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The Crystallization Behavior of As–S–Se Chalcogenide Glass with Small Amounts of Arsenic

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Abstract

The study of the crystallization behaviour of glass As1Se74S25 was carried out. The main disadvantage of glasses with a high selenium content is their tendency to crystallize. The crystalline phases formed after exposure to temperatures 100–180 ˚С were studied by X-ray diffraction analysis. Se; Se4S4; Se5S; As2(Se,S)3; and Se0,72S0,29 (γ-phase) were found. Two temperature regions with different crystallization behaviours were distinguished: at higher temperatures crystallization develops via nucleation and growth of equilibrium phase, but at lower temperatures only via growth of already existing nuclei.

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Funding

The research is partially funded by the Ministry of Science and Higher Education of the Russian Federation as part of World-class Research Center program, grant number 075-15-2022-311 dated from 20 April 2022.

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Authors and Affiliations

  1. Peter the Great St. Petersburg Polytechnic University, St. Petersburg, 195251, Russia

    Victor A. Klinkov, Valentina D. Andreeva & Tatiana V. Larionova

  2. Institute of Chemistry of Silicates named I.V. Grebenshchikov, Russian Academy of Sciences, St. Petersburg, 199034, Russia

    Alexander V. Semencha

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  1. Victor A. Klinkov
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  2. Valentina D. Andreeva
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  3. Tatiana V. Larionova
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  4. Alexander V. Semencha
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Contributions

Conceptualization, V.A.K., T.V.L. and A.V.S.; methodology, A.V.S., V.D.A., V.A.K. and T.V.L.; investigation, V.D.A., V.A.K., T.V.L.; writing—original draft preparation, V.A.K., T.V.L. and A.V.S.; writing—review and editing, V.A.K., T.V.L. and V.K.Y. All authors have read and agreed to the published version of the manuscript.

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Correspondence to Victor A. Klinkov.

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The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses or interpretation of data; in the writing of the manuscript or in the decision to publish the results.

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Klinkov, V.A., Andreeva, V.D., Larionova, T.V. et al. The Crystallization Behavior of As–S–Se Chalcogenide Glass with Small Amounts of Arsenic. J Inorg Organomet Polym 33, 2517–2522 (2023). https://doi.org/10.1007/s10904-023-02648-2

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