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Structural, Vibrational, Optical and Improved Photoluminescence Properties of Dy3+ Doped Ca2KZn2V3O12 Phosphors

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Abstract

A series of dysprosium (Dy3+) ion doped Ca2KZn2V3O12 phosphors were explored which exhibits a broad band and sharp peaks in the visible region under the ultraviolet light excitation. Fourier transform infrared (FTIR) spectra and the optical diffuse reflectance spectra were ascribing the formation of the distorted VO4 tetrahedral group due to the influence of Dy3+ ions. Moreover, a tunable luminescence color was achieved by doping of Dy3+ ion in the Ca2KZn2V3O12 phosphor. Through doping concentration optimization, the Ca2KZn1.9Dy0.1V3O12 phosphor was observed for high color rendering index (CRI) and excellent correlated color temperature (CCT) with cool white emission. Hence, in the designing of the VO4 → Dy3+ energy transfer that is capable of converting ultraviolet light into efficient white light, this phosphor is suitable for solid-state lighting applications.

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Acknowledgements

The authors wish to thank the University Grants Commission (UGC) for the financial support through the Minor Research Project-6838/16 (SERO/UGC), Hyderabad, India.

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Authors and Affiliations

  1. PG and Research Department of Physics, N.M.S.S.V.N. College, Madurai, Tamilnadu, 625 019, India

    T. Jeyakumaran, N. Venkatesh Bharathi & S. Ramaswamy

  2. Physics Research Centre, V.H.N.S.N. College, Virudhunagar, Tamilnadu, 626 001, India

    R. Shanmugavel & P. Sriramachandran

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  1. T. Jeyakumaran
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Correspondence to S. Ramaswamy.

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Jeyakumaran, T., Venkatesh Bharathi, N., Shanmugavel, R. et al. Structural, Vibrational, Optical and Improved Photoluminescence Properties of Dy3+ Doped Ca2KZn2V3O12 Phosphors. J Inorg Organomet Polym 31, 695–703 (2021). https://doi.org/10.1007/s10904-020-01766-5

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