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Energy Storage Performance of Nitrogen Doped Reduced Graphene Oxide/Co-Doped Polyaniline Nanocomposites

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Abstract

The design and exploration of carbon-based electrode materials have become highly significant for developing supercapacitor technology, which has attracted considerable attention in energy storage systems. Here, nitrogen-doped reduced graphene oxide (N-rGO) – Polyaniline (PANI) nanocomposites were synthesized by a facile two-step method in which in situ polymerization of aniline monomer was performed on hydrothermally synthesized N-rGO nanosheets in DBSA and H2SO4 medium for co-doping of PANI chains. The effects of various acid concentrations (DBSA:H2SO4 0.5 − 0.25:1 n/n) and N-rGO:aniline ratios (N-rGO:aniline 1:4–10 m/m) used in the preparation of the electrode material on the capacitive properties were investigated. It is found that the co-doped N-rGO-PANI nanocomposites exhibit a high specific capacitance of 346.3 F g− 1 at 1 A g− 1, remarkable rate capacity (99.9%, 1–10 A g− 1) and excellent cycle stability at 5 A g− 1 (81.3%, 5000 cycles) in a two-electrode system. As a result, constructing co-doped PANI chains and N-doped rGO provided a viable and simple way to improve the capacitive performances of supercapacitors.

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Data Availability

The data generated or analyzed during the present work is available on reasonable request from the corresponding author.

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Acknowledgements

The authors thank The Scientific and Technological Research Council of Türkiye (TÜBİTAK; Project No 120M752).

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Ankara University, 06100, Ankara, Türkiye, Turkey

    Hasan Altınışık & Nuray Yıldız

  2. Department of Chemical Engineering, Faculty of Engineering, İzmir Institute of Technology, 35430, İzmir, Türkiye, Turkey

    Bengü Getiren

  3. Department of Chemical Engineering, Faculty of Engineering, Sivas Cumhuriyet University, 58140, Sivas, Türkiye, Turkey

    Zafer Çıplak

  4. Department of Chemical Engineering, Faculty of Engineering and Natural Sciences, Ankara Yıldırım Beyazıt University, 06010, Ankara, Türkiye, Turkey

    Furkan Soysal

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  1. Hasan Altınışık
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  2. Bengü Getiren
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  3. Zafer Çıplak
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  4. Furkan Soysal
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  5. Nuray Yıldız
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Contributions

All authors contributed to the Writing - original draft preparation and Writing - review and editing. Conceptualization performed by Zafer Çıplak, Furkan Soysal, and Nuray Yıldız. Methodology realized by Zafer Çıplak and Furkan Soysal. Formal analysis and investigation were carried out by Hasan Altınışık and Bengü Getiren. The study was supervised by Nuray Yıldız.

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Correspondence to Nuray Yıldız.

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Altınışık, H., Getiren, B., Çıplak, Z. et al. Energy Storage Performance of Nitrogen Doped Reduced Graphene Oxide/Co-Doped Polyaniline Nanocomposites. J Inorg Organomet Polym 33, 353–367 (2023). https://doi.org/10.1007/s10904-022-02456-0

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