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Selective Determination of Catechol Using One Dimensional Zeolitic Cobalt–Nickel Imidazolate Framework

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Abstract

The bi-metallic zeolitic imidazole framework (ZIF) exhibits greater attention because of its attractive physicochemical properties. Herein, we report the non-enzymatic selective electrochemical detection of catechol (CC) using cobalt–nickel zeolitic imidazolate framework nanofibres (Ni-ZIF-67 NFs) fabricated by the electrospinning route. Owing to donor–acceptor and hydrogen bonding interactions between the metal ions and imidazole, forming tetrahedral coordination with an increased crystalline state further provides excellent mechanical stability. The porous nature of the Ni-ZIF-67 NFs sample gives good catalytic property; as a result, the response of nanofibre composite is linearly proportional to the concentration of CC in the range of 10 nM–1 mM with the detection limit of 4 nM. The prepared electrode shows good anti-interference ability and reproducibility. Finally, the fabricated electrode has been successfully utilized for the detection of targeted analytes for real-time sample analysis i.e. tea and coffee samples with significant results.

Graphical abstract

Ni-ZIF-67 NFs have been successfully fabricated by electrospinning method and utilized for the detection of catechol. The bi-metallic ZIF material shows high stability, improved electrocatalytic behaviour having a detection range of 10 nM–1 mM with the detection limit of 4 nM should be useful further for diverse bio-sensing applications.

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Acknowledgements

The author JW gratefully acknowledges the RUSA 2.0 [F.24-51/2014-U, Policy (TN Multi-Gen), Dept. of. Edn, Gol] for Financial assistance.

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The authors have not disclosed any funding.

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Author notes

  1. S. Girija and S. Sam Sankar have contributed equally to this work.

Authors and Affiliations

  1. Department of Bioelectronics and Biosensors, Alagappa University, Karaikudi, Tamil Nadu, India

    S. Girija & J. Wilson

  2. Electrochemical Process Engineering (EPE) Division, CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi, Tamil Nadu, India

    S. Sam Sankar &  SubrataKundu

Authors
  1. S. Girija
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  2. S. Sam Sankar
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  3. SubrataKundu
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  4. J. Wilson
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Correspondence to SubrataKundu or J. Wilson.

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Girija, S., Sankar, S.S., SubrataKundu et al. Selective Determination of Catechol Using One Dimensional Zeolitic Cobalt–Nickel Imidazolate Framework. J Inorg Organomet Polym 32, 3837–3847 (2022). https://doi.org/10.1007/s10904-022-02392-z

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  • DOI: https://doi.org/10.1007/s10904-022-02392-z

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