Preparation of nano sustained-release fertilizer using natural degradable polymer polylactic acid by coaxial electrospinning. J. Bio. Macromol. 193, 903–914 (2021). https://doi.org/10.1016/j.ijbiomac.2021.10.181
W. Tanan, J. Panichpakdee, P. Suwanakood, S. Saengsuwan, Biodegradable hydrogels of cassava starch-g-polyacrylic acid/natural rubber/polyvinyl alcohol as environmentally friendly and highly efficient coating material for slow-release urea fertilizers. J. Ind. Eng. Chem. 101, 237–252 (2021). https://doi.org/10.1016/j.c.2021.06.008
M.B. Taşkın, Ö. Şahin, H. Taskin, O. Atakol, A. Inal, and A. Gunes, Effect of synthetic nano-hydroxyapatite as an alternative phosphorus source on growth and phosphorus nutrition of lettuce (Lactuca sativa L.) plant. J. Plant. Nutrition. 41(9), 1148–1154 (2018). https://doi.org/10.1080/01904167.2018.1433836
Umar, W., Czinkota, I., Gulyás, M., Aziz, T., & Hameed, M. K.: Development and characterization of slow release N and Zn fertilizer by coating urea with Zn fortified nano-bentonite and ZnO NPs using various binders. Env. Tech.Inno. 26, 102250 (2022) https://doi.org/10.1016/j.eti.2021.102250
S. Wang, X. Li, K. Ren, R. Huang, G. Lei, L. Shen, Y. Zhan, L. Jiang, Surface modification of pyrophyllite for optimizing properties of castor oil-based polyurethane composite and its application in controlled-release fertilizer. Arab. J. Chem. 16(2), 104400 (2023). https://doi.org/10.1016/j.arabjc.2022.104400
Y. Wang, M. Liu, B. Ni, L. Xie, X. Zhang, Preparation and properties of novel slow-release PK agrochemical formulations based on carboxymethylcellulose-graft-poly (acrylic acid-co-itaconic acid) super absorbents. J. Macromol. Sci. 48(10), 806–815 (2011). https://doi.org/10.1021/ie900254b
X. Xu, J. Wang, Y. Tang, X. Cui, D. Hou, H. Jia, S. Wang, L. Guo, J. Wang, A. Lin, Mitigating soil salinity stress with titanium gypsum and biochar composite materials: improvement effects and mechanism. Chemosphere 321, 138127 (2023)
Z. Xu, T. Tang, Q. Lin, J. Yu, C. Zhang, X. Zhao, M. Kah, L. Li, Environmental risks and the potential benefits of nanopesticides: a review. Environ. Chem. Lett. 20(3), 2097–2108 (2022)
C.F. Yamamoto, E.I. Pereira, L.H. Mattoso, T. Matsunaka, C. Ribeiro, Slow release fertilizers based on urea/urea–formaldehyde polymer nanocomposites. J. Chem. Eng. 287, 390–397 (2016). https://doi.org/10.1016/j.cej.2015.11.023
Z. Yu, G. Zhao, M. Liu, Y. Lei, M. Li, Fabrication of a novel atrazine biosensor and its subpart-per-trillion levels sensitive performance. Environ. Sci. Technol. 44(20), 7878–7883 (2010)
H. Zhang, H. Yang, J. Shao, Y. Chen, S. Zhang, H. Chen, Multifunctional carboxymethyl cellulose sodium encapsulated phosphorus-enriched biochar composites: Multistage adsorption of heavy metals and controllable release of soil fertilization. Chem. Eng. J. 453, 139809 (2023)
M. Zhang, B. Gao, J. Chen, Y. Li, A.E. Creamer, H. Chen, Slow-release fertilizer encapsulated by graphene oxide films. J. Chem. Eng. 255, 107–113 (2014). https://doi.org/10.1016/j.cej.2014.06.023
X. Zhang, J. Qu, H. Li, S. La, Y. Tian, L. Gao, Biochar addition combined with daily fertigation improves overall soil quality and enhances water-fertilizer productivity of cucumber in alkaline soils of a semi-arid region. Geoderma 363, 114170 (2020)
Y. Zhang, Y. Jingsong, Y. Rongjiang, W. Xiangping, X. Wenping, Short-term effects of biochar and gypsum on soil hydraulic properties and sodicity in a saline-alkali soil. Pedosphere 30(5), 694–702 (2020)
J. Zhao, R. Song, H. Li, Q. Zheng, S. Li, L. Liu, K. Liu, New formulation to accelerate the degradation of pesticide residues: composite nanoparticles of imidacloprid and 24-epibrassinolide. ACS Omega. 7 (33), 29027–29037 (2022). https://doi.org/10.1021/acsomega.2c02820
T. Zhou, Y. Wang, S. Huang, Y. Zhao, Synthesis composite hydrogels from inorganic-organic hybrids based on leftover rice for environment-friendly controlled-release urea fertilizers. Sci. Total. Environ. 615, 422–430 (2018). https://doi.org/10.1016/j.scitotenv.2017.09.084
X. Zhou, D. Xu, J. Yang, Z. Yan, Z. Zhang, B. Zhong, X. Wang, Treatment of distiller grain with wet-process phosphoric acid leads to biochar for the sustained release of nutrients and adsorption of Cr (VI). J. Hazard. Mater. 441, 129949 (2023)
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Authors greatly acknowledge the financial support from Kerala State Council for Science, Technology and Environment, Government of Kerala, for the project KSCSTE/655/2022-ETP 290/2022.
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Both authors equally contributed for the work. Figures and Tables are drawn by both authors.All authors reviewed the manuscript
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Feba Mohan, M., Praseetha, P.N. Prospects of Biopolymers Based Nanocomposites for the Slow and Controlled Release of Agrochemicals Formulations. J Inorg Organomet Polym 33, 3845–3860 (2023). https://doi.org/10.1007/s10904-023-02695-9
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DOI: https://doi.org/10.1007/s10904-023-02695-9