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Magnetically Recoverable Palladium Nanocatalyst [Pd(II)-Benz-Am-Fe3O4@SiO2] for Ullmann Type Homocoupling of Aryl halides with N2H4 as an Efficient Reductant

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Abstract

A highly efficient and sustainable ferrite supported palladium nanocatalyst (Pd(II)-Benz-Am-Fe3O4@SiO2) has been prepared and characterized by diverse microscopic and spectroscopic techniques. The Pd(II)-Benz-Am-Fe3O4@SiO2 was employed as magnetically recoverable nanocatalyst in the synthesis of symmetrical biaryls by reductive homocoupling of haloarenes (I, Br and Cl) using hydrazine hydrate (N2H4) as reducing agent. The Pd-Benz-Am-Fe3O4@SiO2 nanocatalyst exhibited high surface area and efficient magnetization as 45.25 m2/g and 34 emu/g, respectively. The Electron Dispersive X-ray (EDX) analysis confirmed 3.9 mol % loading of Pd in Pd-Benz-Am-Fe3O4@SiO2. Moverever, high turnover number (TON) and turnover frequency (TOF), operational simplicity and facial recyclability and reusability (up to eight runs) are the remarkable advantages of the nanocatalyst. The catalytic activity and stability of recycled Pd(II)-Benz-Am-Fe3O4@SiO2 catalyst was comprehensively studied from X- ray diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopic (TEM) and EDX analysis.

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Acknowledgements

One of the authors, Pradeep M. Mhaldar, is grateful to Council of Scientific and Industrial Research (CSIR), New Delhi, Government of India, for the award of the Junior Research Fellowship (File no. 09/816(0040)/2017-EMR-I).

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The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

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  1. Department of Chemistry, Shivaji University, Kolhapur, Maharashtra, 416004, India

    Pradeep M. Mhaldar, Mayuri V. Patil, Gajanan S. Rashinkar & Dattaprasad M. Pore

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  1. Pradeep M. Mhaldar
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Mhaldar, P.M., Patil, M.V., Rashinkar, G.S. et al. Magnetically Recoverable Palladium Nanocatalyst [Pd(II)-Benz-Am-Fe3O4@SiO2] for Ullmann Type Homocoupling of Aryl halides with N2H4 as an Efficient Reductant. J Inorg Organomet Polym 32, 3053–3066 (2022). https://doi.org/10.1007/s10904-022-02340-x

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