Skip to main content
SpringerLink
Log in

Triazole Containing Salicylimine Linked Organosilocane for Recognition of Ce3+ Ions in Aqueous Media

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Herein, we report a new chemosensor based on 1, 2, 3-triazole containing salicylimine linked organosilocane for the detection of Ce3+ ions in aqueous solution. This receptor was efficiently prepared by employing condensation reaction followed by Cu(I) catalysed alkyne-azide cycloaddition methodology. All the prepared compounds were characterized by IR, 1H NMR, 13CNMR, CHN analysis and mass spectroscopy. The sensitivity of the synthesized sensor towards Ce3+ ions is preeminent with detection limit as low as 1.44 μM. Density functionalised theory based quantum mechanical calculation suggest the molecular geometry of the organosilocane (host) to make the stable complex with cerium (guest). Moreover, chemosensing ability in aqueous solution facilitates the receptor to be used for detection in real samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Scheme 2
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. D. Dai, Z. Li, J. Yang, C. Wang, J.R. Wu, Y. Wang, D. Zhang, Y.W. Yang, J. Am. Chem. Soc. 141, 4756 (2019)

    Article  CAS  Google Scholar 

  2. J.Y. Yun, A. Kim, S.M. Hwang, D. Yun, H. Lee, K.T. Kim, C. Kim, Bull. Chem. Soc. Jpn. 92, 961 (2019)

    Article  CAS  Google Scholar 

  3. G. Fukuhara, J. Photochem. Photobiol. C 42, 100340 (2020)

    Article  CAS  Google Scholar 

  4. S.M. Sheta, M.A. Akl, H.E. Saad, E.R.H. El-Gharkawy, RSC Adv. 10, 5853 (2020)

    Article  CAS  Google Scholar 

  5. O.G.G. Salgado, J.C. Teodoro, J.P. Alvarenga, C. de Oliveira, T.S. de Carvalho, D. Domiciano, P.E.R. Marchiori, L.R.G. Guilherme, J. Rare Earths 38, 324 (2020)

    Article  CAS  Google Scholar 

  6. M.R. Awual, T. Yaita, H. Shiwaku, Chem. Eng. 228, 327 (2013)

    Article  CAS  Google Scholar 

  7. B. Sun, L. Zhang, T. Zhou, C. Shao, L. Zhang, Y. Ma, Q. Yao, Z. Jiang, F.A. Selimb, H. Chen, Mater. Chem. C 7, 4057 (2019)

    Article  CAS  Google Scholar 

  8. A. Benedetto, C. Bocca, P. Brizio, S. Cannito, M.C. Abete, S. Squadrone, Toxicol. In Vitro 46, 9 (2018)

    Article  CAS  Google Scholar 

  9. G. Pagano, M. Guida, F. Tommasi, R. Oral, Ecotoxicol. Environ. Saf. 115, 40 (2015)

    Article  CAS  Google Scholar 

  10. B. Wu, D. Zhang, D. Wang, C. Qi, Z. Li, Ecotoxicology 21, 2068 (2012)

    Article  CAS  Google Scholar 

  11. N. Bhuvanesha, S. Suresh, K. Velmurugan, A. Thamilselvan, R. Nandhakumar, J. Photochem. Photobiol. A 386, 112103 (2020)

    Article  Google Scholar 

  12. X. Li, Y. Zheng, Y. Tang, Q. Chen, J. Gao, Q. Luo, Q. Wang, Spectrochim. Acta A 206, 240 (2019)

    Article  CAS  Google Scholar 

  13. X. Luo, D. Chen, Z. Xu, Y. Song, H. Li, C. Xian, J. Rare Earths (2020). https://doi.org/10.1016/j.jre.2019.05.016

    Article  Google Scholar 

  14. M. Liu, Z. Xu, Y. Song, H. Li, C. Xian, J. Lumin. 198, 337 (2018)

    Article  CAS  Google Scholar 

  15. M. Panchal, A. Kongor, M. Athar, V. Mehta, P.C. Jha, V.K. Jain, New J. Chem. 42, 311 (2018)

    Article  CAS  Google Scholar 

  16. H.H. Deng, B.Y. Luo, S.B. He, R.T. Chen, Z. Lin, H.P. Peng, X.H. Xia, W. Chen, Anal. Chem. 91, 4039 (2019)

    Article  CAS  Google Scholar 

  17. G. Singh, A. Singh, P. Satija, G. Sharma, Shilpy, J. Singh, J. Singh, K.N. Singh, A. Kaur, New J. Chem. 43, 5525 (2019)

    Article  CAS  Google Scholar 

  18. G. Singh, Sanchita, S. Rani, G. Sharma, P. Kalra, N. Singh, V. Verma, Sens Actuators B 266, 861 (2018)

    Article  CAS  Google Scholar 

  19. G. Singh, J. Singh, S.S. Mangat, J. Singh, S. Rani, RSC Adv. 5, 12644 (2015)

    Article  CAS  Google Scholar 

  20. A. Kumar, P.S. Chae, S. Kumar, Dyes Pigm. 174, 108092 (2020)

    Article  CAS  Google Scholar 

  21. L. Wang, W. Li, W. Zhi, Y. Huang, J. Han, Y. Wang, Y. Ren, L. Ni, Sens Actuators B 260, 243 (2018)

    Article  CAS  Google Scholar 

  22. A.N. Kursunlu, E. Guler, J. Mol. Struct. 1134, 345 (2017)

    Article  CAS  Google Scholar 

  23. L. Liang, J. Ruiz, D. Astruc, J. Inorg. Organomet. Polym. Mater. 20, 503 (2010)

    Article  CAS  Google Scholar 

  24. M.Y. Nassar, H.M. Aly, M.E. Moustafa, E.A. Abdelrahman, J. Inorg. Organomet. Polym. Mater. 27, 1220 (2017)

    Article  CAS  Google Scholar 

  25. N. Kaur, G. Singh, J. Singh, A. Singh, P. Satija, G. Kaur, J. Singh, RSC Adv. 8, 36445 (2018)

    Article  CAS  Google Scholar 

  26. A. Bianco, M. Maggini, M. Nogarole, G. Scorrano, Eur. J. Org. Chem. 13, 2934 (2006)

    Article  Google Scholar 

Download references

Acknowledgements

The authors are thankful to CSIR and DST-PURSE for giving other financial assistance.

Funding

Funding was provided by Council of Scientific and Industrial Research, India [Grant No. 01(2950)/18/EMR-11].

Author information

Authors and Affiliations

  1. Department of Chemistry, Panjab University, Chandigarh, 160014, India

    Gurjaspreet Singh,  Shilpy,  Diksha, Pinky Satija,  Sushma,  Mohit, Jashan Deep Kaur & K. N. Singh

  2. Department of Chemistry, GGDSD College, Sector 32, Chandigarh, India

    Akshpreeet Singh

Authors
  1. Gurjaspreet Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shilpy
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Akshpreeet Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Diksha
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Pinky Satija
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Sushma
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Mohit
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Jashan Deep Kaur
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. K. N. Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Gurjaspreet Singh.

Ethics declarations

Conflict of interest

There are no conflicts to declare.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10904_2020_1780_MOESM1_ESM.docx

Supplementary file1 (DOCX 7813 kb)—The supplementary material contains IR, 1H NMR and 13C NMR of compounds 2 to 4, Massspectrum of compounds 3 and 4 and IR and IH NMR of complex 4 + Ce3+.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Singh, G., Shilpy, Singh, A. et al. Triazole Containing Salicylimine Linked Organosilocane for Recognition of Ce3+ Ions in Aqueous Media. J Inorg Organomet Polym 31, 997–1005 (2021). https://doi.org/10.1007/s10904-020-01780-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-020-01780-7

Keywords

Search

Navigation