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Sonochemically Prepared GdWNFs/CNFs Nanocomposite as an Electrode Material for the Electrochemical Detection of Antibiotic Drug in Water Bodies

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Abstract

The work demonstrates the development of an electrochemical sensor for quantification of Chloramphenicol (CA) using pencil graphite electrode (PGE) modified with Gadolinium tungstate nano flakes and carbon nano fibers composite (PGE/GWNfs/CNFs). The composite was further characterized and confirmed by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy, transmission electron microscopy analysis. The prepared GWNfs/CNFs nano composite was fabricated by drop casting method to get PGE/GWNfs/CNFs working electrode. The modified electrode is then analyzed by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and differential pulse voltammetry (DPV) methods for its electrochemical and electrocatalytic property. The electrochemical investigation of developed sensor shows enhanced activity towards electro-oxidation of CA. The DPV studies revealed high efficacy characteristics such as sensitivity in the range 0.03984 µA µM−1 cm−2, selectivity, good linear range (5–50 μM), and low detection limit (0.4 μM). The study benchmarks the use of GWNfs/CNFs as an excellent transducer material in electrochemical sensing of CA in standard samples thus, it finds an efficient potential application in the analysis of CA in environment sample analysis.

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Acknowledgements

Authors are thankful to VGST CISEE (GRD 647), GOK, and authors acknowledges Researchers Supporting Project Number (RSP-2021/266) King Saud University, Riyadh, Saudi Arabia for funding.

Funding

The authors express thankful to Researchers Supporting Project Number (RSP-2021/266), King Saud Universtiy, Riyadh, Saudi Arabia.

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Author notes

  1. P. Manikanta and B. R. Hariprasad have worked equally.

Authors and Affiliations

  1. Department of Chemistry, S J College of Engineering, JSS Science and Technology University, Mysuru, 570008, India

    P. Manikanta, B. R. Hariprasad, S. Sandeep, C. S. Karthik & P. Mallu

  2. Centre for Nano and Material Science (CNMS), Jain University, Jain Global Campus, Bangalore, 562112, India

    P. Manikanta & Bhari Mallanna Nagaraja

  3. Department of Chemical Engineering and Biotechnology, National Taipei University of Technology (Taipei Tech), Taipei, 10608, Taiwan

    B. P. Sanjay

  4. Department of Chemistry (UG), NMKRV College for Women, Jayanagar 3rd Block, Bengaluru, 560011, India

    A. S. Santhosh

  5. Department of Chemistry, College of Science, King Saud University, P.O. Box. 2455, Riyadh, 11451, Saudi Arabia

    Abdullah A. Al-Kahtani & Ammar Mohamed Tighezza

  6. Grassland and Forage Division, National Institute of Animal Science, Rural Development Administration, Chungcheongnam-do, Cheonan, 3100, South Korea

    Muthusamy Karnan

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  1. P. Manikanta
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  2. B. R. Hariprasad
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  4. S. Sandeep
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  11. Muthusamy Karnan
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Correspondence to S. Sandeep or Bhari Mallanna Nagaraja.

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Manikanta, P., Hariprasad, B.R., Sanjay, B.P. et al. Sonochemically Prepared GdWNFs/CNFs Nanocomposite as an Electrode Material for the Electrochemical Detection of Antibiotic Drug in Water Bodies. J Inorg Organomet Polym 32, 2482–2491 (2022). https://doi.org/10.1007/s10904-022-02357-2

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  • DOI: https://doi.org/10.1007/s10904-022-02357-2

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