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Fabrication of Layered Hydroxide Composite with Polydimethylsiloxane Hydroxy-Terminated for Epoxy Resin Flame Retardancy

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Abstract

The advantage of the concurrent development in polymers flame retardant is illustrated by the hybrid material technology of flame retardants, which, as opposed to conventional flame retardants, blends distinct elements into a whole. Layered zinc hydroxide, sodium dodecyl sulfate, borate ion, and polydimethylsiloxane were used to make a flame retardant composite, a new organic–inorganic hybrid material as a flame retardant. Using analysis methods, the structures of materials were investigated following synthesis. The interlayer space of the layered zinc hydroxide was studied for the intercalation of ions, according to the X-ray diffraction studies. The chemical structure of produced compounds was assessed with energy dispersive spectrum and fourier transforms infrared spectroscopy. The morphology of the synthesized materials was identified using emission scanning electron microscopy. The thermal resistance of the synthesized samples and coating samples was measured by thermogravimetric analysis. By adding a little amount of flame retardant composite flame retardant, the fire danger of epoxy resin was significantly decreased. According to the plate temperature and flammability test experiment, flame retardant composite with 0.075% w/w led to showed that the synergistic role of the flame retardant composite compound including zinc, borate ions, and also the polydimethylsiloxane played a significant role in reducing the risks of epoxy resin hazard flaming as well as reducing heat and damage to the metal substrate.

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Authors and Affiliations

  1. Institute for Color Science and Technology, Department of Resin and Additives, Tehran, Iran

    Milad Abniki, Behzad Shirkavand Hadavand & Farhood Najafi

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  1. Milad Abniki
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  2. Behzad Shirkavand Hadavand
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  3. Farhood Najafi
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Contributions

The initial planning was done by Dr. Milad Abniki and Dr. Farhood Najafi. Laboratory work was done by Dr. Milad Abniki. The interpretation and analysis of the results was done by Dr. Behzad Shirkavand Hadavand. The main manuscript text was written by Dr. Milad Abniki, Dr. Behzad Shirkavand Hadavand, and Dr. Farhood Najafi. All authors reviewed the manuscript.

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Correspondence to Behzad Shirkavand Hadavand.

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Abniki, M., Shirkavand Hadavand, B. & Najafi, F. Fabrication of Layered Hydroxide Composite with Polydimethylsiloxane Hydroxy-Terminated for Epoxy Resin Flame Retardancy. J Inorg Organomet Polym 33, 1946–1954 (2023). https://doi.org/10.1007/s10904-023-02630-y

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