Skip to main content
SpringerLink
Log in

Electrical, and Magnetic Characteristics of Homo- and Hetero-Bimetallic Macromolecular Complexes with π-Conjugated Imine-oxime Backbone

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Seven homo- and hetero-bimetallic macromolecular complexes (BMCs) were prepared via an in-situ multi-step complexation reaction of CuII, NiII and FeIII metal centers with imine- oxime π-conjugated ditropic spacer (1,4-phenylene-bis(2,3-butanedeimineoxime, L2−). The structures of the obtained [M-L2-M]x, [M`-L2-M`]x, [M-L2-M`]x and their μ-oxo-[M-L2-Fe]x BMCs (M = CuII, NiII; M` = FeIII) were elucidated using different spectroscopic (UV–Vis, FT-IR), powder X-ray diffraction (p-XRD) and microscopic (SEM) techniques. The SEM images indicate that the obtained BMCs exhibit nano/micro globular and rod-like textures. The electrical and magnetic characteristics of the obtained BMCs can be described as magneto-semiconducting materials. The structural, electrical, and magnetic properties inherited in the prepared regime demonstrate that the examined semiconducting π-spacer has clear ability to semi-conduct electron transport and delocalize spin leading to antiferromagnetic coupling, thus offering a favorable magnetic exchange pathway between the paramagnetic metal sites. However, ferromagnetic enhancement is observed in the μ-oxo-[M-L2-Fe]x BMCs where the μ-oxo-bridge overplays the role of the π-spacer. A magnetic responsive thin film was conveniently obtained by solvent casting of the μ-oxo-[Ni-L2-Fe]x BMC in a transparent poly(methamethylacrylate) matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Scheme 2
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Y. Wang, D. Astruc, A.S. Abd-El-Aziz, Chem. Soc. Rev. 48, 558 (2019)

    Article  CAS  Google Scholar 

  2. J.M. Seco, I. Oyarzabal, S.P. Yáñez, J. Cepeda, A.R. Diéguez, Inorg. Chem. 55(21), 11230 (2016)

    Article  CAS  Google Scholar 

  3. S.M. Jansze, K. Severin, Acc. Chem. Res. 51(9), 2139 (2018)

    Article  CAS  Google Scholar 

  4. K.S. Mali, N. Pearce, S.D. Feyter, N.R. Champness, Chem. Soc. Rev. 46, 2520 (2017)

    Article  CAS  Google Scholar 

  5. C. Bizzarri, E. Spuling, D.M. Knoll, D. Volz, S. Bräse, Coord. Chem. Rev. 373, 49 (2018)

    Article  CAS  Google Scholar 

  6. C. Rüttiger, H. Hübner, S. Schöttner, T. Winter, G. Cherkashinin, B. Kuttich, B. Stühn, M. Gallei, A.C.S. Appl, Mater. Interfaces 10(4), 4018 (2018)

    Article  Google Scholar 

  7. M.P. Suh, Y.E. Cheon, E.Y. Lee, Coord. Chem. Rev. 252, 1007 (2008)

    Article  CAS  Google Scholar 

  8. J. Zhou, G.R. Whittell, I. Manners, Macromolecules 47(11), 3529 (2014)

    Article  CAS  Google Scholar 

  9. A.A.G. Valdivia, S.P. Yáñez, J.A. García, B. Fernández, J. Cepeda, A.R. Diéguez, Sci. Rep. (2020). https://doi.org/10.1038/s41598-020-65687-6

    Article  PubMed  PubMed Central  Google Scholar 

  10. B. Wang, M. Jacquet, K. Wang, K. Xiong, M. Yan, J. Courtois, G. Royal, New J. Chem. 42, 7823 (2018)

    Article  CAS  Google Scholar 

  11. R.M. Clarke, T. Storr, Dalton Trans. 43(25), 9380 (2014)

    Article  CAS  Google Scholar 

  12. Z. Shao, X. Han, Y. Liu, W. Xu, Q. Wu, Q. Xie, Y. Zhao, H. Hou, Dalton Trans. 48, 6191 (2019)

    Article  CAS  Google Scholar 

  13. X. Pan, X. Wang, X. Wang, Y. Li, G. Liu, H. Lin, CrystEngComm 21, 6472 (2019)

    Article  CAS  Google Scholar 

  14. C.D. Mekuimemba, F. Conan, A.J. Mota, M.A. Palacios, E. Colacio, Inorg. Chem. 57(4), 2184 (2018)

    Article  CAS  Google Scholar 

  15. J.L. Wang, Y. Bai, H. Pan, G.S. Zheng, D.B. Dang, Dalton Trans. 46, 12771 (2017)

    Article  CAS  Google Scholar 

  16. B. Belhadji, L. Bergqvist, R. Zeller, P.H. Dederichs, K. Sato, H.K. Yoshida, J. Phys. 19, 436227 (2007)

    Google Scholar 

  17. M.A. Halcrow, Spin Crossover Materials: Properties and Applications (John Wiley & Sons Ltd, Oxford, UK, 2013)

    Book  Google Scholar 

  18. G. Fornasieri, A. Bordage, A. Bleuzen, Eur. J. Inorg. Chem. 259, 1322 (2018)

    Google Scholar 

  19. X. Li, X. Wu, Z. Li, J. Yang, J.G. Hou, Nanoscale 4, 5680 (2012)

    Article  CAS  Google Scholar 

  20. V. R-Giménez, S. Tatay, C. M-Gastaldo 2020 Chem. Soc. Rev. DOI. 10.1039/C9CS00594C

  21. L. Sun, C.H. Hendon, S.S. Park, Y. Tulchinsky, R. Wan, F. Wang, A. Walsh, M. Dincă, Chem. Sci. 8(6), 4450 (2017)

    Article  CAS  Google Scholar 

  22. C. Mathonière, Eur. J. Inorg. Chem. 3(4), 248 (2018)

    Article  Google Scholar 

  23. P. Blake, J. St. Onge, T-C. Chen, A. Langlois, A. Younus, I J. Hai, B-H Lin, Y-C Chiu, S. R-Gagné 2020 J. Mater. Chem. C. 8, 24, 8213

  24. I. Arafa, H. El-Ghanem, S. Nemrat 2007 In Recent Developments in Polymer Research, A.V. Hopper (eds) Nova Science Publishers Inc., New York, pp 1–28.

  25. I.M. Arafa, H. El-Ghanem, R. Al-Shalabi, J. Inorg. Organomet. Polym. 13, 69 (2003)

    Article  CAS  Google Scholar 

  26. W. Plass, Coord. Chem. Rev. 253, 2286 (2009)

    Article  CAS  Google Scholar 

  27. S. Ross, T. Weyhermüller, E. Bill, E. Bothe, U. Flörke, K. Wieghardt, P. Chaudhuri, Eur. J. Inorg. Chem. 5, 984 (2004)

    Article  Google Scholar 

  28. B.J. Holliday, T.M. Swager, Chem. Commun. 23(36), 23 (2005)

    Article  Google Scholar 

  29. T.A. Shestimerova, A.V. Shevelkov, Russ. Chem. Rev. 87, 28 (2018)

    Article  CAS  Google Scholar 

  30. X. Ma, E.A. Suturina, S. De, P. Négrier, M. Rouzières, R. Clérac, P. Dechambenoit, Angew. Chem. 57(26), 7841 (2018)

    Article  CAS  Google Scholar 

  31. S. Gupta, M. Fátima, C.G. da-Silva, A.J.L. Pombeiro, Heliyon 5(5), e01623 (2019)

  32. C.I. Yang, Z.Z. Zhang, S.B. Lin, Coord. Chem. Rev. 289, 289–290 (2015)

    Article  Google Scholar 

  33. D.S. Bolotin, N.A. Bokach, VYu. Kukushkin, Coord. Chem. Rev. 313, 62 (2016)

    Article  CAS  Google Scholar 

  34. J.W. Maciel, L.H.G. Kalinke, A.K. Valdo, F.T. Martins, R. Rabelo, N. Moliner, J. Cano, M. Julve, F. Lloret, D. Cangussu, J. Braz. Chem. Soc. 30(11), 2413 (2019)

    CAS  Google Scholar 

  35. C. Gatti, G. Macetti, L.L. Presti, Acta. Cryst. B73, 565 (2017)

    Google Scholar 

  36. D.J.R. Brook, C. Fleming, D. Chung, C. Richardson, S. Ponce, R. Das, H. Srikanth, R. Heindl, B.C. Noll, Dalton Trans. 47, 6351 (2018)

    Article  CAS  Google Scholar 

  37. J.R. Kumpfer, S.J. Rowan, J. Am. Chem. Soc. 133, 12866 (2011)

    Article  CAS  Google Scholar 

  38. M.B. Zakaria, A.A. Belik, T. Nagata, T. Takei, S. Tominaka, T. Chikyow, J. Mag. Mag. Mater. 486, 165276 (2019)

    Article  CAS  Google Scholar 

  39. P. Borys, Z.J. Grzywna, J. Memb. Sci. 445, 107 (2013)

    Article  CAS  Google Scholar 

  40. A. Sohail, M. Fatima, R. Ellahi, K.B. Akram, J. Molecular Liquids 285, 47 (2019)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The financial support from the Jordan University of Science and Technology is deeply appreciated (Grant No. 116/2009).

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Science and Arts, Jordan University of Science and Technology, P.O. Box 3030, Irbid, 22110, Jordan

    Isam M. Arafa, Mazin Y. Shatnawi & Ruba M. Al-Equr

Authors
  1. Isam M. Arafa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mazin Y. Shatnawi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ruba M. Al-Equr
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Isam M. Arafa.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Arafa, I.M., Shatnawi, M.Y. & Al-Equr, R.M. Electrical, and Magnetic Characteristics of Homo- and Hetero-Bimetallic Macromolecular Complexes with π-Conjugated Imine-oxime Backbone. J Inorg Organomet Polym 31, 1323–1335 (2021). https://doi.org/10.1007/s10904-020-01805-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-020-01805-1

Keywords

Search

Navigation