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Recent Progress in Oxidative Dehydrogenation of Alkane (C2–C4) to Alkenes in a Fluidized Bed Reactor Under Mixed Metallic Oxide Catalyst

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Abstract

Short-chain olefins are the important feedstock for the chemical industries. The selection of a proper catalyst for oxidative dehydrogenation (ODH) reaction is critical. Here, the study summarized different catalysts by physicochemical techniques such as BET surface area, Raman spectroscopy, and temperature programmed reduction (TPR). The BET analysis of different catalysts gives an optimum value of active and metal loading catalysts for optimum alkenes selectivity. From different Raman spectroscopy analyses, the study pointed out the factor responsible for varying mono vanadate and poly vanadate formation. From TPR analysis of different catalysts, this study pointed out the factors that varied on increasing or decreasing temperature and the effect on the selectivity of alkenes. The effect of different operating conditions was studied. Without catalyst regeneration after each ODH run, the catalyst under the study shows stable behavior and increases the selectivity of the desired product. The CREC riser simulator was used for ODH of propane and ethane, while two zones of fluidized bed reactor (TZFBR) and ICFBR reactors were used for ODH of butane. From the study of MoO3/MgO catalyst, it was observed that TZFBR have high selectivity of butadiene than CFBR and fixed bed reactor. It was concluded that the catalyst VOx–Nb/La-ɣAl2O3 has high conversion (20.1%) of ethane and good selectivity of (85.7%) of ethylene, while in ODH of propane and butane the catalyst 7.5 VOx/ɣAl2O3·ZrO2 (1:1) and MoO3/MgO have high selectivity of propane and 1,3-butadiene respectively. This review will help researchers in decision making for the selection of proper catalyst for ODH of alkane to alkenes.

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Abbreviations

ODH:

Oxidative dehydrogenation

TPR:

Temperature programmed reduction

TZFBR:

Two zones of fluidized bed reactor

MMO:

Mixed metallic oxide

FCC:

Fluidized catalytic cracking

BET:

Brunauer–Emmett–Teller

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Acknowledgements

This study was funded by University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province (No. UNPYSCT- 2020050), Heilongjiang Institute of Technology Doctoral Research Fund (2017BJ31), Provincial Leading Talent Echelon Cultivation Project of Heilongjiang Institute of Technology (No. 2020LJ03). This work was also supported by the Fundamental Research Grant Scheme, Malaysia [FRGS/1/2019/STG05/UNIM/02/2] and MyPAIR-PHC-Hibiscus Grant [MyPAIR/1/2020/STG05/UNIM//1]. The authors would also like to acknowledge UCSI University Research and Innovation Grant [REIG-FAS-2020/028].

Funding

This study was funded by University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province (No. UNPYSCT- 2020050), Heilongjiang Institute of Technology Doctoral Research Fund (2017BJ31), Provincial Leading Talent Echelon Cultivation Project of Heilongjiang Institute of Technology (No. 2020LJ03), UCSI University Research and Innovation Grant [REIG-FAS-2020/028].

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Authors and Affiliations

  1. School of Chemical and Materials Engineering (SCME), National University of Sciences and Technology (NUST), Islamabad, 44000, Pakistan

    Zahid Ullah, Muzammil Khan, Umair Sikandar & Muhammad Taqi Mehran

  2. Department of Chemical Engineering, University of Engineering and Technology, Peshawar, 25120, Pakistan

    Imran Khan

  3. Department of Chemical, Polymer and Composite Materials Engineering, University of Engineering and Technology (New-Campus), Lahore, Pakistan

    Asif Jamil

  4. Department of Petroleum Engineering, School of Engineering, Asia Pacific University of Technology and Innovation, 57000, Kuala Lumpur, Malaysia

    Muhammad Mubashir

  5. Department of Chemical and Environmental Engineering, Faculty of Science and Engineering, University of Nottingham Malaysia Campus, Jalan Broga, 43500, Semenyih, Selangor Darul Ehsan, Malaysia

    Pei En Tham & Pau Loke Show

  6. Faculty of Applied Sciences, UCSI University, UCSI Heights, Cheras, 56000, Kuala Lumpur, Malaysia

    Kuan Shiong Khoo

  7. Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection, Wenzhou University, Wenzhou, 325035, China

    Pau Loke Show

  8. Department of Chemical Engineering and Materials Science, Yuan Ze University, Taoyuan, Taiwan

    Kuan Shiong Khoo

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  1. Zahid Ullah
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ZU: Writing—original draft, Writing—review & editing, IK & MK: Conceptualization, Formal analysis, Data curation, Funding acquisition, Investigation, KSK: Supervision, Validation, Writing—review & editing, AJ & US: Data curation, Formal analysis, Funding acquisition, Investigation, Visualization, TM & MM: Conceptualization, Visualization, PET: Supervision, Validation, Writing—review & editing, PLS: Funding acquisition, Supervision, Validation.

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Correspondence to Umair Sikandar, Kuan Shiong Khoo or Pau Loke Show.

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Ullah, Z., Khan, M., Khan, I. et al. Recent Progress in Oxidative Dehydrogenation of Alkane (C2–C4) to Alkenes in a Fluidized Bed Reactor Under Mixed Metallic Oxide Catalyst. J Inorg Organomet Polym 34, 1–13 (2024). https://doi.org/10.1007/s10904-022-02433-7

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