Abstract
Polycarbazole (PCz) has been synthesized by chemical oxidation method using APS as an oxidizing agent and PCz/CuO and PCz/Fe2O3 nanocomposites by in situ polymerization method for different wt% of CuO and Fe2O3 at room temperature. XRD patterns confirmed crystalline nature of samples. FTIR indicated strong interaction between PCz and nano fillers. The morphological and optical absorption studies were carried out using SEM and UV–Vis respectively. Addition of CuO or Fe2O3 to PCz decreased its direct and indirect band gaps. However, band gap showed a small change with dopant contents up to 30%. Urbach energy decreased with the addition of dopants. But Urbach energy of the composites increased with increasing dopants content from 10 to 30%. DC conductivity of PCz and its nanocomposites has been measured by following two probe technique in the temperature range 300–423 K. The conductivity of both the nanocomposites is found to be less than the pure PCz and it is found to increase with wt% of CuO or Fe2O3 as the case may be. The activation energy has been determined by fitting Arrhenius expression to the dc conductivity data at high temperature. The activation energy of polycarbazole is determined to be less than that of the composites. In both the composites, activation energy decreased and conductivity increased with the increase of dopant content.
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M.C. Santos, O.H.C. Hamdan, S.A. Valverde, E.M. Bianchi, Synthesis and characterization of V2O5/PANI thin films for application in amperometric ammonia gas senors. Organic Electron 65, 116–120 (2019)
K.M. Zaidan, H.F. Hussein, R.A. Hassan, Synthesis and characterization of (Pani/n-si) solar cell. Energy Procedia 6, 85–91 (2011). https://doi.org/10.1016/j.egypro.2011.05.010
M. Gokcen, T. Tunc, S. Altindal, I. Uslu, Electrical and photocurrent characteristics of Au/PVA (Co-doped)/n-Si Photoconductive diodes. Mater. Sci. Eng., B 177(5), 416–420 (2012). https://doi.org/10.1016/j.mseb.2012.01.004
B. Muthulakshmi, D. Kalpana, S. Pitchumani, N.G. Renganathan, Electrochemical deposition of polypyrrole for symmetric supercapacitors. J. Power Sour. 158(2), 1533–1537 (2006). https://doi.org/10.1016/j.jpowsour.2005.10.013
P. Burgmayer, R.W. Murray, Faster ion gate membranes. J. Electroanal. Chem. 147, 339–344 (1983). https://doi.org/10.1016/S0022-0728(83)80080-1
J.M. Sansinena, J. Gao, H.L. Wang, High-performance, monolithic polyaniline electrochemical actuators. Adv. Func. Mater. 13(9), 703–709 (2003). https://doi.org/10.1002/adfm.200304347
S.T. Doslu, B.D. Mert, B. Yazici, Polyindole top coat on TiO2 sol-gel films for corrosion protection of steel. Corros. Sci. Colume 66, 51–58 (2013). https://doi.org/10.1016/j.corsci.2012.08.067
C. Qi, O.M. Lu, P. Hemmershoj, D. Zhou, Y. Han, B. Laursen, C.G. Yan, B. Han, Micro porous polycarbazole with high specific surface area for gas storage and separation. J. Am. Chem. Soc 134, 6084–6087 (2012). https://doi.org/10.1021/ja300438w
A. Zahoor, T. Qiu, J. Zhang, Synthesis and characterization of Ag@polycarbazole nanopaticles and their novel optical behavior. J. Mater. Sci. 44, 6054–6059 (2009). https://doi.org/10.1007/s10853-009-3831-y
U. Baig, A.W. Waseem, L.T. Hun, Facile synthesis of electrically conductive polycarbazole-zirconium(IV)phosphate cation exchange nanocomposite and its room temperature ammonia sensing performance. New J. Chem 20, 1–27 (2015). https://doi.org/10.1039/C5NJ01029B
A. Srivatava, P. Chakrabarti, Fabrication and electrical characterization of a polycarbazole/ZnO based organic and inorganic hybride heterojunction diode. Superlattices Microstruct. 88, 723–730 (2015). https://doi.org/10.1016/j.spmi.2015.10.035
L.N. Shubha, P. Madhusudana Rao, Temperature characterization of dielectric permittivity and AC conductivity of nano copper oxide- doped polyaniline composite. J. Adv. Dielectr. (2016). https://doi.org/10.1142/S2010135X16500181
A.M. El Sayed, W.M. Morsi, α-Fe2O3/(PVA + PEG) Nanocomposite films; synthesis, optical, and dielectric characterizations. J. Mater. Sci. 49, 5378–5387 (2014). https://doi.org/10.1007/s10853-014-8245-9
J. Yan, M. Li, H. Wang, X. Lian, Y. Fan, Z. Xie, B. Niu, W. Li, preparation and property studies of chitosan-PVA biodegradable antibacterial multiplayer films doped with Cu2O and nano-chitosan composites. Food Control 126, 108049 (2021). https://doi.org/10.1016/j.foodcont.2021.108049
J. Zhang, D. Shu, T. Zhang, H. Chen, H. Zhao, Y. Wang, Z. SUN, T. Shaoqing, X. Fang, X.U. Cao, Capacitive properties of PANI/MnO2 synthesized via simultaneous-oxidation route. J. Alloys Compd. 532, 1–9 (2021). https://doi.org/10.1016/j.jallcom.2012.04.006
A. De, A. Das, S. Lahiri, Heavy ion irradiation on conducting polypyrrole and ZrO2-polypyrrole nanocomposites. Synth. Met. 144(3), 303–307 (2004). https://doi.org/10.1016/j.synthmet.2004.04.006
M.O. Ansari, F. Mohammad, Thermal stability, electrical conductivity and ammonia sensing studies on p-toluenesulfonic acid doped polyaniline:titanium dioxide(pTSA/Pani:TiO2) nanocomposites. Sens. Actuators, B Chem. 157(1), 122–129 (2011). https://doi.org/10.1016/j.snb.2011.03.036
P. Manivel, S. Ramakrishnan, N.K. Kothukar, A. Balamurugan, N. Ponpandian, D. Mangalaraj, C. Viswanathan, Optical and electrochemical studies of polyaniline/SnO2 fibrous nanocomposites. Mater. Res. Bull. (2013). https://doi.org/10.1016/j.materresbull.2012.11.033
S. Ashokan, P. Jayamurugan, V. Ponnuswamy, Effects of CuO and oxidant on the morphology and conducting properties of PANI:CuO hybrid nanocomposites for humidity sensor application. Polym. Sci. 61, 86–97 (2019)
G. Rajasudha, L.M. Jayan, D. Durga Lakshmi, P. Thangadurai, N. Boukos, V. Narayanan, A. Stephen, Polyindole-CuO composite polymer electrolyte containing LiClo4 for lithium ion polymer batteries. Polym. Bull. (2012). https://doi.org/10.1007/s00289-011-0548-1
K. Malook, I. Haque, M. Khan, M. Ali, Polypyrrole-Cuo based composites, promotional effects of CuO contents on polypyrrole characteristics. J. Mater. Sci.: Mater. Electron. 30, 3882–3888 (2019). https://doi.org/10.1007/s10854-019-00673-x
R. Gangopadhyaya, A. De, S. Das, Transport properties of polypyrrole-ferric oxide condcucting nanocomposite. J. Appl. Phys. 87, 2363 (2000). https://doi.org/10.1063/1.372188
R. Ganesan, D. Dhinasekaran, P. Thangadurai, N. Boukos, N. Vengidusamy, S. Arumainathan, Preparation and characterizaton of polyindole-iron oxide composite polymer electrolyte containing LiClO4. Polym.-Plast. Technol. Eng. 51, 225–230 (2012). https://doi.org/10.1080/03602559.2011.618159
N.C. Horti, M.D. Kamatagi, N.R. Patil, S.K. Nataraj, S.A. Patil, S.R. Inamdar, Synthesis and photoluminescence properties of polycarbazole/tin oxide (PCz/SnO2) polymer nanocomposites. Polym. Bull. (2020). https://doi.org/10.1007/s00289-020-03428-5
M. Das, S. Roy, Preparation, characterization and properties of newly synthesized SnO2–polycarbazole nanocomposite via room temperature solution phase synthesis process. Mater. Today: Proceed. 18, 5438–5446 (2019). https://doi.org/10.1016/j.matpr.2019.07.573
V. Raj, D. Madeswari, M. Mubarak Ali, Journal of applied science, Chemical Formation, Characterization and Properties of Polycarbazole. 116, 147–154 (2010), https://doi.org/10.1002/app.31511.
A. Kumar, M. Tiwari, R. Prakash, Electrochemical study of interfacially synthesized polycarbazole with different oxidants. ChemElectroChem 2, 2001–2010 (2015). https://doi.org/10.1002/celc.201500318
M. Aslam, M.A. Kalyar, Z.A. Raza, Fabrication of nano-CuO-loaded PVA composite films with enhanced optomechanical properties. Polym. Bull. https://doi.org/10.1007/s00289-020-03173-9.
J. Selvi, S. Mahalakshmi, V. Parthasarathy, Vhechia Hu, Yi-Feng Lin, Kuo-Lun Tung, R. Anbarasan, A.A Annie, Optical, thermal, mechanical porperties, and non-isothermal degradation kinetic studies on PVA/CuO nanocomposites. 40, 3737–3748 (2019) https://doi.org/10.1002/pc.25235.
M. Shakir, N. Iram, M.S. Khan, S.I. Al-Resayes, A.A. Khan, U. Baig, Electrical conductivity, isothermal stability, and ammonia-sensing performance of newly synthesized and characterized organic−inorganic polycarbazole−titanium dioxide nanocomposite. Ind. Eng. Chem. Res 53, 8035–8044 (2014). https://doi.org/10.1021/ie404314q
P. Syed Abthagir, R. Saraswathi, Charge transport and thermal properties of polyindole, polycarbazole and their derivatives. Thermochim. Acta 424, 25–35 (2004)
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Raghavendra, B., Sankarappa, T. & Malge, A. Structural, Optical and Electrical Conductivity Studies in Polycarbazole and its Metal Oxide Nano Composites. J Inorg Organomet Polym 32, 2416–2427 (2022). https://doi.org/10.1007/s10904-022-02358-1
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DOI: https://doi.org/10.1007/s10904-022-02358-1